An energetic material-filled layered frame composite structure and its preparation method
A frame structure and composite structure technology, applied in offensive equipment, explosives processing equipment, explosives, etc., can solve the problems of insufficient control theory and technical support, lack of feasible ideas, etc., to achieve performance improvement, reduce sensitivity, and enhance thermal conductivity. Effect
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Embodiment 1
[0029] Dissolve the chitosan powder in deionized water, stir and vibrate mechanically, and prepare a chitosan hydrosol with a concentration of 2 mg / ml.
[0030] Using the ice template method, pour the above-prepared chitosan hydrosol into the polytetrafluoroethylene thermal insulation lining with a metal bottom, place it on a stainless steel low-temperature platform at about -40°C, and freeze to induce the gradient of the chitosan hydrosol Crystallization, promoting the directional crystallization of solvent deionized water to form layered ice crystals. Continue freezing to promote the directional freezing of the hydrosol as a whole.
[0031] The frozen hydrosol was freeze-dried to obtain the chitosan layered framework structure.
[0032] The microstructure of the chitosan layered framework structure was observed by scanning electron microscopy, and figure 1 The SEM morphology. It can be seen that the chitosan layered framework structure has a parallel layered structure, th...
Embodiment 2
[0042] The glucomannan powder was dissolved in deionized water, stirred and oscillated mechanically to prepare a glucomannan hydrosol with a concentration of 2 mg / ml.
[0043] Using the ice template method, pour the above-prepared glucomannan hydrosol into the polytetrafluoroethylene thermal insulation lining with a metal bottom, place it on a stainless steel low-temperature platform at about -40°C, and freeze the induced glucomannan water. Sol gradient crystallization promotes directional crystallization of solvent deionized water to form layered ice crystals. Continue freezing to promote the directional freezing of the hydrosol as a whole.
[0044] The frozen hydrosol is freeze-dried to obtain a glucomannan layered framework structure with a layer thickness of about 200-500 nm and an internal space height between layers of 40-100 μm.
[0045] The obtained glucomannan layered framework structure was used as a template, and the HMX acetone saturated solution was added to the ...
Embodiment 3
[0052] Dissolve lignin powder in deionized water, stir and vibrate mechanically, and prepare lignin hydrosol with a concentration of 2mg / ml.
[0053] Using the ice template method, pour the above-prepared lignin hydrosol into the polytetrafluoroethylene thermal insulation lining with a metal bottom, place it on a stainless steel low-temperature platform at about -40°C, and freeze to induce the lignin hydrosol gradient Crystallization, promoting the directional crystallization of solvent deionized water to form layered ice crystals. Continue freezing to promote the directional freezing of the hydrosol as a whole.
[0054] The frozen hydrosol is freeze-dried to obtain a lignin layered frame structure with a layer thickness of about 1-3 μm and an internal space height between layers of 50-90 μm.
[0055] The obtained lignin layered framework structure is used as a template, and the LLM-105 dimethyl sulfoxide solution heated to 100°C is added to the lignin layered framework struc...
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