High-nuclear zinc cluster compound based on sulfur-containing triazole ligand and preparation method thereof
A technology of clusters and triazoles, which is applied in the field of complex synthesis, can solve the problems of difficulty in obtaining single crystals, low solubility of complexes, and easy precipitation, etc., and achieve the effect of improving solubility and wide application prospects
Inactive Publication Date: 2016-07-13
GUANGXI NORMAL UNIV
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The invention discloses a high-nuclear zinc cluster compound based on a sulfur-containing triazole ligand and a preparation method thereof. According to the molecular structural graph, the high-nuclear zinc cluster compound is the 3-thioketone-5-mercapto methyl-1,2,4-triazole 24-nuclear zinc cluster compound. In the preparation process, by the adoption of the method of adding the second kind of metal salt cadmium nitrate, the solubleness of the indissolvable sulfur-containing triazole cluster compound is improved; the zinc cluster compound has the potential application value in the aspects of modern medicine, optics, magnetics, and ion selective absorption and separation. The method has the wide application prospect in the aspect of preparation of indissolvable cluster compound monocrystals.
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