Acid-free kaolin bleaching process method
A process method and kaolin technology, applied in the direction of aluminum silicate, silicate, etc., can solve problems such as unfavorable long-term development of kaolin processing industry, unfavorable kaolin application, environmental impact, etc.
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Embodiment 1
[0030] One of the specific implementations of a kaolin acid-free bleaching process of the present invention comprises the following steps:
[0031] Step 1, mixing in medicament: adding hydrosulfite to the desanded and classified weakly alkaline kaolin slurry, stirring and mixing until uniform, to obtain the first slurry of kaolin slurry.
[0032] Step 2, static bleaching, the first slurry of kaolin slurry in step 1 is placed in a slurry storage device to stand still, and a sufficient bleaching reaction is carried out to obtain a second slurry of kaolin slurry. Wherein, the slurry storage device is specifically a slurry storage tank. The main reaction of the bleaching process of above-mentioned steps is: . Fe present in kaolin slurry 3+ Oxides, in hydrosulfite (ie sodium dithionate Na 2 S 2 o 4 ) under the condition of existence, after stirring and reacting for a period of time, the colored Fe in kaolin 3+ reduced to Fe 2+ .
[0033] Step 3, ion exchange, place the se...
Embodiment 2
[0041] The second specific embodiment of a kind of kaolin acid-free bleaching process of the present invention, the main technical scheme of this embodiment is the same as that of embodiment 1, and the features not explained in this embodiment adopt the explanation in embodiment 1, in This will not be repeated here. The difference between this embodiment and embodiment 1 is that the solid ion exchanger added in step 3 can be a cation exchange resin.
[0042] Specifically, step 3 is ion exchange. Put the second slurry of kaolin slurry in step 2 in the stirring device, add cation exchange resin, and stir slowly. Fe in two slurry 2+ Perform ion exchange to obtain the third slurry of kaolin slurry. Cationic exchange resin was used to remove Fe in kaolin slurry solution 2+ Exchanged to the cationic resin, instead of the role of acid, remove Fe 2+ , and effectively prevent Fe 2+ Oxidized to Fe 3+ , and the phenomenon of "returning yellow" of kaolin products appears, to achieve...
Embodiment 3
[0047] The third specific embodiment of a kind of kaolin acid-free bleaching process of the present invention, the main technical scheme of this embodiment is the same as that of embodiment 1, and the features not explained in this embodiment adopt the explanation in embodiment 1, in This will not be repeated here. The difference between this embodiment and embodiment 1 is that after step four, step five is further included to adsorb Fe 2+ Regeneration of the solid ion exchanger: the separated adsorbed Fe 2+ The solid ion exchanger of the solid ion exchanger is added with regeneration agent, and is reduced to the solid ion exchanger in step 3.
[0048] After the solid ion exchanger has been used for a period of time, it needs to be regenerated, that is, the regeneration agent is used to make the ion exchange reaction proceed in the opposite direction, so that the functional groups of the ion exchanger can restore their ability to exchange ions with water, so that they can be ...
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