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Deep corrosion method of electrode aluminum foil for flash lamp

A flash lamp and electrode technology, applied in the direction of circuits, capacitors, electrical components, etc., can solve the problems of inability to carry out deep corrosion, perforation corrosion, high leakage current, etc., to reduce primary corrosion current, reduce primary acidity, reduce loss and leakage current Effect

Active Publication Date: 2013-01-23
新疆广投桂东电子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The invention overcomes the technical problem that the existing corrosion technology cannot carry out deep corrosion or even perforation corrosion, and solves the technical problems of high loss, high leakage current and low specific volume of the original corrosion technology

Method used

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  • Deep corrosion method of electrode aluminum foil for flash lamp
  • Deep corrosion method of electrode aluminum foil for flash lamp
  • Deep corrosion method of electrode aluminum foil for flash lamp

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Soak the aluminum foil in the pretreatment solution for 60 seconds, clean it and place it in a primary corrosion mixture containing 2.0wt% hydrochloric acid, 25wt% sulfuric acid and 0.5wt% aluminum ions at a temperature of 80°C, and apply a current density of 550mA / cm 2 Conduct electrolytic corrosion with direct current for 210 seconds, clean it with pure water and put it into the secondary corrosion solution containing 4wt% hydrochloric acid, 0.5wt% aluminum ion and 0.1g / L corrosion inhibitor at 85°C and pass through it with 50mA / cm 2 The electric current is treated for 900 seconds, and then the foil sample is cleaned and soaked in the post-treatment solution for 30 seconds, then dried, and the capacity is tested at 361Vf.

Embodiment 2

[0031] Soak the aluminum foil in the pretreatment solution for 120 seconds, clean it and place it in a primary corrosion mixture containing 6wt% hydrochloric acid, 30wt% sulfuric acid and 2wt% aluminum ions at a temperature of 73°C, and apply a current density of 450mA / cm 2 Electrolytic corrosion for 180 seconds with direct current, cleaned with pure water and then placed in a secondary corrosion solution containing 5.5wt% hydrochloric acid, 3wt% aluminum ions and 0.3g / L corrosion inhibitor at 82°C with a flow rate of 75mA / cm 2 The current treatment is 720 seconds, and then the foil sample is cleaned and soaked in the post-treatment solution for 60 seconds, then dried, and the capacity is tested at 361Vf.

Embodiment 3

[0033] Soak the aluminum foil in the pretreatment solution for 150 seconds, clean it and place it in a primary corrosion mixture containing 10wt% hydrochloric acid, 45wt% sulfuric acid and 5.5wt% aluminum ions at a temperature of 70°C, and apply a current density of 200mA / cm 2 Conduct electrolytic corrosion with direct current for 90 seconds, clean it with pure water and put it into a secondary corrosion solution containing 8wt% hydrochloric acid, 5.5wt% aluminum ions and 0.5g / L corrosion inhibitor at 75°C with a flow rate of 100mA / cm 2 The electric current is treated for 600 seconds, and then the foil sample is cleaned and soaked in the post-treatment solution for 180 seconds, then dried, and the capacity is tested at 361Vf.

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Abstract

The invention discloses a deep corrosion method of an electrode aluminum foil for a flash lamp. The method comprises the following steps of: pre-processing a crude aluminum foil; performing primary corrosion to form holes; performing secondary corrosion for hole expansion; post-processing; and performing pure water washing, wherein in the step of performing the primary corrosion to form the holes, the holes are formed at one time by using high-hydrochloric acid content, low-acidity and low-temperature mixed solution of hydrochloric acid and sulfuric acid at high current density for a long time; and in the step of performing the secondary corrosion for hole expansion, the hole expansion with low corrosion capacity is performed by using a high-acidity hydrochloric acid system at a low temperature and low current density. By the method, interpenetrated vertical holes are formed in an electrode foil, and surface holes are uniform, so that the specific surface areas of the holes are improved, the electrostatic capacity of the electrode foil is increased, and the loss and the leakage current are reduced. After the produced etched electrode foil is formed, the specific volume reaches 1.3to 1.36mu F / cm<2> through 361vf detection, and the formed foil has smaller tg delta and the leakage current of less than 20mu A on every square centimeter of area.

Description

1. Technical field [0001] The invention relates to the technical field of electrode aluminum foil corrosion, in particular to a method for deep corrosion of electrode aluminum foil for flash lamps. 2. Background technology [0002] Electrode aluminum foil for flashlight aluminum electrolytic capacitors needs to be continuously charged and discharged in a short period of time, requiring high energy storage density, small loss and leakage current. Ordinary high-voltage aluminum electrolytic capacitors work in a different way, with relatively lower requirements, and usually play a filtering role in the circuit. Therefore, the requirements for the special electrode foil for flash lamps are higher. The characteristics of this foil are high specific volume, low loss, and small leakage current. The corrosion method usually adopts deep corrosion or even perforation corrosion, which can effectively prevent the high temperature rise caused by frequent charging and discharging. At pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/055C25F3/04
Inventor 宋洪洲蔡小宁熊传勇陆雅军
Owner 新疆广投桂东电子科技有限公司