Release liner for pressure sensitive adhesives
a technology of release liner and adhesive, which is applied in the field of release liner, can solve the problems of reducing the likelihood that the liner will shrink significantly from the adhesive upon heating, or significantly buckle, and achieves the effect of ensuring the liner is not likely to significantly decompose or melt, and ensuring the stability of the liner
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example 1
[0047] A film was prepared by extruding a blend of 85 parts of TEO (thermoplastic elastomeric olefin) and 15 parts of LLDPE (linear low density polyethylene), and about 1 part of a red pigment (PM4532 available from Techmer, Clinton, Tenn.) to a thickness of 0.153 mm thick using a blown film extruder. The TEO was a thermoplastic polyolefin having fillers and constituting a 50 / 50 blend of polypropylene and EPDM (ethylene propylene diene monomer). It was obtained as DEXFLEX SB-814 from D&S Plastics Intl. (now Solvay Engineered Plastics, Auburn Hills, Mich.). The LLDPE was a linear low density polyethylene available as ESCORENE LD117.85 from Exxon Chemical Co. (Houston, Tex.). The blown film extruder was run to achieve sufficiently high melt flow temperatures to provide a uniform flat film. Extruder temperatures ranged from about 177° C. to about 205° C. The film was then coated on each side with ultraviolet cured silicone compositions available from Akrosil to make a release liner. Sp...
example 2
[0048] A 0.153 mm thick film composite was prepared by coextruding 0.127 mm of TEO (DEXFLEX SB-814) having about 1% red pigment (PM4532) as a core, 0.013 mm of LDPE (low density polyethylene) on one surface of the TEO, and 0.013 mm of MDPE (medium density polyethylene) on the other surface of the TEO, on a blown film extruder. The low density polyethylene had a density of 0.92 g / cc and was obtained under the tradename PETROTHENE NA353 from Quantum Chemical Corp (Cincinnati, Ohio). The medium density polyethylene had a density of about 0.93 g / cc and was a blend of 33 parts by weight LDPE (PETROTHENE NA353) and 67 parts high density polyethylene having a density of 0.96 g / cc. It was obtained under the tradename PETROTHENE LT6180 from Quantum Chemical Corp. The medium and low density polyethylenes provided differential release surfaces for an acrylate pressure-sensitive adhesive. The release liner was tested for tear strength. The liner had a machine direction tear strength of 0.5 poun...
examples 3-6
[0049] A release liner was prepared by blending TEO (DEXFLEX SB-814), with varying amounts of a low density polyethylene as shown in Table 1, and forming a 0.153 mm thick film using a blown film extruder. The TEO was colored with a carbon black pigment. The polyethylene was DOWLEX 2045 which is a linear low density polyethylene having a density of 0.92 g / cc and a narrow molecular weight distribution. The liners were tested for release force as described above except that the samples were aged in an oven at 121° C. for 30 minutes and cooled to room temperature before testing. The release values are shown in Table 1. The data show that in the preferred ranges of TEO and polyethylene (Examples 5 and 6), acceptable release values (i.e., under about 40 oz / inch) are obtained. All of the liners were tested for expansion and contraction on a TEO substrate using the Test Method described above. None of them exhibited any visible shrinkage or wrinkling.
TABLE 1TEO / LDPE BlendsExampleParts TEO...
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