Process for preparing water-soluble ceria nanocrystalline
A cerium dioxide, water-soluble technology, applied in the field of preparation of water-soluble CeO2 nanocrystals
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Embodiment 1
[0014] Example 1: Weigh 2mmol Ce(acac) 3 ·H 2 O, add a 100ml two-necked round bottom flask, then add 20ml of 2-pyrrolidone. Insert the thermometer into one bottleneck, and insert the water-cooled reflux condenser into the other bottleneck. Heat the mixture to 75℃, Ce(acac) 3 Dissolve in 2-pyrrolidone to obtain a 0.1 mol / L 2-pyrrolidone solution of cerium acetylacetonate, heat the solution to 240°C and reflux for 60 minutes, remove the heating mantle, and cool to room temperature to obtain water-soluble CeO 2 Transparent brown sol of nanoparticles. Add 200ml of methanol to the solution, which has water-soluble CeO 2 Nanoparticles precipitate out, centrifuge the precipitate, wash the precipitate 5 times with acetone (50ml each time), and dry it with N2 flow for 4 hours to obtain light yellow water-soluble CeO 2 Nanoparticles. If a certain amount of deionized water or 2-pyrrolidone is added to the solid particles, a transparent colloidal solution can be obtained. figure 1 Is water-s...
Embodiment 2
[0015] Example 2: Weigh 4mmol Ce(acac) 3 ·H 2 O, add a 100ml two-necked round bottom flask, then add 20ml of 2-pyrrolidone. Insert the thermometer into one bottleneck, and insert the water-cooled reflux condenser into the other bottleneck. Heat the mixture to 85°C, Ce(acac) 3 Dissolve in 2-pyrrolidone to obtain a 0.2mol / L 2-pyrrolidone solution of cerium acetylacetonate, heat the solution to 225°C and reflux for 120 minutes, remove the heating mantle, and cool to room temperature to obtain water-soluble CeO 2 Transparent brown sol of nanoparticles. Add 300ml of methanol to this solution, with water-soluble CeO 2 Nano particles precipitate out, centrifuge the precipitate, wash the precipitate 5 times with acetone (80ml each time), and dry it at 50°C for 10 hours to obtain light yellow water-soluble CeO 2 Nanoparticles. Prepared water-soluble CeO 2 The diameter of the nanoparticles is about 10 nm, and the particles are spherical.
Embodiment 3
[0016] Example 3: Weigh 3mmol Ce(acac) 3 ·H 2 O, add a 100ml two-necked round bottom flask, then add 20ml of 2-pyrrolidone. Insert the thermometer into one bottleneck, and insert the water-cooled reflux condenser into the other bottleneck. Heat the mixture to 80°C, Ce(acac) 3 Dissolve in 2-pyrrolidone to obtain a 0.15 mol / L 2-pyrrolidone solution of cerium acetylacetonate. Heat the solution to 230°C and reflux for 100 minutes. Remove the heating mantle and cool to room temperature to obtain water-soluble CeO 2 Transparent brown sol of nanoparticles. Add 300ml of methanol to the sol, which has water-soluble CeO 2 Nano particles precipitate out, centrifuge the precipitate, wash the precipitate 5 times with acetone (80ml each time), and dry it at 60°C for 5 hours to obtain light yellow water-soluble CeO 2 Nanoparticles. Prepared water-soluble CeO 2 The diameter of the nanoparticles is about 8nm, and the particles are spherical.
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