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34 results about "Oxido reduction" patented technology

Method for removing chloride ions in copper sulphate solution

The invention relates to an economic method for removing chloride ions in a copper sulphate solution. The method comprises the following steps: adjusting a pH value and oxido reduction potential and adjusting copper sulphate with sodium carbonate and sodium sulfite to a reaction interval where Na2[CuCl3] can stable exist; carrying out heating, adding elemental copper powder, allowing Na2[CuCl3] in the solution and the elemental copper powder to undergo comproportionation so as to produce a white CuCl cuprous salt precipitate insoluble in water; and carrying out full cooling to separate cuprous salt sediment and the copper sulphate solution so as to obtain a dechlorinated copper sulphate solution. The method utilizes the characteristic that wet cuprous salt sediment is not stable under the condition of a high pH value to convert the wet cuprous salt sediment into dechlorinated copper residues consisting of CuO, CuCO3 and Cu(OH)2 and to return the dechlorinated copper residues into a system for reuse, and a produced sodium chloride solution has high concentration and can be directly used for evaporative preparation of industrial NaCl. The method is widely applicable to removal of chloride ions of various concentrations from high-concentration copper sulphate solutions; reagents added for reaction do not influence quality; except cost for heating, operation cost is negligible; and the method is economic and easily practicable.
Owner:SHAANXI RUIKAI ENVIRONMENTAL PROTECTION & TECH CO LTD

Biomass gasification catalytic cracking process and integral gasification catalytic reactor

InactiveCN102807901ARetained fluidized bed technologyAvoid sensible heat lossGranular/pulverulent flues gasificationFluidized bedFixed bed
The invention relates to a biomass gasification catalytic cracking process and an integral gasification catalytic reactor. According to the process, the integral reactor of which the lower part is provided with a biomass gasification section and the upper part is provided with a tar catalytic cracking section is adopted; the biomass gasification section is a fluidized bed, air serving as a primary gasification agent is introduced from the lower part, biomass enters the reactor from the middle-and-lower part to perform oxido-reduction gasification reaction with the gasification agent at the temperature of between 600 and 750 DEG C to generate gas accompanied with tar; the gas accompanied with the tar enters the tar catalytic cracking section on the upper part, the tar catalytic cracking section is a fixed bed into which a tar cracking catalyst is filled, a secondary gasification agent is introduced from the lower lateral part for filling the tar cracking catalyst, and the tar is cracked and converted into small-molecular combustible gas in the tar catalytic cracking section at the catalytic cracking temperature of between 750 and 800 DEG C; and generated ash content is discharged from an ash discharge opening on the lower part of the reactor, and the gas is discharged from a gas outlet on the top of the reactor to enter the next process. By the biomass gasification catalytic cracking process, the problem that the tar is separated from flying ash difficultly in the biomass gasification process is solved, and the gasification efficiency is improved.
Owner:HUAZHONG NORMAL UNIV +1

Purifying method for black and odorous water and sediment nutrient salt

The invention discloses a purifying method for black and odorous water and sediment nutrient salt. The purifying method comprises the following steps: a) carrying out aeration treatment on the surface sediment and the overlying water of the black and odorous water to synchronously reduce the ammonia nitrogen contents of the water and the surface sediment, and meanwhile immobilizing the phosphorus in the water by adsorption; b) carrying out settling treatment on the water subjected to the aeration treatment; and c) repeatedly carrying out the treatments in the steps a) and b) on the water subjected to the settling treatment until the concentration of ammonia nitrogen in the water is lower than a predetermined concentration, keeping the water standing still, and finishing the purification of the water. According to the purifying method provided by the invention, the adding of a chemical agent is not needed, while all that is needed to do is change the position of an aerator on the basis of the traditional aeration to directly oxygenate and aerate the surface sediment, so that the oxido-reduction condition of the sullage-water interface of a black and odorous river channel is effectively improved while water reoxygenation is realized, an oxidizing layer with a certain thickness is formed, the ammonia nitrogen contents of the water and the surface sediment are synchronously reduced, and meanwhile the adsorption immobilization of the phosphorus in the water is realized. After being treated according to the method, the black and odorous water is improved in transparency and reduced in odor strength.
Owner:NANTONG UNIVERSITY +1

Preparation method of amycin controlled-release chitosan nano particles with pH/oxido-reduction dual response

The invention relates to a preparation method of amycin controlled-release chitosan nano particles with pH / oxido-reduction dual response. Thiolated chitosan, carboxymethyl chitosan, sodium tripolyphosphate, doxorubicin hydrochloride and hydrogen peroxide are taken as raw materials. The preparation method comprises the following steps: mixing a thiolated chitosans solution with a doxorubicin hydrochloride solution so as to obtain a solution I; mixing a carboxymethyl chitosan solution with a sodium tripolyphosphate solution so as to obtain a mixed solution II; dropwise adding the mixed solution I into the mixed solution II while stirring, controlling the dosage of carboxymethyl chitosan and thiolated chitosan, regulating the ph value of the solution to 6-8, performing ultrasonic blending, performing ion crosslinking and polymer condensing, then dropwise adding hydrogen peroxide into the system so as to finish oxidization crosslinking, performing room-temperature stirring reaction, separating products, and drying the products to obtain the amycin controlled-release chitosan nano particles with pH / oxido-reduction dual response. The amycin controlled-release chitosan nano particles with pH / oxido-reduction dual response is capable of escaping away from tumor cell endosome / lysosome, is capable of automatically regulating and controlling to realize cytoplast release based on unique microenvironments of tumor cells, improving the amycin medicine delivery efficiency and the medical effect, and has a favorable research and development application background in multiple aspects such as medicine and medical materials.
Owner:OCEAN UNIV OF CHINA

Small-sized device for treating chromate waste water by virtue of automatic pH regulation, oxidoreduction and activated carbon and application thereof

The invention discloses a small-sized device for treating chromate waste water by virtue of automatic pH regulation, oxidoreduction and activated carbon and application thereof. The device is composed of a water inlet pipe, an oxidoreduction region, an absorption region, a water outlet region, a chromium slag discharge pipe, an acid-base and reducing agent feeding pipe and a water discharge pipe, wherein the water inlet pipe is arranged on the top of a reaction device; the water inlet pipe is linked with the oxidoreduction region; the absorption region is located at the outer layer of the oxidoreduction region; the acid-base and reducing agent feeding pipe, a stirrer and a pH detector are arranged on the top of a reactor; the chromium slag discharge pipe is placed at the bottom of the oxidoreduction region; the absorption region is communicated with the oxidoreduction region through a valve; the valve is arranged at the bottom of the absorption region; an activated carbon column is arranged in the absorption region; the water outlet region is located outside the absorption region; and a water outlet pipe is arranged at the bottom of the water outlet region. The chromate waste water passes through the oxidoreduction region and the absorption region and then is removed by virtue of the water outlet region, thereby achieving the effective removal of chromium ions in the chromate waste water.
Owner:HOHAI UNIV

Biomass gasification catalytic cracking process and integral gasification catalytic reactor

InactiveCN102807901BRetained fluidized bed technologyAvoid sensible heat lossGranular/pulverulent flues gasificationFluidized bedFixed bed
The invention relates to a biomass gasification catalytic cracking process and an integral gasification catalytic reactor. According to the process, the integral reactor of which the lower part is provided with a biomass gasification section and the upper part is provided with a tar catalytic cracking section is adopted; the biomass gasification section is a fluidized bed, air serving as a primary gasification agent is introduced from the lower part, biomass enters the reactor from the middle-and-lower part to perform oxido-reduction gasification reaction with the gasification agent at the temperature of between 600 and 750 DEG C to generate gas accompanied with tar; the gas accompanied with the tar enters the tar catalytic cracking section on the upper part, the tar catalytic cracking section is a fixed bed into which a tar cracking catalyst is filled, a secondary gasification agent is introduced from the lower lateral part for filling the tar cracking catalyst, and the tar is cracked and converted into small-molecular combustible gas in the tar catalytic cracking section at the catalytic cracking temperature of between 750 and 800 DEG C; and generated ash content is discharged from an ash discharge opening on the lower part of the reactor, and the gas is discharged from a gas outlet on the top of the reactor to enter the next process. By the biomass gasification catalytic cracking process, the problem that the tar is separated from flying ash difficultly in the biomass gasification process is solved, and the gasification efficiency is improved.
Owner:HUAZHONG NORMAL UNIV +1

A method for removing chloride ions in copper sulfate solution

The invention relates to an economic method for removing chloride ions in a copper sulphate solution. The method comprises the following steps: adjusting a pH value and oxido reduction potential and adjusting copper sulphate with sodium carbonate and sodium sulfite to a reaction interval where Na2[CuCl3] can stable exist; carrying out heating, adding elemental copper powder, allowing Na2[CuCl3] in the solution and the elemental copper powder to undergo comproportionation so as to produce a white CuCl cuprous salt precipitate insoluble in water; and carrying out full cooling to separate cuprous salt sediment and the copper sulphate solution so as to obtain a dechlorinated copper sulphate solution. The method utilizes the characteristic that wet cuprous salt sediment is not stable under the condition of a high pH value to convert the wet cuprous salt sediment into dechlorinated copper residues consisting of CuO, CuCO3 and Cu(OH)2 and to return the dechlorinated copper residues into a system for reuse, and a produced sodium chloride solution has high concentration and can be directly used for evaporative preparation of industrial NaCl. The method is widely applicable to removal of chloride ions of various concentrations from high-concentration copper sulphate solutions; reagents added for reaction do not influence quality; except cost for heating, operation cost is negligible; and the method is economic and easily practicable.
Owner:SHAANXI RUIKAI ENVIRONMENTAL PROTECTION & TECH CO LTD

A preparation method of doxorubicin controlled-release chitosan nanoparticles with ph/redox double response

The invention relates to a preparation method of amycin controlled-release chitosan nano particles with pH / oxido-reduction dual response. Thiolated chitosan, carboxymethyl chitosan, sodium tripolyphosphate, doxorubicin hydrochloride and hydrogen peroxide are taken as raw materials. The preparation method comprises the following steps: mixing a thiolated chitosans solution with a doxorubicin hydrochloride solution so as to obtain a solution I; mixing a carboxymethyl chitosan solution with a sodium tripolyphosphate solution so as to obtain a mixed solution II; dropwise adding the mixed solution I into the mixed solution II while stirring, controlling the dosage of carboxymethyl chitosan and thiolated chitosan, regulating the ph value of the solution to 6-8, performing ultrasonic blending, performing ion crosslinking and polymer condensing, then dropwise adding hydrogen peroxide into the system so as to finish oxidization crosslinking, performing room-temperature stirring reaction, separating products, and drying the products to obtain the amycin controlled-release chitosan nano particles with pH / oxido-reduction dual response. The amycin controlled-release chitosan nano particles with pH / oxido-reduction dual response is capable of escaping away from tumor cell endosome / lysosome, is capable of automatically regulating and controlling to realize cytoplast release based on unique microenvironments of tumor cells, improving the amycin medicine delivery efficiency and the medical effect, and has a favorable research and development application background in multiple aspects such as medicine and medical materials.
Owner:OCEAN UNIV OF CHINA
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