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Acid-free kaolin bleaching process method

A process method and kaolin technology, applied in the direction of aluminum silicate, silicate, etc., can solve problems such as unfavorable long-term development of kaolin processing industry, unfavorable kaolin application, environmental impact, etc.

Inactive Publication Date: 2011-04-20
茂名市银华高岭土实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In the technical scheme of the above-mentioned Chinese invention patent application, although the amount of acid used in the entire bleaching process is reduced compared with the amount of acid used in the acid bleaching method, it is still necessary to add sulfuric acid or other acids in the entire bleaching process. It not only affects the quality of kaolin products, but also has a certain impact on the environment; at the same time, due to Fe 2+ It is necessary to ensure that it is relatively stable under acidic conditions and is not easily oxidized into Fe 3+ , under this condition, because kaolin products contain excessive sulfuric acid and sulfate, etc., the viscosity of kaolin will increase, which is not conducive to the application of kaolin. This will inevitably lead to an increase in production costs, and the particle size of kaolin is relatively small, and the dehydration process of kaolin products after washing is also relatively difficult, which not only increases the process steps, but also directly increases production costs, which is not conducive to the long-term development of the kaolin processing industry.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] One of the specific implementations of a kaolin acid-free bleaching process of the present invention comprises the following steps:

[0031] Step 1, mixing in medicament: adding hydrosulfite to the desanded and classified weakly alkaline kaolin slurry, stirring and mixing until uniform, to obtain the first slurry of kaolin slurry.

[0032] Step 2, static bleaching, the first slurry of kaolin slurry in step 1 is placed in a slurry storage device to stand still, and a sufficient bleaching reaction is carried out to obtain a second slurry of kaolin slurry. Wherein, the slurry storage device is specifically a slurry storage tank. The main reaction of the bleaching process of above-mentioned steps is: . Fe present in kaolin slurry 3+ Oxides, in hydrosulfite (ie sodium dithionate Na 2 S 2 o 4 ) under the condition of existence, after stirring and reacting for a period of time, the colored Fe in kaolin 3+ reduced to Fe 2+ .

[0033] Step 3, ion exchange, place the se...

Embodiment 2

[0041] The second specific embodiment of a kind of kaolin acid-free bleaching process of the present invention, the main technical scheme of this embodiment is the same as that of embodiment 1, and the features not explained in this embodiment adopt the explanation in embodiment 1, in This will not be repeated here. The difference between this embodiment and embodiment 1 is that the solid ion exchanger added in step 3 can be a cation exchange resin.

[0042] Specifically, step 3 is ion exchange. Put the second slurry of kaolin slurry in step 2 in the stirring device, add cation exchange resin, and stir slowly. Fe in two slurry 2+ Perform ion exchange to obtain the third slurry of kaolin slurry. Cationic exchange resin was used to remove Fe in kaolin slurry solution 2+ Exchanged to the cationic resin, instead of the role of acid, remove Fe 2+ , and effectively prevent Fe 2+ Oxidized to Fe 3+ , and the phenomenon of "returning yellow" of kaolin products appears, to achieve...

Embodiment 3

[0047] The third specific embodiment of a kind of kaolin acid-free bleaching process of the present invention, the main technical scheme of this embodiment is the same as that of embodiment 1, and the features not explained in this embodiment adopt the explanation in embodiment 1, in This will not be repeated here. The difference between this embodiment and embodiment 1 is that after step four, step five is further included to adsorb Fe 2+ Regeneration of the solid ion exchanger: the separated adsorbed Fe 2+ The solid ion exchanger of the solid ion exchanger is added with regeneration agent, and is reduced to the solid ion exchanger in step 3.

[0048] After the solid ion exchanger has been used for a period of time, it needs to be regenerated, that is, the regeneration agent is used to make the ion exchange reaction proceed in the opposite direction, so that the functional groups of the ion exchanger can restore their ability to exchange ions with water, so that they can be ...

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Abstract

The invention discloses an acid-free kaolin bleaching process method, comprising the following steps of: chemical agent mixing: adding rongalite into desanded and graded alkalescent kaolin ore pulp, stirring and mixing evenly to obtain the first sizing agent of the kaolin ore pulp; static bleaching: putting the first sizing agent of the kaolin ore pulp into a pulp storage device and standing still, fully bleaching and reacting to obtain the second sizing agent of the kaolin ore pulp; ion exchange: putting the second sizing agent of the kaolin ore pulp into an ion exchange dasher, and adding solid exchanger, slowly stirring for ion exchange to obtain the third sizing agent of the kaolin ore pulp; solid-liquid separation: putting the third sizing agent of the kaolin ore pulp into a solid-liquid separation device, separating solid ion exchanger capable of adsorbing Fe2+ in the third sizing agent of the kaolin ore pulp so as to obtain separated kaolin ore pulp. The acid-free kaolin bleaching process method has the characteristics of simple processstrong practicality, low cost and environment friendly, is easy for operation and safe and realizes the purpose of acid-free bleaching.

Description

technical field [0001] The invention relates to a kaolin reduction bleaching process technology, in particular to an acid-free kaolin bleaching process. Background technique [0002] Kaolin is widely used in industries such as ceramics, papermaking, refractory materials, coatings, rubber and cables. The whiteness of kaolin is an important indicator that affects its application value and application field, especially in the papermaking and ceramic industries, which have high requirements for the whiteness of kaolin. Therefore, in order to obtain kaolin products with high whiteness, the bleaching process of kaolin is kaolin processing. A very important craft in craft. [0003] In the prior art, the bleaching process of kaolin usually adopts an acid bleaching method, specifically adjusting the kaolin pulp to acidity with sulfuric acid, and then adding a reducing agentsulfuric acid (chemical name: sodium dithionate, molecular formula: Na 2 S 2 o 4 ), the oxides of ferric ir...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/26
Inventor 王运新
Owner 茂名市银华高岭土实业有限公司
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