The present application relates to a series of compounds methyl trifluoroborate and methyl trifluoroborate
nonlinear optical crystal and preparation method and use, the molecular general formula of the series of compounds is A3[CH3BF3]X2, wherein A=NH4, K, Rb, Cs, X=[NO3], Cl, Br, the molecular weight is 207.86-641.37, top seed method is prepared, orthorhombic
system,
space group Cmc 21 (No.36), the
cell parameter is a=11.9141 (17)-12.6254 (2) Å, b=8.1556 (12)-8.4654 (17) Å, c=10.9621 (14)-11.5625 (15) Å, α =90, β =90, γ =90, Z =4, V=1065.2 (3)-1261.9 (1) Å 3 The series of compounds methyl trifluoroborate
nonlinear optical crystal obtained by the method has the advantages of wide
light transmission waveband, stable physical and chemical properties, moderate mechanical
hardness, not easy to break, easy to
cut, polish
processing and preservation and the like.