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Environment-friendly non-poisonous durable antibacterial polypropylene material

A technology of antibacterial polypropylene and grafted polypropylene, which is applied in the field of modified plastics, can solve the problems of short action time, harmfulness to human body, and easy hydrolysis, etc., and achieves improved mechanical strength and heat distortion temperature, good antibacterial effect, and reduced shrinkage rate Effect

Active Publication Date: 2018-07-06
SHANGHAI JINCHANG ENG PLASTICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Inorganic antibacterial agents have the advantages of antibacterial persistence, heat resistance, durability, safety, etc., but their disadvantages are high price and slow antibacterial effect, which cannot kill bacteria quickly; while organic antibacterial agents can effectively inhibit harmful bacteria , the production and reproduction of mold, but the action time is short and harmful to the human body, easy to hydrolyze, and can only be used below 300 °C
[0012] CN101089038B discloses a kind of antibacterial polypropylene plastic, and it adopts nano-silver and organosilicon antibacterial agent as conforming antibacterial agent, can obtain good antibacterial effect, but its mechanical property does not have any improvement

Method used

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  • Environment-friendly non-poisonous durable antibacterial polypropylene material
  • Environment-friendly non-poisonous durable antibacterial polypropylene material
  • Environment-friendly non-poisonous durable antibacterial polypropylene material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] An environmentally friendly, non-toxic and durable antibacterial polypropylene material is characterized in that its raw materials include: 100 parts by mass of homopolypropylene resin, 30 parts by mass of nano-calcium silicate, 10 parts by mass of maleic anhydride grafted polypropylene Polymer, 1 mass part of titanium dioxide dispersant, 0.3 mass part of antioxidant, 0.3 mass part of phenyl o-hydroxybenzoate, 0.2 mass part of 8-hydroxyquinoline La complex, 2 mass parts of methyl Ammonium iodide, 0.6 parts by mass of ferrocenemethanol, and 0.1 part by mass of 6-bromo-2,3-naphthyridine.

[0035] Homopolypropylene resin was purchased from Li Changrong Chemical (Fuju) 6331 injection molding grade homopolypropylene.

[0036] Anatase titanium dioxide dispersant was purchased from Jinan Yuxing BA01-01 A1 anatase titanium dioxide.

[0037] The preparation method of 8-hydroxyquinoline La complex

[0038] Raw materials; 8-hydroxyquinoline (analytical grade Tianjin Chemical Rea...

Embodiment 2

[0045] An environmentally friendly, non-toxic and durable antibacterial polypropylene material is characterized in that its raw materials include: 100 parts by mass of homopolypropylene resin, 35 parts by mass of nano-calcium silicate, 15 parts by mass of maleic anhydride grafted polypropylene polymer, 1.5 parts by mass of titanium dioxide dispersant, 0.5 parts by mass of antioxidant 1076, 0.5 parts by mass of phenyl o-hydroxybenzoate, 0.3 parts by mass of 8-hydroxyquinoline La complex, 3 parts by mass of formazan ammonium iodide, 0.8 parts by mass of ferrocenemethanol and 0.1 part by mass of 6-bromo-2,3-naphthyridine.

[0046] Homopolypropylene resin was purchased from Li Changrong Chemical (Fuju) 6331 injection molding grade homopolypropylene.

[0047] Anatase titanium dioxide dispersant was purchased from Jinan Yuxing BA01-01 A1 anatase titanium dioxide.

[0048] The preparation method of 8-hydroxyquinoline La complex

[0049] Raw materials: 8-hydroxyquinoline (analytical...

Embodiment 3

[0057] An environmentally friendly, non-toxic and durable antibacterial polypropylene material is characterized in that its raw materials include: 100 parts by mass of homopolypropylene resin, 25 parts by mass of nano-calcium silicate, 5 parts by mass of maleic anhydride grafted polypropylene polymer, 0.5 parts by mass of titanium dioxide dispersant, 0.1 parts by mass of antioxidant 1076, 0.1 parts by mass of phenyl o-hydroxybenzoate, 0.1 parts by mass of 8-hydroxyquinoline La complex, 1 part by mass of formazan ammonium iodide, 0.4 parts by mass of ferrocenemethanol and 0.1 part by mass of 6-bromo-2,3-naphthyridine.

[0058] Homopolypropylene resin was purchased from Li Changrong Chemical (Fuju) 6331 injection molding grade homopolypropylene.

[0059] Anatase titanium dioxide dispersant was purchased from Jinan Yuxing BA01-01 A1 anatase titanium dioxide.

[0060] The preparation method of 8-hydroxyquinoline La complex

[0061] Raw materials: 8-hydroxyquinoline (analytical g...

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Abstract

The invention relates to an antibacterial polypropylene material and a preparation method thereof. The antibacterial polypropylene material is prepared from the following raw materials: homo-polypropylene resin, nanometer calcium silicate, a maleic anhydride grafted polypropylene homopolymer, a titanium dioxide dispersing agent, an antioxidant, salicylic acid phenyl ester, an 8-hydroxyquinoline Lacoordination complex, methyl ammonium iodide and ferrocene methyl alcohol; the preparation method comprises the following steps of pre-dispersion, mixing, squeezing and the like. The prepared antibacterial polypropylene is good in antibacterial effect, environment-friendly and non-poisonous, the mechanical strength and thermal deformation temperature are improved, and the shrinking percentage islowered.

Description

technical field [0001] The invention belongs to the field of modified plastics, in particular to an environment-friendly, non-toxic and durable antibacterial polypropylene material. Background technique [0002] Polypropylene is a thermoplastic resin produced by the polymerization of propylene. According to the arrangement position of the methyl group, it can be divided into three types: isotactic polypropylene, atactic polypropylene and syndiotactic polypropylene. [0003] When the methyl groups are arranged on the same side of the molecular main chain, it is called isotactic polypropylene. If the methyl groups are arranged randomly on both sides of the molecular main chain, it is called atactic polypropylene. When the methyl groups are arranged alternately on both sides of the molecular main chain, it is called interstitial polypropylene. Regular polypropylene. In the polypropylene resin produced in general industry, the isotactic structure content is about 95%, and the ...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L51/06C08L3/02C08K13/02C08K3/34C08K3/22C08K5/57C08K5/19C08K5/3437
CPCC08K2201/011C08L23/12C08L2201/08C08L2205/03C08L51/06C08L3/02C08K13/02C08K5/19C08K5/3437C08K3/34C08K3/22C08K5/57
Inventor 段宝荣徐兴芳
Owner SHANGHAI JINCHANG ENG PLASTICS CO LTD
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