Black bisazo sulfonic acid compound, and salt, preparation method and application thereof
A technology of disazosulfonic acid and compound, which is applied in a class of black disazosulfonic acid compound or its salt, its preparation and application field, can solve the problems of ink instability and impossibility, and achieve improved ozone resistance and improved ozone resistance. The effect of high stability and solubility
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[0055] The preparation of the ink composition of the present invention is to dissolve the black disazosulfonic acid compound or its salt, or its mixture, in water or the water-soluble organic solvent described in the present invention, and make it Made by dissolving together with the ink additives mentioned above.
[0056] In the above production method, there is no particular limitation on the order in which the components are dissolved. The dye may be dissolved in water or the water-soluble organic solvent in advance, and the ink control agent may be added to dissolve the dye, or an aqueous solvent or an ink preparation agent may be added after dissolving the dye in water. The order may be different from this. Furthermore, an ink composition may be produced by adding a water-soluble organic solvent and an ink additive to a solution obtained by desalting a reaction liquid containing the dye or a solution containing the pigment by reverse osmosis membrane. When preparing the...
Embodiment 1
[0066] 36.5 parts of 2-amino-5-(2-sulfonic acid oxyethylsulfone) benzenesulfonic acid (commonly known as sulfonated para-ester), dissolved in 200 grams of water under stirring, added 37.5 parts of 30% hydrochloric acid, added 50 parts of ice , cooled to 0--5°C, added dropwise 50 parts of aqueous solution containing 7 parts of sodium nitrite under stirring, maintained the reaction temperature at about 0-5°C, stirred for 1 hour, added 3 parts of urea, and filtered after stirring for 0.5 hours to obtain Clear diazotization solution.
[0067] Dissolve 18 parts of 4-amino-5-hydroxy-naphthalene-2,7-disulfonic acid (commonly known as H-acid) in 100 parts of water, add 50 parts of ice cubes, stir, and drop about 60% diazotization solution , maintain the temperature at 5-10°C, stir for 2-3 hours, adjust the pH to 3 with 10% aqueous sodium hydroxide solution, and continue the reaction for 2 hours to obtain a red solution. Then adjust the pH to 9-10 with 10% sodium hydroxide aqueous sol...
Embodiment 2
[0072] Weigh 11.6 parts of the dye Dye I-0 obtained from Example 1, dissolve it in 100 parts of water, add 1.5 parts of ethanolamine, adjust the pH at 9.5-10.5 with 20% sodium hydroxide, stir and heat up to 50-60 ° C, during the reaction NaOH was added dropwise to maintain the pH until the pH was constant. The reaction solution was cooled. Use a high-pressure reverse osmosis membrane system to remove inorganic salts in the system, after concentration, add the same volume of methanol, the black precipitate precipitates, filters, and dries to obtain 10 parts of black dye Dye I-1, its mass spectrum (EI-MS) m / z (-) is: 246.3([ M -4Na] 4- / 4);336.0([ M -3Na] 3- / 3),328.7([ M -4Na+H] 3- / 3); 515.5([ M -2Na] 2- / 2),504.5([ M -3Na+H] 2- / 2),493.5([ M -4Na+2H] 2- / 2). The most abundant and accurate molecular mass of dye Dye I-1 M is 1077.0.
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