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Polarographic residual chlorine sensor

A residual chlorine and polarographic technology, applied in the field of polarographic residual chlorine sensors, can solve the problems of reduced sensitivity and reduced measurement current value, and achieve the effect of high-precision and high residual chlorine concentration measurement

Inactive Publication Date: 2013-07-03
SANYO ELECTRIC CO LTD
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Problems solved by technology

Furthermore, since the electrode reaction depends on its surface area, when the area of ​​the conductive material constituting the working electrode that is in contact with the water to be measured, that is, the electrode surface area becomes smaller, the measured current value is greatly reduced in proportion to the electrode surface area, and the sensitivity is reduced. The problem

Method used

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Embodiment Construction

[0050] Next, the polarographic residual chlorine sensor 1 according to one embodiment of the present invention will be described in detail based on the drawings. exist figure 1 Among them, the polarographic residual chlorine sensor 1 of the embodiment is equipped with, for example, a working electrode 2, a counter electrode 4, and a reference electrode 6 as electrodes immersed in the water to be measured 8 stored in the container 10 (for example, water in a swimming pool). The three-electrode polarographic residual chlorine sensor is provided with a measurement unit 12 and a calculation unit 14.

[0051] The working electrode 2 will be described in detail later, but gold is used as a conductive material constituting the working electrode 2 in Examples. The counter electrode 4 is made of platinum in the example, and the reference electrode 6 is made of silver or silver chloride in the example. In addition, platinum may be used as the conductive material of the working electr...

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Abstract

The present invention provides a polarographic residual chlorine sensor capable of reducing the change over time of the electrode surface area of a working electrode. The polarographic residual chlorine sensor determiners the residual chlorine concentration by at least immersing the working electrode (2) and a counter electrode in the water to be measured, and measuring the current flow between the working electrode and a counter electrode caused by an oxidation-reduction reaction. The cross-sectional areas of a conductive material (16) constituting the working electrode perpendicular to the axial direction at different positions are the same shape, and are covered by a casing (17) in the manner of leaving axially two end faces, and an end face is immersed in the water to be measured.

Description

technical field [0001] The present invention relates to a polarographic residual chlorine sensor for measuring the concentration of chlorine, hypochlorous acid, hypochlorite ions, and other residual chlorine contained in water to be measured using a polarographic method. Background technique [0002] At present, water used in circulating baths, swimming pools, etc. is injected with agents such as sodium hypochlorite for sterilization. When the concentration of residual chlorine in the water is high, there is a fear of adverse effects on the human body, so the amount of residual chlorine is measured and monitored with a hypochlorous acid concentration measuring device using the DPD method or the polarographic method, The amount of residual chlorine was adjusted to a predetermined residual chlorine concentration. [0003] Generally, as shown in Patent Document 1, the measuring device of the residual chlorine concentration of the polarographic method includes a working electro...

Claims

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Application Information

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IPC IPC(8): G01N27/48
CPCG01N27/30G01N27/3277G01N27/416G01N27/48G01N33/182
Inventor 铃木大辅山本哲也八重樫正宽
Owner SANYO ELECTRIC CO LTD
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