Automobile exhaust treatment catalytic material and preparation method thereof
A catalytic material and automobile exhaust technology, applied in chemical instruments and methods, physical/chemical process catalysts, separation methods, etc., can solve problems such as low specific surface area, easy agglomeration of catalysts, and reduced catalytic activity, so as to improve dispersion and enhance Effects of denitrification catalytic efficiency and excellent physical adsorption
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[0017] Add 5mmol of zinc nitrate and 5mmol of tetrabutyl titanate into 3ml of DMF / ethanol mixed solvent with a volume ratio of 1:0.5, then add 8mg of PVP and 3mg of ammonium bicarbonate, stir for 3h to mix well, and use it as spinning solution Electrospinning to form PVP-ZnTiO 3 , the process parameters of electrospinning are: flow rate 0.1mm / min, voltage 15kV, receiving distance 10cm; then heat treatment at 350℃ in air for 1h to obtain hollow porous ZnTiO 3 Nanofibers;
[0018] Dissolve 2mmol sodium molybdate and 2mmol cobalt nitrate in 20ml, a mixture of ethanol and glycerol with a volume ratio of 1:1, then add 4mmol trisodium citrate to make the hollow porous ZnTiO 3 The nanofibers were placed in the above mixed solution, solvothermal reaction at 180 °C, and then heat-treated at 300 °C for 1 h to obtain hollow and porous ZnTiO 3 -CoMoO 4 .
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