The invention discloses a rare earth, nickel and copper co-doping cerium dioxide/cerium dioxide film and a preparing method thereof. The preparing method includes the specific steps that firstly, soluble salt, nickel salt, copper salt, rare earth salt, water and ethylene glycol are mixed into an electrolyte; secondly, a cerium sheet serves as an anode, transparent tape is stuck to one face of the cerium sheet, a platinum sheet or a lead sheet serves as a cathode, the anode and the cathode are put into the electrolyte to be subjected to anodizing, and after anodizing is over, an anode oxidization part is obtained; and thirdly, the anode oxidization part is put into a muffle furnace to be roasted, and the film is obtained, wherein the surface of the film is provided with multiple nanometer straight holes, the lower face of the film is provided with compact rare earth, nickel and copper co-doping cerium dioxide, and the other face of the film is provided with cerium dioxide. The preparing method is simple, and the hole length of the multiple nanometer straight holes in the surface of the film ranges from 18 microns to 112 microns, wherein the surface of the film is provided with the multiple nanometer straight holes, and the lower face of the film is provided with compact rare earth, nickel and copper co-doping cerium dioxide.