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Method for producing nickel alloy porous body

a nickel alloy and porous body technology, applied in the direction of solid-state diffusion coating, electrolytic process, coating, etc., can solve the problems of affecting the quality of nickel alloy porous body, so as to facilitate the control of concentration and uniform diffusion

Inactive Publication Date: 2018-02-01
SUMITOMO ELECTRIC IND LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The invention provides a way to make a porous body out of a nickel alloy. It allows for easy control of the metal concentration and ensures that the added metal is evenly distributed throughout the porous body.

Problems solved by technology

The porous metal body is vulnerable to processing that involves plastic deformation, such as bending or pressing, and breaks when subjected to such processing, which is a problem.
However, in the porous metal body produced by the sintering process, since the skeleton is formed by sintering between metal or metal oxide powder particles, even if the powder particle size is decreased, voids occur in considerable numbers in the skeleton in cross section.
As a result, even when a body having high breaking strength is obtained by designing a single metal or alloy species, since the elongation at break is low, the body is vulnerable to processing that involves plastic deformation, such as bending or pressing, and breaks when subjected to such processing, which is a problem, as in the case described above.
However, the low productivity of the diffusion coating process results in a high cost, and the element capable of forming an alloy with the Ni porous body is limited to Cr and Al, all of which are problems.

Method used

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  • Method for producing nickel alloy porous body
  • Method for producing nickel alloy porous body
  • Method for producing nickel alloy porous body

Examples

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example 1

[0100](Electrical Conduction Treatment of Resin Formed Body)

[0101]First, as resin formed bodies having a three-dimensional mesh-like structure, polyurethane foam sheets (pore size 0.45 mm) with a thickness of 1.5 mm were prepared. Subsequently, 100 g of graphite with a volume-average particle size of 10 μm, 20 g of carbon black with a volume-average particle size of 0.1 μm, and 100 g of a nickel alloy oxide powder with a volume-average particle size shown in Table 1 were dispersed in 0.5 L of a 10% aqueous solution of an acrylic ester resin, and a viscous coating material was produced at this composition ratio.

[0102]As the nickel alloy oxide powder, a nickel-chromium alloy oxide powder, a nickel-cobalt alloy oxide powder, a nickel-tin alloy oxide powder, and a nickel-copper alloy oxide powder was used. The nickel alloy oxide powders were obtained by oxidizing the corresponding nickel alloy powders and used by disintegrating and classifying the oxidized powders so that the volume-ave...

example 2

[0113]Nickel alloy porous bodies 5 to 8 were produced as in Example 1 except that, instead of the nickel-chromium alloy oxide powder, the nickel-cobalt alloy oxide powder, the nickel-tin alloy oxide powder, and the nickel-copper alloy oxide powder, a nickel-chromium alloy powder, a nickel-cobalt alloy powder, a nickel-tin alloy powder, and a nickel-copper alloy powder were used. The volume-average particle size and coating weight of the nickel alloy powders are shown in Table 1.

[0114]Cross sections of skeletons of the nickel alloy porous bodies 5 to 8 were observed by an electron microscope as in Example 1. As a result, it was confirmed that the added metal particles do not remain on the inner surface of the skeleton of the nickel alloy porous body and that the added metal is uniformly diffused into nickel.

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Abstract

A method for producing a nickel alloy porous body includes a step of applying a coating material that contains a nickel alloy powder of nickel and an added metal, the nickel alloy powder having a volume-average particle size of 10 μm or less, onto a surface of a skeleton of a resin formed body having a three-dimensional mesh-like structure; a step of plating with nickel the surface of the skeleton of the resin formed body onto which the coating material has been applied; a step of removing the resin formed body; and a step of diffusing the added metal into the nickel by a heat treatment.

Description

TECHNICAL FIELD[0001]The present invention relates to a method for producing a nickel alloy porous body that is usable, for example, as a current collector for a battery, filter, or catalyst carrier, that is excellent in terms of strength and toughness, and that is produced at a low cost and from a wide range of materials.BACKGROUND ART[0002]Porous metal bodies have been used in various applications, such as current collectors for batteries, filters, and catalyst carriers. Accordingly, there are many known documents regarding production techniques for porous metal bodies, as described below.[0003]Japanese Unexamined Patent Application Publication No. 7-150270 (PTL 1) proposes a porous metal body having high strength, which is obtained by applying a coating material containing reinforcing fine particles of an oxide, carbide, or nitride of an element selected from Groups II to VI of the periodic table onto a surface of a skeleton of a three-dimensional mesh-like resin having interconn...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C25D1/08C25D5/56C22C1/08C25D5/50B22F1/12
CPCC25D1/08C25D5/50C25D5/56C22C1/08B22F2301/15B22F2304/10B22F1/12C23C10/28
Inventor OKUNO, KAZUKIHIGASHINO, TAKAHIROAWAZU, TOMOYUKIMAJIMA, MASATOSHINISHIMURA, JUNICHITSUKAMOTO, KENGOTSUCHIDA, HITOSHISAITO, HIDETOSHI
Owner SUMITOMO ELECTRIC IND LTD