30 results about "Methylene-lactone" patented technology

This invention pertains to a process for making alpha-methylenelactones and alpha-substituted hydrocarbylidene lactones. The present invention obtains high yields of alpha-methylene-gamma-butyrolactone by heating gamma-butyrolactone and formaldehyde in the presence of a base.

Hair care composition comprising from about 0.1% to about 20% of a sulfopropyl(meth)acrylate compound, an alpha methylene lactone, or a mixture thereof, wherein the sulfopropyl(meth)acrylate compound and the alpha methylene lactone each have a molecular weight of less than 500 grams / mole; and a dermatologically acceptable carrier.

Hair care composition comprising from about 0.1% to about 20% of a sulfopropyl(meth)acrylate compound, an alpha methylene lactone, or a mixture thereof, wherein the sulfopropyl(meth)acrylate compound and the alpha methylene lactone each have a molecular weight of less than 500 grams / mole; and a dermatologically acceptable carrier.

Hair care composition comprising from about 0.1% to about 20% of a sulfopropyl(meth)acrylate compound, an alpha methylene lactone, or a mixture thereof, wherein the sulfopropyl(meth)acrylate compound and the alpha methylene lactone each have a molecular weight of less than 500 grams / mole; and a dermatologically acceptable carrier.

This invention concerns a process for the addition of formaldehyde to the alpha carbon atom of lactones for the production of alpha-methylenelactones, and specifically alpha-methylene-gamma-butyrolactone.

Compositions comprising homopolymers or copolymers containing repeat units derived from alpha-methylenelact(ones)(ams) such as alpha-methylenebutyrolactones and an inorganic filler such as alumina trihydrate are described. The decorative sheets and articles made from these compositions may have one or more of higher thermal resistance, higher hardness, higher scratch and mar resistance, faster polymerization rates, antimicrobial properties, lower coefficient of thermal expansion and, owing to a higher refractive index, a higher transparency.

Process for converting certain lactones to their alpha-methylene substituted forms that not only exhibits high initial activity (conversion), but also provides high reactor productivity (mass of product per mass of catalyst per unit of time) and sustained maintenance of a high level of activity and productivity with time on stream.

This invention pertains to a process for making alpha-methylenelactones and alpha-substituted hydrocarbylidene lactones. More specifically, the present invention obtains high yields of alpha-methylene-gamma-butyrolactone by heating gamma-butyrolactone and diethyl oxalate in the presence of a base. The second step comprises treatment of the alpha-oxalyl enolate salt with formaldehyde to afford the alpha-methylene-gamma-butyrolactone.

Polymers containing alpha-methylenelact(ones)(ams) such as alpha-methylenebutyrolactones are useful in blends with other polymers. For examples such polymers which have reactive groups are toughened by mixing with a rubbery material which has complimentary reactive groups, or polymers containing repeat units derived from alpha-methylenelact(ones)(ams) are toughened by mixing with polymeric core-shell particles having an elastomeric core and a specified thermoplastic shell. The properties of thermoplastics are also improved by blending with alpha-methylenelact(ones)(ams) such as alpha-methylenebutyrolactones containing (co)polymers.

Polymers containing alpha-methylenelact(ones)(ams) such as alpha-methylenebutyrolactones are useful in blends with other polymers. For examples such polymers which have reactive groups are toughened by mixing with a rubbery material which has complimentary reactive groups, or polymers containing repeat units derived from alpha-methylenelact(ones)(ams) are toughened by mixing with polymeric core-shell particles having an elastomeric core and a specified thermoplastic shell. The properties of thermoplastics are also improved by blending with alpha-methylenelact(ones)(ams) such as alpha-methylenebutyrolactones containing (co)polymers.

This invention pertains to a process for making alpha-methylenelactones and alpha-substitute hydrocarbylidene lactones. More specifically, the present invention obtains high yields of alpha-methylene-gamma-butyrolactone by heating gamma-butyrolactone and diethyl oxalate in the presence of a base. The second step comprises treatment of the alpha-oxalyl enolate salt with formaldehyde to afford the alpha-methylene-gamma-butyrolactone.

Process for converting certain lactones to their alpha-methylene substituted forms in a supercritical or near-critical fluid phase reaction using a novel grafted catalyst that not only exhibits high initial activity (conversion), but also maintains a high level of activity with time on stream.

Process for converting certain lactones to their alpha-methylene substituted forms using an oxynitride catalyst or a composite oxynitride catalyst incorporating lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, or barium or combinations thereof.

This invention discloses resilient, acrylic graft polymers comprising α-methylene lact(one)(am) monomers such as α-methylene-γ-butyrolactone, and blends of such polymers with thermoplastic matrix resins.This invention also discloses hard, non-resilient, acrylic graft polymers comprising α-methylene lact(one)(am) monomers such as α-methylene-γ-butyrolactone, and to blends of such polymers with thermoplastic matrix resins.This invention further discloses a general process for emulsion polymerization of α-methylene lact(one)(am) monomers such as α-methylene-γ-butyrolactone and its copolymers.

Process for converting certain lactones to their alpha-methylene substituted forms using (i) a catalyst derived from a hydrotalcite or (ii) a composite catalyst comprising the hydrotalcite-derived catalyst into which at least one of lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium has been incorporated.

Supercritical fluid phase process for converting certain lactones to their alpha-methylene substituted forms using a catalyst made from a thermally decomposed hydrotalcite.

This invention is directed to a coating composition used for original equipment manufacturing or refinishing uses in the automotive industry, which coating composition utilizes an acrylic polymer which contains substituted or unsubstituted exomethylene lactones or lactams as a comonomer.

Process for converting certain lactones to their alpha-methylene substituted forms in a supercritical or near-critical fluid phase reaction using an oxynitride catalyst or a composite oxynitride catalyst incorporating lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, or barium or combinations thereof.

Process for converting certain lactones to their alpha-methylene substituted forms using an oxynitride catalyst or a composite oxynitride catalyst incorporating lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, or barium or combinations thereof.

Process for converting certain lactones to their alpha-methylene substituted forms in a supercritical or near-critical fluid phase reaction using a novel grafted catalyst that not only exhibits high initial activity (conversion), but also maintains a high level of activity with time on stream.

Process for converting certain lactones to their alpha-methylene substituted forms using (i) a catalyst derived from a hydrotalcite or (ii) a composite catalyst comprising the hydrotalcite-derived catalyst into which at least one of lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium has been incorporated.

Process for converting certain lactones to their alpha-methylene substituted forms that not only exhibits high initial activity (conversion), but also provides high reactor productivity (mass of product per mass of catalyst per unit of time) and sustained maintenance of a high level of activity and productivity with time on stream.

Polymers containing α-methylenelact(ones)(ams) such as α-methylenebutyrolactones are useful in blends with other polymers. For examples such polymers which have reactive groups are toughened by mixing with a rubbery material which has complimentary reactive groups, or polymers containing repeat units derived from α-methylenelact(ones)(ams) are toughened by mixing with polymeric core-shell particles having an elastomeric core and a specified thermoplastic shell. The properties of thermoplastics are also improved by blending with α-methylenelact(ones)(ams) such as α-methylenebutyrolactones containing (co)polymers.

The present invention relates to a production method of α-methylene lactone which comprises the following steps: (A) a step of producing an enolate intermediate by making lactone react with alkyl formate under the presence of an alkoxide base; and (B) making the enolate intermediate react with paraformaldehyde. The production method of the present invention is capable of reducing the process time, improving yield, and minimizing the contamination of a reactor.

Hair care composition comprising from about 0.1% to about 20% of a sulfopropyl(meth)acrylate compound, an alpha methylene lactone, or a mixture thereof, wherein the sulfopropyl(meth)acrylate compound and the alpha methylene lactone each have a molecular weight of less than 500 grams / mole; and a dermatologically acceptable carrier.

This invention is directed to a coating composition used for original equipment manufacturing or refinishing uses in the automotive industry, which coating composition utilizes an acrylic polymer which contains substituted or unsubstituted exomethylene lactones or lactams as a comonomer.