High-nuclear zinc cluster compound based on sulfur-containing triazole ligand and preparation method thereof
A technology of clusters and triazoles, which is applied in the field of complex synthesis, can solve the problems of difficulty in obtaining single crystals, low solubility of complexes, and easy precipitation, etc., and achieve the effect of improving solubility and wide application prospects
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Example Embodiment
[0016] Example
[0017] Synthesis of high nuclear zinc cluster based on sulfur-containing triazole ligand:
[0018] Weigh 0.2mmol (0.0294g) H 3 L, 0.2mmol (0.0745g) Zn(ClO 4 ) 2 ·6H 2 O,0.2mmol(0.0617g)Cd(NO 3 ) 2 ·4H 2 O was mixed in 10 mL of DMF, the resulting mixture was stirred and reacted at room temperature for 6 hours, and then filtered to obtain a colorless solution. The filtrate was allowed to stand and volatilized slowly. After 25 days, colorless cubic crystals were separated from the mother liquor, which was separated, washed, and dried.
[0019] See figure 1 In the molecular structure diagram of the zinc cluster compound of the present invention, for the convenience of observation, the peripheral guest solvent molecules are deleted. It can be clearly observed from the figure that the zinc cluster compound of the present invention is a 24-core double-layer cyclic cluster compound composed of twenty-four zinc ions, twenty-four ligands and six coordinated water molecules. ...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap