Automobile exhaust treatment catalytic material and preparation method thereof

A catalytic material and automobile exhaust technology, applied in chemical instruments and methods, physical/chemical process catalysts, separation methods, etc., can solve problems such as low specific surface area, easy agglomeration of catalysts, and reduced catalytic activity, so as to improve dispersion and enhance Effects of denitrification catalytic efficiency and excellent physical adsorption

Inactive Publication Date: 2021-11-16
莱西市寰球新能源技术中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the catalyst is prone to agglomeration, resulting in a low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Add 5mmol of zinc nitrate and 5mmol of tetrabutyl titanate into 3ml of DMF / ethanol mixed solvent with a volume ratio of 1:0.5, then add 8mg of PVP and 3mg of ammonium bicarbonate, stir for 3h to mix well, and use it as spinning solution Electrospinning to form PVP-ZnTiO 3 , the process parameters of electrospinning are: flow rate 0.1mm / min, voltage 15kV, receiving distance 10cm; then heat treatment at 350℃ in air for 1h to obtain hollow porous ZnTiO 3 Nanofibers;

[0018] Dissolve 2mmol sodium molybdate and 2mmol cobalt nitrate in 20ml, a mixture of ethanol and glycerol with a volume ratio of 1:1, then add 4mmol trisodium citrate to make the hollow porous ZnTiO 3 The nanofibers were placed in the above mixed solution, solvothermal reaction at 180 °C, and then heat-treated at 300 °C for 1 h to obtain hollow and porous ZnTiO 3 -CoMoO 4 .

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PUM

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Abstract

The invention discloses an automobile exhaust treatment catalytic material which is prepared by the following method: adding zinc nitrate and tetrabutyl titanate into a DMF/ethanol mixed solvent, then adding PVP and ammonium bicarbonate, stirring and mixing uniformly, performing electrostatic spinning by taking the mixture as a spinning solution to form PVP-ZnTiO3, and then performing heat treatment in air at 350-450 DEG C to obtain hollow porous ZnTiO3 nanofiber; dissolving sodium molybdate and cobalt nitrate in a mixed solution of ethanol and glycerol, then adding trisodium citrate, placing the hollow porous ZnTiO3 nanofibers in the mixed solution, carrying out solvothermal reaction at 180-200 DEG C, and then carrying out heat treatment at 300-400 DEG C to obtain the hollow porous ZnTiO3-CoMoO4.

Description

technical field [0001] The application relates to the technical field of environmental protection, in particular to a composite material that can be used for highly efficient catalysis of nitrogen oxides in automobile exhaust and a preparation method thereof. Background technique [0002] With the rapid development of society and the increasing number of motor vehicles around the world, the pollutants from vehicle exhaust have become one of the main sources of urban air pollution, which not only seriously threatens human health, but also causes great damage to the environment. Therefore, all countries are formulating more and more stringent automobile exhaust emission regulations to limit the emission of pollutants in automobile exhaust. At present, one of the effective methods for treating nitrogen oxides in automobile exhaust is catalytic reduction technology (SCR), and the core part of the SCR system is the catalyst, whose performance directly determines the removal effic...

Claims

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Application Information

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IPC IPC(8): B01J23/889B01J35/10B01D53/86B01D53/56
CPCB01J23/8892B01J35/1004B01D53/8628
Inventor赵瑞荣
Owner莱西市寰球新能源技术中心