A preparing method of a photovoltaic material comprising a donor-acceptor type thiophene-pyridine copolymer
A thienopyridine copolymer, donor-acceptor type technology, applied in the field of photovoltaic material preparation, can solve the problem of not containing both metal and copolymer materials, and achieve high light energy conversion rate
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[0011] The technical solutions of the present invention will be described in further detail below in conjunction with specific embodiments.
[0012] Preparation method of photovoltaic material comprising acceptor-type thienopyridine copolymer, which will give acceptor-type thienopyridine copolymer 60%; SnO 2 5%; 2% silane coupling agent, 8% cuprous sulfide, and 25% dichloromethane are mixed and heated to 450 degrees Celsius within 30 minutes and kept at 450 degrees Celsius for 1 hour. Percentages are mass percentages. The donor-acceptor type thiophene pyridine copolymer is 3-hexylthiophene- co -pyridine copolymer, the preparation process is as follows: 2,5-dibromo-3-hexylthiophene and 2,5-dibromopyridine are used as raw materials, and 1,3-bis(diphenylphosphine)propane nickel dichloride is used as Catalyst, adopts Grignard reagent method to synthesize 3-hexylthiophene- co - pyridine copolymers. After keeping at 400-500 degrees Celsius for 1-2 hours, it is applied to the sur...
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