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Preparation method of mg-based hydrogen storage nanowires

A nanowire and hydrogen storage technology, which is applied in the field of preparation of Mg-based hydrogen storage nanowires, can solve problems such as unsafe thermal insulation materials and low-temperature devices, and achieves improved hydrogen storage capacity, a large amount of hydrogen storage, and changes in the preparation process. Effect

Active Publication Date: 2019-08-27
中盛鑫控股有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The usual way to store hydrogen is to compress it and store it in a high-pressure container or store it in a heat-insulated container after liquefaction. However, this means that it is very unsafe or requires good heat insulation materials and low-temperature devices, and it can only be used in special occasions.

Method used

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  • Preparation method of mg-based hydrogen storage nanowires
  • Preparation method of mg-based hydrogen storage nanowires
  • Preparation method of mg-based hydrogen storage nanowires

Examples

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preparation example Construction

[0018] figure 1 It is a flow chart of the preparation method of the Mg-based hydrogen storage nanowire according to the embodiment of the present invention. As shown in the figure, the preparation method of Mg-based hydrogen storage nanowires includes the following steps:

[0019] Step 101: preparing metal Mg, metal Ce, metal La, metal Gd, metal Li and metal Ni;

[0020] Step 102: batching according to a predefined chemical formula;

[0021] Step 103: Vacuum smelting metal Mg, metal Ce, metal La, metal Gd, metal Li and metal Ni prepared according to a predefined chemical formula to obtain a Mg-based alloy ingot;

[0022] Step 104: placing the Mg-based alloy ingot in the crucible, and then melting the Mg-based alloy ingot in the crucible;

[0023] Step 105: using a high-speed airflow to spray the molten Mg-based alloy droplets flowing from the nozzle of the crucible to obtain Mg-based alloy powder;

[0024] Step 106: performing heat treatment on the Mg-based alloy powder; ...

Embodiment 1

[0031] The preparation method of the Mg-based hydrogen storage nanowire of the present invention comprises the following steps: preparing metal Mg, metal Ce, metal La, metal Gd, metal Li and metal Ni; carrying out batching according to a predefined chemical formula; carrying out the preparation according to the predefined chemical formula The metal Mg, metal Ce, metal La, metal Gd, metal Li and metal Ni of the ingredients are vacuum smelted to obtain a Mg-based alloy ingot; the Mg-based alloy ingot is placed in a crucible, and then the Mg-based alloy ingot in the crucible is melted; Using high-speed airflow to spray the molten Mg-based alloy droplets flowing out from the nozzle of the crucible to obtain Mg-based alloy powder; heat-treating the Mg-based alloy powder; ball milling the heat-treated Mg-based alloy powder to obtain ball-milled Mg-based alloy powder Dissolve PAN in DMF to obtain a PAN spinning solution, wherein the PAN concentration is 10wt%; dissolve the Mg-based al...

Embodiment 2

[0033] The preparation method of the Mg-based hydrogen storage nanowire of the present invention comprises the following steps: preparing metal Mg, metal Ce, metal La, metal Gd, metal Li and metal Ni; carrying out batching according to a predefined chemical formula; carrying out the preparation according to the predefined chemical formula The metal Mg, metal Ce, metal La, metal Gd, metal Li and metal Ni of the ingredients are vacuum smelted to obtain a Mg-based alloy ingot; the Mg-based alloy ingot is placed in a crucible, and then the Mg-based alloy ingot in the crucible is melted; Using high-speed airflow to spray the molten Mg-based alloy droplets flowing out from the nozzle of the crucible to obtain Mg-based alloy powder; heat-treating the Mg-based alloy powder; ball milling the heat-treated Mg-based alloy powder to obtain ball-milled Mg-based alloy powder Dissolve PAN in DMF to obtain a PAN spinning solution, wherein the PAN concentration is 15wt%; dissolve the Mg-based al...

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Abstract

The invention provides a method for preparing Mg-based hydrogen storage nanowires, comprising the following steps: preparing metal Mg, metal Ce, metal La, metal Gd, metal Li and metal Ni, and performing batching and vacuum melting to obtain a Mg-based alloy ingot ; Atomize the Mg-based alloy ingot to obtain Mg-based alloy powder; heat-treat the Mg-based alloy powder; ball mill the heat-treated Mg-based alloy powder to obtain the ball-milled Mg-based alloy powder; dissolve PAN in DMF In the process, the PAN spinning solution is obtained, wherein the PAN concentration is 10-15wt%; the Mg-based alloy powder that has been heat-treated but not ball-milled is dissolved in the PAN spinning solution to obtain the first spinning solution; the ball-milled The Mg-based alloy powder is dissolved in the PAN spinning solution to obtain a second spinning solution; and the first spinning solution and the second spinning solution are formed into Mg-based hydrogen storage nanowires by coaxial electrospinning. The invention proposes a new method for preparing a hydrogen storage material. The alloy prepared by the method of the invention has a larger total amount of hydrogen storage and a faster rate of hydrogen absorption and desorption.

Description

technical field [0001] The invention belongs to the technical field of hydrogen energy utilization, and relates to a preparation method of Mg-based hydrogen storage nanowires. Background technique [0002] With the depletion of fossil energy and the increasingly serious pollution caused by combustion, finding clean and sustainable energy is a problem related to human survival and development. Hydrogen has become an important energy source in the 21st century. A consensus. Hydrogen is regarded as the best substitute for fossil fuels because in comparison, hydrogen energy is rich in resources (more than 70% of the earth's surface is covered by water); clean and environmentally friendly (using low-temperature fuel cells to convert hydrogen through electrochemical reactions There is no pollution in the process of generating electric energy and water); renewable (hydrogen generates electric energy or heat energy by chemical reaction and generates water, and water can be converte...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/02C22C23/06B22F9/08B22F9/04B22F9/06B82Y40/00
CPCC22C1/02C22C23/06B82Y40/00B22F9/04B22F9/06B22F9/082B22F2009/043B22F2998/10B22F1/142
Inventor 康丽纳
Owner 中盛鑫控股有限公司
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