The invention discloses a method for preparing a
manganese sulfate solution with low manganous
dithionate through desulfuration by using the
slurry prepared by an
anode liquid in electrolytic
manganese production and
manganese ore, and belongs to the field of electrolytic manganese production. According to method, the
slurry prepared by the
anode liquid and the manganese ore is used as a desulfurizing agent, meanwhile, a multi-stage spray washing
tower with a
sieve plate is additionally arranged for
flue gas desulfurization and manganese immersion, after the obtained
slurry is filtered, an
oxidizing agent in the
liquid phase is added to reduce the manganous
dithionate in the slurry, so that the production of the electrolytic manganese and / or manganese
sulfate is facilitate; the
solid-phasesubstance obtained by filtering undergoes secondary acidolysis , and then the
leaching rate of the manganese can be further improved; by adopting the process and the method, the
leaching rate of themanganese can reach more than 94.3%, meanwhile, the high-concentration
sulfur dioxide in the
flue gas is reduced to the value lower than 100mg / m<3>, and the desulfurization efficiency can reach more than 99%; the prepared desulfurized manganese leaching solution is sent to an
electrolysis section for electrolytic manganese production, the average single-shift yield is increased from 2.5kg-2.6kg inthe prior art to 3.1kg-3.2kg; and when the manganese
sulfate solution which is prepared by the method and provided with the low manganous
dithionate is used for electrolytic manganese production, theyield of the manganese can be improved, the plate
loading rate of the manganese can be increased, the quality and the yield of the manganese can be improved, and the
energy consumption and the production cost can be reduced.