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Method for determining lead, cadmium, chromium and mercury in plastic through EDTA-2Na complexation digestion

An edta-2na, plastic technology, which is used in the preparation of test samples, material excitation analysis, thermal excitation analysis, etc., can solve the problem that mercury cannot be measured, and achieve the purpose of preventing mercury loss, effective analysis results, and avoiding precipitation. Effect

Inactive Publication Date: 2015-11-11
DONGGUAN ENTRY EXIT INSPECTION & QUARANTINE BUREAU +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows us to accurately detect both lead, Cadmium or other heavy metallic substances found within certain materials such as polyethene terephthaltepside ("PET"). It does this by utilizing specific techniques called EDTA2NAHYALETTM® Complex Degradative Extractive Technique (EDTA2). These methods have been developed over several decades ago due to their ability to efficiently break down organics containing these compounds into smaller molecules without losing them altogether.

Problems solved by technology

This patented technical problem addressed by these inventors relates to improving accuracy in detecting harmful materials such as lead, Cadmium and Chromium without relying solely upon conventional analysis techniques like liquid scintillance.

Method used

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  • Method for determining lead, cadmium, chromium and mercury in plastic through EDTA-2Na complexation digestion
  • Method for determining lead, cadmium, chromium and mercury in plastic through EDTA-2Na complexation digestion
  • Method for determining lead, cadmium, chromium and mercury in plastic through EDTA-2Na complexation digestion

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Embodiment Construction

[0023] The measuring instrument used in this method is: ICP-OES710-OES type inductively coupled plasma atomic emission spectrometer, the working conditions are: emission power: 1.20kW; plasma gas: 15.0L min -1 ;Auxiliary air flow: 1.50L min -1 ; Atomizing gas: 200kPa; One reading time: 5s; Stabilization time: 15s.

[0024] SM200 anti-heavy metal pollution type rotary grinder is equipped with a special bottom sieve without heavy metal pollution grinding, the sieve hole is 0.5mm; Zhejiang Shangyu Daoxu Wusi Instrument Sand Screen Factory national standard inspection sieve, the hole diameter is 0.5mm. In addition, for comparison, the traditional wet digestion instrument ----- EH35B intelligent sample digester should be used when testing the comparative example.

[0025] In addition, prepare lead, cadmium, chromium mixed element standard solution, mercury single element standard solution are 50mg L -1 .

[0026] The reagents used in the present invention are all high-grade pure...

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Abstract

The present invention discloses a method for determining lead, cadmium, chromium and mercury in a plastic through EDTA-2Na complexation digestion. The method comprises: 1, preparing a detected sample, wherein EDTA-2Na is added to a sample solution and volume metering is performed to obtain the sample to be detected; 2, drawing a standard work curve, wherein prepared standard solutions with different concentrations are sequentially placed into an inductively coupled plasma atomic emission spectrometer, the standard work curve is drawn, and the corresponding linear regression equation is obtained according to the standard work curve; and 3, determining the detected sample, wherein the sample to be detected and obtained in the step 1 is tested, and the lead content, the cadmium content, the chromium content and the mercury content in the sample are calculated according to the linear regression equation. According to the present invention, with the EDTA-2Na complexation digestion method, the problem that the traditional wet digestion method can not determine the lead and the mercury in the plastic is solved; and with the method, the total content of the four elements such as lead, cadmium, chromium and mercury can be simultaneously and accurately determined, the detection accuracy and the detection precision can meet the detection requirements of the RoHS command, and the analysis results are effective and reliable.

Description

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Claims

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Application Information

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Owner DONGGUAN ENTRY EXIT INSPECTION & QUARANTINE BUREAU
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