A compound that selectively recognizes mercury ions and its preparation method and application
A compound and selective technology, applied in organic chemistry, fluorescence/phosphorescence, instruments, etc., can solve the problems of time-consuming, labor-intensive, application limitations, low-level purification process, etc., to achieve non-toxic by-product formation, convenient and fast operation, and purification operation simple effect
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0044] like figure 1 As shown, the preparation method of the compound that selectively recognizes mercury ions in the embodiment of the present invention includes the following steps:
[0045] S01: providing a first solution, wherein the first solution comprises a rhodamine compound dispersed in a first solvent;
[0046] S02: heating the first solution to reflux, mixing and reacting the first solution with a hydrazine hydrate solution, cooling, and purifying the product to obtain rhodamine hydrazide;
[0047] S03: providing a second solution, wherein the second solution comprises the rhodamine hydrazide dispersed in a second solvent;
[0048] S04: heating the second solution to reflux, mixing the second solution with Lawson's reagent, and removing the second solvent after reacting in an inert gas atmosphere, and separating sulfur hydrazide;
[0049] S05: providing a third solution, wherein the third solution comprises the sulfur hydrazide dispersed in a third solvent;
[00...
Embodiment 1
[0056] Example 1 of the present invention is a method for preparing a compound that selectively recognizes mercury ions, comprising the steps of: dissolving rhodamine B in an appropriate amount of ethanol, heating up to reflux, adding hydrazine hydrate (the molar ratio of rhodamine B to hydrazine hydrate is 1:20) Solution, after the reaction is complete, cool to room temperature, wash and purify the product to obtain rhodamine B hydrazide; dissolve rhodamine B hydrazide in an appropriate amount of toluene, heat up to reflux, add Lawson's reagent (the molar ratio of rhodamine B hydrazide to Lawson's reagent is 1 : 1), after reacting under nitrogen atmosphere, rotary evaporation removes solvent, and column chromatography separates sulfur hydrazide; Measure 15mL ethanol and dissolve 100mg (0.2mmol) sulfur hydrazide, heat up to reflux, add 26.7mg (sulfur hydrazide and para The molar ratio of phthalaldehyde is 1:1) terephthalaldehyde, catalyzed by 120 μL glacial acetic acid (1.8 mmol)...
Embodiment 2
[0060] Embodiment 2 of the present invention The preparation method of the compound that selectively recognizes mercury ions comprises the following steps: dissolving rhodamine B in an appropriate amount of ethanol, heating up to reflux, adding hydrazine hydrate (the molar ratio of rhodamine B to hydrazine hydrate is 1:20) Solution, after the reaction is complete, cool to room temperature, wash and purify the product to obtain rhodamine B hydrazide; dissolve rhodamine B hydrazide in an appropriate amount of toluene, heat up to reflux, add Lawson's reagent (the molar ratio of rhodamine B hydrazide to Lawson's reagent is 1 : 1), after reaction under nitrogen atmosphere, rotary evaporation removes solvent, and column chromatography separates sulfur hydrazide; Measure 15mL ethanol dissolving 100mg (0.2mmol) sulfur hydrazide, heat up to reflux, add 13.4mg (sulfur hydrazide and para The molar ratio of phthalaldehyde is 2:1) terephthalaldehyde, catalyzed by 80 μL glacial acetic acid (...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com