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A compound and a polymer material using it

A technology of polymer materials and compounds, which is applied in the fields of compounds of Group 5/15 elements of the periodic table, organic chemistry, chemical instruments and methods, etc., and can solve problems such as high heat distortion temperature

Active Publication Date: 2018-03-06
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, phosphate esters have not been able to meet the requirements of low viscosity when processing engineering plastics and high heat distortion temperature when using them.

Method used

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  • A compound and a polymer material using it
  • A compound and a polymer material using it
  • A compound and a polymer material using it

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0073] Preparation of 3,3-bis(4-hydroxyphenyl)benzalkrolactam :

[0074] The chemical structural formula of 3,3-bis(4-hydroxyphenyl)benzalkolactam is formula VII-OH.

[0075] Add 63.6g of phenolphthalein and 550g of ammonia water into a three-necked flask with a condenser and a stirrer. The color of the solution is dark purple. Stir at room temperature for 7 days until the color of the solution turns pink, and then pour it into 1000ml of 3.7% dilute hydrochloric acid In the solution, a large amount of solids were precipitated, and the pH was adjusted to about 7 again, filtered, washed with water, and vacuum-dried at 80° C. to constant weight to obtain 60.23 g of pink powdery solids with a yield of 95%. pass 1 H NMR analysis gave 3,3-bis(4-hydroxyphenyl)benzalkrolactam.

[0076] Preparation of 3,3-bis(4-hydroxyphenyl)benzalactam bis(phenoxyphosphate)

[0077] Add 80ml of deionized water, 4g (0.1mol) of sodium hydroxide and 15.9g of 3,3-bis(4-hydroxyphenyl) benzalkolactam...

Embodiment 2

[0082]Add phenolphthalein (7.95g, 0.025mol), resorcinol (7.80g, 0.075mol), triethylamine (20.2g, 0.2mol), 1-methylimidazole into a three-necked flask equipped with a condenser and a stirrer 0.25g, 150ml of dichloromethane, mixed and stirred for 0.5h, dropwise added phenyl dichlorophosphate (21.95, 0.105mol), controlled the rate of addition, dropped after 2h, then continued to react for 3h, added phenol (0.94g, 0.010mol) , continue to react overnight. After the reaction, add 300ml of deionized water, stir for 0.5h, adjust the pH of the water phase to about 7, separate the organic phase, pour it into 500ml of petroleum ether to obtain a fibrous sticky solid, dry it in vacuum at 100°C to obtain a transparent glass Solid phenolphthalein / resorcinol / phenyl dichlorophosphate ternary co-condensation polymer, denoted as sample 2 # .

[0083] sample 2 # The chemical structure formula is:

[0084]

[0085] That is, in formula I: n, m, s=1; y / x=3; R 11 , R 12 , R 13 , R 14 and ...

Embodiment 3

[0087] Add phenolphthalein (15.9g, 0.050mol), resorcinol (0.52g, 0.050mol), triethylamine (20.2g, 0.2mol) and 1-methylimidazole into a three-necked flask equipped with a condenser and a stirrer 0.25g, 150ml of dichloromethane, mixed and stirred for 0.5h, dropwise added phenyl dichlorophosphate (21.95g, 0.105mol), controlled the rate of addition, 2h dripped, then continued to react for 3h, added phenol (0.94g, 0.010mol ), and continue to react overnight. After the reaction, add 300ml of deionized water, stir for 0.5h, adjust the pH of the water phase to about 7, separate the organic phase, pour it into 500ml of petroleum ether to obtain a fibrous sticky solid, dry it in vacuum at 100°C to obtain a transparent glass Solid phenolphthalein / resorcinol / phenyl dichlorophosphate ternary co-condensation polymer, denoted as sample 3 # .

[0088] sample 3 # The chemical structure formula is:

[0089]

[0090] That is, in formula I: n, m, s=1; y / x=1; R 11 , R 12 , R 13 , R 14 a...

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Abstract

The invention discloses a polyphosphate compound containing a phenolphthalein derivative and a high polymer material applying the same. The polyphosphate compound containing the phenolphthalein derivative has high thermal stability and can serve as a viscosity reducer and a fire retardant; and when the polyphosphate compound containing the phenolphthalein derivative is applied to the high polymer material, processing viscosity of engineering plastic can be greatly reduced, thermal properties of the macromolecular material are also better reserved, and a good fire retardant effect is also realized.

Description

technical field [0001] The application relates to a compound with flame retardancy and a polymer material using it, belonging to the field of polymer materials. Background technique [0002] Flame-retardant polymer materials, especially glass fiber reinforced polyamide, polyester PBT, high-temperature nylon and polycarbonate, are widely used in the manufacture of electrical sockets, connectors, relays and other small electronic components in the electronics and electrical industry. Traditionally, the flame retardancy of polymer materials is realized by brominated flame retardants, but brominated flame retardants can produce strong carcinogenic dioxins when burned, and the hydrogen bromide produced at the same time can cause secondary pollution, so In recent years, the use of brominated flame retardants has been gradually restricted, and the flame retardant of polymer materials has turned to halogen-free flame retardants. Among them, bisphosphate or oligophosphate flame reta...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08K5/521C08L69/00C08L85/02C08L67/02C08K7/14C07F9/572
CPCC07F9/5728C08G79/04C08K5/521C08L67/02C08L69/00C08L2201/02C08L85/02C08K7/14
Inventor 姚强黄铠
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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