A kind of negative electrode material of lithium ion battery and preparation method thereof
A lithium-ion battery and negative electrode material technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of inability to meet large-scale energy storage, low specific capacity, etc., achieve good application and promotion prospects, and low redox potential Effect
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[0101] Example 1 Preparation of 3,3',4,4'-benzophenone tetracarboxylic diimide polymer (PBZTI)
[0102]
[0103] PBZTI is any of the following polymers:
[0104] A:
[0105] B:
[0106] C:
[0107] D:
[0108] Among them, n=1-5.
[0109] Its concrete reaction steps are as follows:
[0110] at room temperature, N 2 Under protective conditions, 3.2385g 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) was added into a three-necked flask along a dry funnel, and 10mL of 1-methyl-2-pyrrolidone ( NMP) was added into the three-necked flask, during the addition process, all the BTDA on the funnel and the bottle wall were washed down, and stirred for 20 min until a uniform transparent solution was formed.
[0111] at room temperature, N 2 Under protective conditions, 0.5057g N 2 h 4 Add the three-necked flask along the dry funnel. At this time, light yellow agglomeration occurs. Add 5mL NMP into the three-necked flask with a disposable dropper. During the ad...
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