The invention discloses a liquid-phase plasma rock blasting method suitable for blasting rocks and concrete structures. According to the method, strong discharging is implemented in strong sodium chloride or potassium chloride electrolyte solutions for stimulating generation of high-density liquid-phase plasmas; in the high-density liquid-phase plasmas, due to the mutual effect of the electrical property of ion clusters, intense vibration occurs in the sections where ions exist in an instant, high temperature and high pressure are generated in the plasma sections, clustering shock waves of the ions are formed and extend outwards, and therefore the energy of ion waves is spread to the surrounding rocks, natural defects such as joints and fractures in the rocks or the concrete structures are enlarged, new cracks and weakness planes are formed until the rocks or the concrete structures are damaged, and the purpose of blasting the rocks or the concrete structures through the plasmas is realized. Compared with traditional explosive blasting methods, the liquid-phase plasma rock blasting method has the remarkable advantages that dust is avoided, fume is avoided, poisonous and harmful gas is avoided, throwing is avoided, and the noise is low.