The invention discloses a jewellery rose 
gold surface treatment plating solution, a preparation method and an 
electroplating method thereof. The preparation method comprises the following steps: weighing and pouring about 1 g of 
copper sulphate, about 120 g of 
ammonium sulphite, about 40 g of EDTA-2Na and about 100 g of 
potassium citrate into a 
beaker of 1L; then, adding 600 ml of water for diluting and dissolving, adding a stirring bar, placing the 
beaker in a heat collection type constant temperature heating 
magnetic stirrer, and heating and stirring the 
beaker for 40 minutes; taking out the beaker, and adding diamminedichloropalladium and 
sodium gold sulphite, wherein the 
palladium content of the diamminedichloropalladium is about 6 g, and the 
gold content of the 
sodium gold sulphite is about 10 g; adding water to about 950 ml, placing the beaker into the heat collection type constant temperature heating 
magnetic stirrer again, heating and stirring for 15 minutes, taking out the beaker, and filtering the solution; testing the acidity and 
alkalinity of the filtered solution by using PH paper with the specification of 6 to 9, wherein when the PH value is 8, the solution is the plating solution; if the PH value is less than 8, taking 
ammonia water by using a plastic cap dropper, adding half of the plastic cap dropper of the 
ammonia water, stirring for 2 to 3 minutes by using a glass rod, and testing the PH value again until the obtained PH value is 8; adding pure water to complement the solution to 1L to obtain the plating solution.