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A method for reducing energy consumption and water consumption of a syngas-to-methanol system and a system for producing methanol from syngas

A technology for synthesis gas and methanol production, which is applied in the preparation of organic compounds, chemical instruments and methods, preparation of hydroxyl compounds, etc., and can solve the problems of large amount of circulating water, large power consumption, high energy consumption and water consumption, etc.

Active Publication Date: 2021-01-19
CHNA ENERGY INVESTMENT CORP LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Industrial methanol is obtained by the reaction of synthesis gas containing carbon monoxide, carbon dioxide and hydrogen under the action of a certain temperature, pressure and catalyst, and the reaction product is obtained by cooling, gas-liquid separation, filtration and washing, and rectification. Although the heat of reaction has also been properly recovered, for large-scale methanol synthesis units, the energy consumption and water consumption of cooling and rectification are still relatively large (after the reactor outlet preheats the inlet gas, it still needs to consume a large amount of electric energy (accounting for 30% of the total energy consumption of the device), and at the same time, during flash evaporation, about 0.15t of steam is consumed for each ton of methanol produced, which needs to be further reduced, and the amount of circulating water used to condense the flashed gas is also large

Method used

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  • A method for reducing energy consumption and water consumption of a syngas-to-methanol system and a system for producing methanol from syngas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] process such as figure 1 As shown, among them,

[0037] (1) Reaction: Preheat (heat exchange) the synthesis gas raw material to 234°C and continuously feed it into the reactor at a flow rate of 167t / h to react in the presence of a catalyst with a reaction pressure of 7.6MPa;

[0038] (2) primary cooling: the reaction product (285° C.) obtained in step (1) is exchanged for heat by means of a heat exchanger;

[0039] (3) Secondary cooling: the reaction product after primary cooling and heat exchange is cooled to 65°C by an air cooler, and then cooled to 53°C by a water cooler;

[0040] (4) Gas-liquid separation: the product after the secondary cooling enters the gas-liquid separator for gas-liquid separation (7.7MPa), and obtains a liquid phase product and a gas phase product;

[0041] (5) Decompression: the liquid phase product is depressurized to 0.32MPa through a decompression valve;

[0042] (6) flash evaporation: the material after the decompression is passed into...

Embodiment 2

[0047] process such as figure 1 As shown, among them,

[0048] (1) Reaction: Heating (exchanging heat) the synthesis gas raw material to 233°C and continuously passing it into the reactor at a flow rate of 167t / h to react in the presence of a catalyst, the reaction pressure is 8MPa;

[0049] (2) Primary cooling: the reaction product (284° C.) obtained in step (1) is subjected to heat exchange by means of a heat exchanger;

[0050] (3) Secondary cooling: the reaction product after primary cooling and heat exchange is cooled to 60°C by an air cooler, and then cooled to 45°C by a water cooler;

[0051] (4) Gas-liquid separation: the product after the secondary cooling enters the gas-liquid separator for gas-liquid separation (7.2MPa), and obtains a liquid phase product and a gas phase product;

[0052] (5) Decompression: the liquid phase product is depressurized to 0.35MPa through a decompression valve;

[0053] (6) Flash evaporation: pass the decompressed material into the fl...

Embodiment 3

[0058] process such as figure 1 As shown, among them,

[0059] (1) Reaction: Heating (exchanging heat) the synthesis gas raw material to 237°C and continuously passing it into the reactor at a flow rate of 167t / h to react in the presence of a catalyst, and the reaction pressure is 7MPa;

[0060] (2) Primary cooling: the reaction product (286° C.) obtained in step (1) is subjected to heat exchange by means of a heat exchanger;

[0061] (3) Secondary cooling: the reaction product after primary cooling and heat exchange is cooled to 70°C by an air cooler, and then cooled to 40°C by a water cooler;

[0062] (4) Gas-liquid separation: the product after the secondary cooling enters the gas-liquid separator for gas-liquid separation (7.9MPa), and obtains a liquid phase product and a gas phase product;

[0063] (5) Decompression: the liquid phase product is depressurized to 0.3MPa through a decompression valve;

[0064] (6) Flash evaporation: the decompressed material is passed int...

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Abstract

The invention relates to the field of industrial methyl alcohol preparation, and discloses a method for reducing energy consumption and water consumption of a system for preparing methyl alcohol by synthesis gas and the system for preparing the methyl alcohol by the synthesis gas. The method comprises the following steps: enabling synthesis gas raw materials to react to obtain a methyl alcohol-containing reaction product; performing primary cooling, secondary cooling and gas-liquid separation on the reaction product; performing flash evaporation on a liquid phase product obtained by performingthe gas-liquid separation; condensing a gas phase product after the flash evaporation is performed, wherein the primary cooling mode is that the reaction product exchanges heat with the synthesis gasraw materials and the liquid phase product which is obtained by the gas-liquid separation; a cooling medium for condensing is provided by the gas phase product obtained by the gas-liquid separation.The system comprises a reactor, a primary cooling unit, a secondary cooling unit, a gas-liquid separator, a flash evaporating tower and a condenser which are connected in sequence; the primary coolingunit comprises a first heat exchanger and a second heat exchanger; a gas phase product outlet of the gas-liquid separator is connected with a cooling medium inlet of the condenser. According to the method and the system, the using amount of steam and recycling water can be reduced.

Description

technical field [0001] The invention relates to the field of methanol production from industrial synthesis gas, in particular to a method for reducing energy consumption of a system for producing methanol from synthesis gas and a system for preparing methanol from synthesis gas. Background technique [0002] Industrial methanol is obtained by the reaction of synthesis gas containing carbon monoxide, carbon dioxide and hydrogen under the action of a certain temperature, pressure and catalyst, and the reaction product is obtained by cooling, gas-liquid separation, filtration and washing, and rectification. Although the heat of reaction has also been properly recovered, for large-scale methanol synthesis units, the energy consumption and water consumption of cooling and rectification are still relatively large (after the reactor outlet preheats the inlet gas, it still needs to consume a large amount of electric energy (accounting for 30% of the total energy consumption of the d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C29/76C07C29/151C07C31/04
CPCC07C29/151C07C29/76C07C31/04
Inventor 姚金松李初福张峰姜兴剑孙保全孙高攀苗强
Owner CHNA ENERGY INVESTMENT CORP LTD