A kind of calcium-poor silicon-rich ecological cement and its application

An ecological cement and silicon-rich technology, applied in cement production and other directions, can solve the problems of incalculable economic and social benefits, high limestone decomposition temperature, and high carbon emissions, and achieve the effects of low requirements, reduced heavy metal pollution, and reduced costs.

Active Publication Date: 2018-02-16
HUNAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the other hand, because SiO 2 It is the main chemical component of industrial waste residue, which enables silica-rich cement to maximize the use of solid waste, which is environmentally friendly; moreover, due to the high decomposition temperature of limestone, high energy consumption, and high carbon emissions, if the cement industry avoids the use of limestone resources Excessive dependence will greatly reduce energy consumption, carbon emissions and exhaust emissions, greatly enhance the sustainability of development, and its long-term economic and social benefits will be inestimable

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Composition of silicon-rich body: 50 parts of natural rock 1, 43 parts of natural rock 2, 7 parts of caustic soda, milled with a small test ball for half an hour to a fully uniform powder, kept at 700°C for 3 hours, then quickly cooled in air. Add 20% (mass ratio to the cooled powder, the same below) of slaked lime (analytical pure) and 45% natural gypsum powder into the cooled powder and ball mill for 35 minutes to obtain cement. Fineness: 6% remaining on 200 mesh sieve. According to GB / T17671-1999 cement mortar strength test method, the flexural strength of 3 days and 28 days is 2.1MPa and 4.1MPa respectively, and the compressive strength of 3 days and 28 days is 11.8MPa and 25.6MPa respectively.

Embodiment 2

[0047] Silicon-rich body composition: 65 parts of natural rock 3, 30 parts of mine tailings, 5 parts of caustic soda, milled with a small test ball for half an hour to a fully uniform powder, kept at 950°C for 2 hours, then taken out and quickly cooled in the air. Add 25% slaked lime and 40% natural gypsum to the cooling material and ball mill for 35 minutes to get cement. Fineness: 7% remaining on 200 mesh sieve. According to GB / T17671-1999 cement mortar strength test method, the 3-day and 28-day flexural strengths are 3.2MPa and 5.8MPa respectively, and the 3-day and 28-day compressive strengths are 17.5MPa and 31.5MPa respectively.

Embodiment 3

[0049] 96 parts of natural rock 2 and 4 parts of caustic soda were mixed with a small test ball mill for half an hour to a fully uniform powder, and then taken out after 3 hours of heat preservation at 600 ° C and quickly cooled in the air. Add 30% slaked lime and 20% natural gypsum to the cooling material and ball mill for 35 minutes to get cement. Fineness: 4% remaining on 200 mesh sieve. According to GB / T17671-1999 cement mortar strength test method, the flexural strength of 3 days and 28 days is 4.7MPa and 7.4MPa respectively, and the compressive strength of 3 days and 28 days is 24.5MPa and 44.6MPa respectively.

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Abstract

The invention discloses a calcium-poor and silicon-rich ecological cement and application thereof. The cement is prepared from a silicon-rich body and a calcium-rich body in a mixing mode. The silicon-rich body is obtained by adding a small amount of alkali metal salt into a wide-source silicon-aluminum material and then carrying out low-temperature calcination, and the calcium-rich body is composed of a raw material releasing Ca(OH)2 when hydrated and a raw material containing CaSO4. Compared with portland cement, the calcium-poor and silicon-rich ecological cement is good in early strength property, and the long-term strength can meet most use requirements; the raw materials of the calcium-poor and silicon-rich ecological cement are easy to obtain, and carbon emission, energy consumption, pollution and the like are substantially reduced; furthermore, a large quantity of solid industrial residues can be consumed, and the calcium-poor and silicon-rich ecological cement has important economic and social value.

Description

technical field [0001] The invention belongs to the field of ecological gelling materials and applications thereof, and in particular relates to a calcium-poor silicon-rich ecological cement and applications thereof. Background technique [0002] Since the British J. Asputin applied for the patent of Portland cement (called Portland cement in my country) in 1824, the application of this cement has been greatly developed in the past 200 years. The industry chain based on it is extremely complete and huge, especially the concrete related technology based on Portland cement as the cementitious material is developing rapidly. First of all, the improvement of production equipment has greatly improved the production efficiency of cement and reduced the production cost; secondly, the development of mixed materials and admixture technology has not only reduced the cost of cement concrete and carbon emissions, but also made full use of industrial waste. Comprehensive performance in ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/06C04B7/147
CPCC04B7/06C04B7/147C04B7/04Y02P40/10
Inventor 彭美勋李隆江唐宇成呼琳琳陈翔周旋肖秋国张欣申少华
Owner HUNAN UNIV OF SCI & TECH
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