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A preparing method of a photovoltaic material comprising a donor-acceptor type thiophene-pyridine copolymer

A thienopyridine copolymer, donor-acceptor type technology, applied in the field of photovoltaic material preparation, can solve the problem of not containing both metal and copolymer materials, and achieve high light energy conversion rate

Inactive Publication Date: 2016-03-16
SUZHOU GUOHUAN ENVIRONMENT DETECTION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Existing photovoltaic materials are generally in the form of copolymers or metal complexes, but there are no materials containing both metals and copolymers

Method used

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Embodiment Construction

[0011] The technical solutions of the present invention will be described in further detail below in conjunction with specific embodiments.

[0012] Preparation method of photovoltaic material comprising acceptor-type thienopyridine copolymer, which will give acceptor-type thienopyridine copolymer 60%; SnO 2 5%; 2% silane coupling agent, 8% cuprous sulfide, and 25% dichloromethane are mixed and heated to 450 degrees Celsius within 30 minutes and kept at 450 degrees Celsius for 1 hour. Percentages are mass percentages. The donor-acceptor type thiophene pyridine copolymer is 3-hexylthiophene- co -pyridine copolymer, the preparation process is as follows: 2,5-dibromo-3-hexylthiophene and 2,5-dibromopyridine are used as raw materials, and 1,3-bis(diphenylphosphine)propane nickel dichloride is used as Catalyst, adopts Grignard reagent method to synthesize 3-hexylthiophene- co - pyridine copolymers. After keeping at 400-500 degrees Celsius for 1-2 hours, it is applied to the sur...

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Abstract

The invention belongs to the field of photovoltaic materials, and particularly relates to a preparing method of a photovoltaic material comprising a donor-acceptor type thiophene-pyridine copolymer. The method includes mixing 50-60% of the donor-acceptor type thiophene-pyridine copolymer, 1-10% of SnO2, 1-2% of a silane coupling agent, 5-10% of cuprous sulfide and 20-40% of dichloromethane, heating to 400-500 DEG C, and maintaining the temperature at 400-500 DEG C for 1-2 h, with the percentages being mass percentages. The photovoltaic material contains metals and the copolymer and is high in light conversion efficiency.

Description

technical field [0001] The invention belongs to the field of photovoltaic materials, and in particular relates to a method for preparing a photovoltaic material comprising a donor-acceptor type thienopyridine copolymer. Background technique [0002] Existing photovoltaic materials are generally in the form of copolymers or metal complexes, but there are no materials containing both metals and copolymers. Contents of the invention [0003] The purpose of the present invention is to overcome the above-mentioned problems, and provide a method for preparing a photovoltaic material containing both metal and copolymer and having a high light energy conversion rate and containing a donor-acceptor type thienopyridine copolymer. [0004] In order to achieve the above object, the technical solution adopted in the present invention is: a method for preparing a photovoltaic material comprising a donor-acceptor type thienopyridine copolymer, which is characterized in that it includes t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G61/12
CPCC08G61/126C08G2261/12C08G2261/3229C08G2261/91
Inventor 康达莲赵杰邓会超
Owner SUZHOU GUOHUAN ENVIRONMENT DETECTION
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