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Compound rubidium borofluoride and rubidium borofluoride non-linear optical crystal and preparation method and use of rubidium borofluoride non-linear optical crystal

A technology of nonlinear optics and rubidium fluoroborate, applied in the field of compounds, can solve problems such as the difficulty of growing large-sized crystals

Active Publication Date: 2017-10-20
XINJIANG TECHN INST OF PHYSICS & CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As we all know, the only practical deep ultraviolet nonlinear optical crystal is KBe invented by Chinese scientists. 2 BO 3 f 2 (KBBF) crystal, which has a layered growth habit, and it is difficult to grow large-sized crystals, which limits its application to a certain extent.

Method used

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  • Compound rubidium borofluoride and rubidium borofluoride non-linear optical crystal and preparation method and use of rubidium borofluoride non-linear optical crystal
  • Compound rubidium borofluoride and rubidium borofluoride non-linear optical crystal and preparation method and use of rubidium borofluoride non-linear optical crystal
  • Compound rubidium borofluoride and rubidium borofluoride non-linear optical crystal and preparation method and use of rubidium borofluoride non-linear optical crystal

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Experimental program
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Effect test

Embodiment 1

[0055] Preparation compound:

[0056] According to the reaction formula: RbF+2B 2 o 3 →RbB 4 o 6 F, compound RbB was synthesized by solid-state reaction 4 o 6 F:

[0057] RbF, B 2 o 3 Mix evenly at a molar ratio of 1:2, put it into a platinum crucible, place it in a muffle furnace and raise the temperature to 600°C, and keep the temperature constant for 48 hours to obtain the compound RbB 4 o 6 F.

Embodiment 2

[0059] Preparation compound:

[0060] According to the reaction formula: RbF+4H 3 BO 3 →RbB 4 o 6 F+6H 2 O, compound RbB was synthesized by solid phase reaction 4 o 6 F:

[0061] RbF, B 2 o 3 Mix evenly at a molar ratio of 1:2, put it into a platinum crucible, place it in a muffle furnace and raise the temperature to 650°C, and keep the temperature constant for 24 hours to obtain the compound RbB 4 o 6 F.

Embodiment 3

[0063] Preparation compound:

[0064] According to the reaction formula: 12RbOH+4RbBF 4 →RbB 4 o 6 F+15RbF+6H 2 O, compound RbB was synthesized by solid phase reaction 4 o 6 F:

[0065] RbOH, RbBF 4 Mix evenly at a molar ratio of 3:1, put it into a platinum crucible, place it in a muffle furnace and raise the temperature to 350°C, and keep the temperature constant for 120 hours to obtain the compound RbB 4 o 6 F.

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Abstract

The invention provides a compound rubidium borofluoride and a rubidium borofluoride non-linear optical crystal and a preparation method and use of the rubidium borofluoride non-linear optical crystal. The compound rubidium borofluoride has a chemical formula of RbB4O6F, has molecular weight of 243.71 and is prepared through a solid phase synthesis method or a vacuum packaging method. The crystal has a chemical formula of RbB4O6F, has molecular weight of 243.71, belongs to the orthorhombic system, and has a space group of Pna 21 and cell parameters such as a=7.6742A, b=11.228A, c=6.6218A, alpha=beta=gamma=90 degrees, unit-cell volume of 570.57 A<3>, crystal frequency-doubled effect about 1.9 times that of KH2PO4 (KDP) and ultraviolet absorption edge shorter than 190nm. The crystal is formed through a melt method, a high temperature melt method, a vacuum encapsulation method, a hydrothermal method or a room-temperature solution method. The crystal has good chemical stability and can be used as an ultraviolet and deep-ultraviolet non-linear optical crystal in an all-solid-state laser.

Description

technical field [0001] The invention relates to a compound rubidium fluoroborate RbB 4 o 6 F and rubidium fluoroborate RbB 4 o 6 F nonlinear optical crystal and its preparation method and application. Background technique [0002] Deep ultraviolet nonlinear optical crystals can use their frequency conversion properties to convert near-infrared and visible lasers into deep ultraviolet lasers with wavelengths less than 200nm, and have important application values ​​in medical, communication, scientific research and other fields. As we all know, the only practical deep ultraviolet nonlinear optical crystal is the KBe invented by Chinese scientists. 2 BO 3 f 2 (KBBF) crystal, which has a layered growth habit, and it is difficult to grow large-sized crystals, which limits its application to a certain extent. Therefore, it is of great significance and practical value to prepare and synthesize new deep ultraviolet nonlinear optical crystal materials with excellent comprehens...

Claims

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Application Information

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IPC IPC(8): C01B35/12C30B29/10C30B15/00C30B17/00C30B11/02C30B9/12C30B7/10C30B7/14G02F1/355
CPCC01B35/121C30B7/10C30B7/14C30B9/12C30B11/02C30B15/00C30B17/00C30B29/10G02F1/3551
Inventor 潘世烈王颖张方方
Owner XINJIANG TECHN INST OF PHYSICS & CHEM CHINESE ACAD OF SCI
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