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Fluidized bed reactor, application thereof and hydrocarbon oil desulfurization method

A fluidized bed reactor and reactor technology are applied in the fields of fluidized bed reactors and gasoline adsorption desulfurization, which can solve problems such as affecting the stable operation of the device and being unable to discharge the reactor, simplifying the structure design of the device, reducing the crushing effect, good economic effect

Active Publication Date: 2020-04-28
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the fluidized adsorption reactor, the fine powder of the catalyst and the fine powder produced by the long-term wear of the particles will be elucidated into the sedimentation space of the fluidized bed for long-term suspension, so that the suspended particles have no chance to return to the dense bed of the fluidized bed , and cannot be discharged from the reactor, which will affect the stable operation of the device in the long run

Method used

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  • Fluidized bed reactor, application thereof and hydrocarbon oil desulfurization method
  • Fluidized bed reactor, application thereof and hydrocarbon oil desulfurization method
  • Fluidized bed reactor, application thereof and hydrocarbon oil desulfurization method

Examples

Experimental program
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Effect test

Embodiment 1

[0089] use as figure 1 The structure of the fluidized bed reactor shown is as follows: a partition member is provided in the settling zone of the reactor, the inclination angle of the baffle plate 15 is 60°, and the opening cross section of the partition member is circular. The upper part of the settling zone is equipped with a metal filter tube filter, and the lower space of the settling section is not equipped with a gas-solid separation device. There are two delivery pipes and fluid guiding structures entering the upper settling space, which are evenly distributed along the circumference, and the nozzle of the delivery pipe 8 protrudes from the partition member 14 at a distance of 200 mm. The height-to-width ratio of the outlet channel opening of the fluid-guiding structure is 3:1, the ratio of the radius of the outer wall of the outlet channel to the radius of the settlement area is 0.9, and the outlet normal direction of the outlet channel is in the radial direction of th...

Embodiment 2

[0096] Embodiment 2 adopts attached figure 1 The fluidized bed reactor shown is different from Example 1 in that the ratio of the outer edge radius R1 of the arc-shaped outlet channel to the upper space of the reactor settling section is 0.6, and the outlet normal direction of the outlet channel and the arc-shaped channel The included angle a of the circle tangent at the exit with the center of the radial section of the settlement space as the center is 8°, and the outer circumference of the exit channel is 600mm. The ratio of the cross-sectional area of ​​the delivery pipe 8 to the cross-sectional area of ​​the settlement zone is 0.025. The outlet gas velocity of the fluid guiding structure 9 is 6m / s.

[0097] Reaction method, sulfur-containing hydrocarbon oil raw material, reaction conditions are the same as embodiment 1.

[0098] The device runs continuously for 500 hours. During the reaction process, the following indicators were monitored: (1) filter pressure drop; (2)...

Embodiment 3

[0102] Embodiment 3 adopts as attached figure 2 In the fluidized bed reactor shown, the settling area of ​​the reactor is provided with a partition member, the partition member is a quasi-conical shape formed by 9 small cones and its material legs, and the included angle between the dividing plate 15 and the horizontal plane constituting the partition member is 45°, the opening cross-section of each partition member is an irregular polygon. The upper part of the settling area is provided with a metal filter tube filter 13, and there are three conveying pipes and fluid guide outlet structures entering the upper settling space, which are evenly distributed along the circumference. The aspect ratio of the opening of the outlet channel of the fluid guide outlet structure 9 is 4:1, and the ratio of the radius of the surrounding plate outside the outlet channel to the radius of the settlement zone is 0.9. The angle a between the outlet normal of the arc-shaped outlet passage and t...

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Abstract

The invention discloses a fluidized bed reactor and application thereof, and a hydrocarbon oil desulfurization method. The fluidized bed reactor comprises a reaction section (3) at the lower portion and a settling section at the upper portion, wherein the settling section is divided into a settling section upper space and a settling section lower space by a separation component (14), the separation component (14) is composed of a cone-like body and a discharging pipe (17), the cone skirt edge on the top is seamlessly connected with the reactor wall, a fluid guide structure (9) is arranged in the settling section upper space, penetrates through the separation component (14) through a conveying pipe (8) and is opened in the settling section upper space, the bottom of the discharging pipe (17) of the separation component (14) is opened in the reaction section (3), and a gas outlet is formed in the top of the settling section upper space through a filter. According to the fluidized bed reactor provided by the invention, separated catalyst fine powder particles can be timely conveyed to the dense-phase bed layer of a reactor, so that the suspension amount of the catalyst particles in the settling zone of the fluidized bed reactor is remarkably reduced, and the operation period of the device is prolonged.

Description

technical field [0001] The invention relates to a fluidized bed reactor in the field of oil refining and chemical industry and an application method thereof, more specifically, to a fluidized bed reactor and a gasoline adsorption desulfurization method using the fluidized bed reactor. Background technique [0002] With the continuous improvement of environmental protection requirements, the indicators of gasoline sulfur content are becoming increasingly stringent. This puts forward higher requirements for gasoline desulfurization technology. The fluidized bed gasoline desulfurization process is an important gasoline desulfurization process. [0003] CN1658965A proposes a method and device for desulfurization from hydrocarbon-containing fluid, wherein the desulfurization is enhanced by improving the contact between hydrocarbon-containing fluid and sulfur-absorbing solid particles in a fluidized bed reactor. The reactor adopts a fluidized bed reactor. From bottom to top, the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J8/24C10G25/09C10G53/08
CPCB01J8/1872B01J8/24C10G25/09C10G53/08C10G2300/1037C10G2300/104C10G2300/1044C10G2300/202C10G2300/70C10G2400/02
Inventor 朱丙田侯栓弟毛俊义朱振兴毛安国张同旺刘凌涛韩颖
Owner CHINA PETROLEUM & CHEM CORP
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