3D-printing composite material with fragrance and antibacterial property, preparation method and application thereof

A technology of 3D printing and composite materials, applied in the field of new materials and new processing of polymer materials, can solve the problems of poor compatibility of fragrance-type composite materials, limited categories and product forms, and few reports on preparation methods, and achieve fragrance retention time. Long-lasting, process formulation optimization, and compatibility problem-solving effects

CN108912632AInactive Publication Date: 2018-11-30GUANGZHOU FEISHENG HIGH POLYMER MATERIAL CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Publication Date
2018-11-30
Estimated Expiration
Not applicable · inactive patent

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Abstract

The invention discloses a 3D-printing composite material with fragrance and antibacterial property, a preparation method and an application thereof. The 3D-printing composite material is prepared fromthe following components in parts by weight: 40-97 parts of high-molecular polymer, 0.2-55 parts of spice agent, 0.1-5 parts of antibacterial agent, 0.2-5 parts of plasticizing additive, 0.5-10 partsof organic additive, 0.5-5 parts of dispersing agent, 0.05-1 part of antioxidant and 0-1 part of pigment powder. The 3D-printing composite material disclosed by the invention has the beneficial effects that the fragrance with multiple types of fragrances is achieved, the original odor of plastics can be effectively covered or reduced, the antibacterial property and the mechanical property are good, and the types and manufacturing processes of materials in the technical field of 3D printing are enriched; in addition, the 3D-printing composite material is non-toxic and harmless, waste materialscan be naturally biodegraded and also can be recycled, so that the economic cost is lower relatively.
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Description

technical field

[0001] The invention belongs to the technical field of new materials and new processing of polymer materials, and specifically relates to a 3D printing composite material with fragrance and antibacterial properties, a preparation method and an application thereof. Background technique

[0002] 3D printing technology is a rapid prototyping manufacturing technology that is gradually developing. It is a precise and personalized rapid prototyping technology. advantage. Its basic principle is mainly based on polymer materials, using fused deposition modeling technology, and completing the construction and formation of object models by layer-by-layer printing and accumulation.

[0003] At present, polylactic acid (PLA), polyacrylonitrile-polybutadiene-polystyrene terpolymer (ABS), polyurethane (TPU), and wood fiber wire (WOOD) are widely used in the market. Ordinary plastics, there are also some engineering plastics such as polycarbonate (PC), nylon (PA) and so o...

Examples

Embodiment 1

[0047]

[0048] refer to figure 1 The technological process, first 0.1 weight part of antioxidant 1010, 0.05 weight part of antioxidant 168, 0.2 weight part of rose fragrance type solid fragrance, 0.5 weight part of hydrophobic silicon dioxide and 1.0 weight part of titanium dioxide are added to the high-speed The mixer is pre-mixed and mixed evenly to obtain a flavor pre-mix; wherein the pre-mix speed of the high-speed mixer is 300r / min, the pre-mix time is 1min, and the pre-mix temperature is 30°C; then 95.95 parts by weight of polyethylene glycol Lactone and 1.0 parts by weight of methyl silicone oil are added to a high-speed mixer with a premixing speed set at 500r / min, a premixing time set at 1min, and a premixing temperature of 40°C for premixing to obtain a high-molecular polymer diffusing agent Mixture; then 0.2 parts by weight of nano-zinc oxide microparticles, 0.2 parts by weight of stearic acid amide and 0.8 parts by weight of rosin are added to the high-speed mi...

Embodiment 2

[0050]

[0051] First, 0.1 parts by weight of antioxidant 1010, 0.05 parts by weight of antioxidant 168, 1.0 parts by weight of rose fragrance type solid fragrance, 0.5 parts by weight of hydrophobic silicon dioxide and 1.0 parts by weight of titanium dioxide are added to a high-speed mixer for pre-treatment. Mix and mix evenly, and obtain the fragrance premix; wherein the premix speed of the high-speed mixer is 300r / min, the premix time is 1min, and the premix temperature is 30°C; then 95.15 parts by weight of polycaprolactone, 1.0 Add the methyl silicone oil in parts by weight to a high-speed mixer whose premixing speed is set to 500r / min, the premixing time is set to 1min, and the premixing temperature is 40°C to premix evenly to obtain a polymer diffusing agent mixture; 0.2 parts by weight of nano-zinc oxide microparticles, 0.2 parts by weight of stearic acid amide and 0.8 parts by weight of rosin are added to the high-speed mixer and pre-mixed again with the polymer dif...

Embodiment 3

[0053]

[0054] First, 0.1 parts by weight of antioxidant 1010, 0.05 parts by weight of antioxidant 168, 2.0 parts by weight of rose fragrance type solid fragrance, 0.5 parts by weight of hydrophobic silicon dioxide and 1.0 parts by weight of titanium dioxide are added to a high-speed mixer for pre-treatment. Mix and mix evenly, and obtain the fragrance premix; wherein the premix speed of the high-speed mixer is 300r / min, the premix time is 1min, and the premix temperature is 30°C; then 94.15 parts by weight of polycaprolactone, 1.0 Add the methyl silicone oil in parts by weight to a high-speed mixer whose premixing speed is set to 500r / min, the premixing time is set to 1min, and the premixing temperature is 40°C to premix evenly to obtain a polymer diffusing agent mixture; 0.2 parts by weight of nano-zinc oxide microparticles, 0.2 parts by weight of stearic acid amide and 0.8 parts by weight of rosin are added to the high-speed mixer and pre-mixed again with the polymer dif...