The invention relates to a chloride ion penetration-resistant concrete doped with waste glass. The chloride ion penetration-resistant concrete doped with the waste glass comprises the following raw materials: 10-30 wt% of a cementing material (cement, glass micropowder and silica fume), 3-8 wt% of fine glass aggregate, 25-40 wt% of natural sand, 35-50 wt% of gravel, 5-15 wt% of water, and an admixture, based on the total mass of 100%, wherein based on the total mass of 100%, the cementing material (cement, glass micropowder and silica fume) comprises 70-85 wt% of cement, 10-20 wt% of glass micropowder and 5-10 wt% of silica fume. The chloride ion penetration-resistant concrete doped with the waste glass is prepared by the following steps: dosing the prepared glass micropowder, fine glass aggregate, gravel, cement and silica fume in proportion, adding into a mixer, and premixing for more than 20 s; adding the weighed admixture which is 0.5-1.5 wt% of the total mass of the cementing material, and water into the premix in a water-binder ratio of 0.38-0.55, and mixing for more than 120 s. The fine glass aggregate and the glass micropowder are prepared from the waste glass.