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Magnetic material, magnet, and rotating machine

A magnetic material and rotating machine technology, applied in the fields of magnets, magnetic materials, and rotating machines, can solve the problems of energy product reduction and difficulty in using rotating machines, and achieve the effects of reducing magnetic flux density and energy product reduction and suppression

Inactive Publication Date: 2009-12-02
HITACHI LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, although the coercive force is increased, since the energy product is reduced, it is difficult to use it in a magnetic circuit requiring high magnetic flux or a rotating machine requiring high torque (torque), etc.

Method used

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  • Magnetic material, magnet, and rotating machine
  • Magnetic material, magnet, and rotating machine
  • Magnetic material, magnet, and rotating machine

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The NdFeB alloy is hydrodehydrogenated powder having a particle size of about 1 to 1000 μm, and the coercivity of the powder at room temperature is 16 kOe. mixed with the NdFeB (main phase is Nd 2 Fe 14 B) The fluoride of the powder is NdF 3 . NdF 3 The raw material powder is pre-pulverized to form an average particle size from 0.01 to 100 μm, mixed with NdFeB powder and NdF 3 And pour it into the gap between the twin rolls. In order to make the shape of the fluoride powder into a layer, let the roll surface temperature range from 300°C to 600°C, NdFeB powder and fluoride powder are easily deformed by the roll. The fluoride is deformed into a flat shape together with the NdFeB powder by double rollers. The pressure is 100kg / cm 2 above. The magnetic powder pressed by the twin rolls forms fluoride in layers on the surface of the magnetic powder, and fluoride may be mixed as needed and pressed by the twin rolls. Mixed fluorides except NdF 3 In addition, there are...

Embodiment 2

[0022] A treatment solution for forming a dysprosium (Dy) fluoride coating film was produced as follows.

[0023] (1) Introduce 4 g of Dy acetate or Dy nitrate, which are highly soluble salts in water, into about 100 mL of water, and dissolve completely using a vibrator or an ultrasonic stirrer.

[0024] (2) Slowly add hydrogen fluoride diluted to 10% to achieve the generation of DyF 3 The equivalent of the chemical reaction.

[0025] (3) Use an ultrasonic stirrer for the gel-like precipitated DyF 3 The resulting solution was stirred for more than 1 hour.

[0026] (4) After centrifugation at a speed of 4000 r.p.m, the supernatant liquid was removed, and approximately the same amount of methanol was added.

[0027] (5) Stir the DyF containing gel 3 After the methanol solution became a suspension completely, it was stirred with an ultrasonic stirrer for more than 1 hour.

[0028] (6) Repeat the operations of (4) and (5) 4 times until no anions such as acetate ions or nitrat...

Embodiment 3

[0039] A treatment solution for forming a neodymium (Nd) fluoride coating film was prepared as follows.

[0040] (1) Introduce 4 g of Nd acetate or Nd nitric acid, which are highly soluble salts in water, into about 100 mL of water, and dissolve completely using a vibrator or an ultrasonic stirrer.

[0041] (2) Slowly add hydrogen fluoride diluted to 10% to achieve the generation of NdF 3 The equivalent of the chemical reaction.

[0042] (3) Use an ultrasonic stirrer to generate gel-like precipitated NdF 3 The solution was stirred for more than 1 hour.

[0043] (4) After centrifugation at a speed of 4000 r.p.m, the supernatant liquid was removed, and approximately the same amount of methanol was added.

[0044] (5) Stirring containing gel-like NdF 3 After the methanol solution became a suspension completely, it was stirred with an ultrasonic stirrer for more than 1 hour.

[0045] (6) Repeat the operations of (4) and (5) 4 times until no anions such as acetate ions or nitrat...

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Abstract

In the magnetic powder and magnet produced by mixing fluoride powder on the surface of NdFeB powder, the mixing amount of fluoride decreases together with the residual intermediate flux density, and the energy product decreases significantly. It is a problem to suppress such a decrease in magnetic properties. In order to solve the above problems, the fluoride is formed in layers, and the oxygen concentration, the generated phase and the lattice constant of the fluoride are controlled. In addition, the magnetic material contains magnetic powder containing rare earth elements, and fluorides containing alkaline earth elements or rare earth elements are formed on the surface of the magnetic powder, and the oxygen concentration of the fluoride is higher than that of the magnetic powder.

Description

technical field [0001] The present invention relates to a magnetic material, a magnet and a rotating machine. Background technique [0002] A conventional fluoride-containing rare earth sintered magnet is described in JP-A-2003-282312. In the prior art described above, the fluoride forms a granular grain boundary phase, and the grain size of the grain boundary phase particles is several μm. In such a sintered magnet, when the coercive force is increased, the energy product decreases significantly. The grain boundary phase on the crystal grains is mainly at the grain boundary, and there is no record about the structure and composition of fluoride in the prior art. [0003] [Patent Document 1] JP-A-2003-282312 [0004] In Patent Document 1, Table 3 describes the addition of NdFeB sintered magnet powder and DyF as a fluoride. 3 And the magnetic properties of the sintered magnet produced. Add DyF 3 At 5% by weight, the value of the residual magnetic flux density (Br) is 11...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/08
Inventor 小室又洋佐通祐一小园裕三近藤保夫
Owner HITACHI LTD