Blue active dye mixture and preparation and application thereof

A technology of reactive dyes and mixtures, applied in the field of dyes, can solve the problem that the combined properties of reactive dyes cannot meet the needs, etc., and achieve the effect of good comprehensive fastness characteristics.

Active Publication Date: 2014-03-26
HUBEI COLOR ROOT TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In many cases, especially when dyeing in very dark shades, the combined properties of reactive dyes are often not sufficient

Method used

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  • Blue active dye mixture and preparation and application thereof
  • Blue active dye mixture and preparation and application thereof
  • Blue active dye mixture and preparation and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0082] Embodiment 1, formula (1) dyestuff preparation:

[0083] After beating 40.41 parts of bromine (compound of formula (4)) in an appropriate amount of water for 1 hour, add 23 parts of 3.5-diamino2.4.6-trimethylbenzenesulfonic acid (compound of formula (A-1)), Then add 2.9 parts of cuprous chloride and 4.6 parts of sodium sulfite, raise the temperature to 60°C, adjust the pH to 8 with soda ash, condense for 4 hours, refine with diatomaceous earth for 2-3 times, then acidify and salt out (add 15 parts by volume percentage) % sodium chloride for salting out; add hydrochloric acid to adjust pH=1 (acid out), filter after 2 hours, add appropriate amount of water to dissolve the filter cake, obtain a blue dye mother solution, and mix 13.5 parts of cyanuric fluoride ( The compound of formula (6)) is added dropwise into the blue dye matrix solution to undergo condensation reaction, the process control is T=10℃, pH=3.5-8.0, and the reaction is maintained for 1 hour after adding, an...

Embodiment 2

[0085] Embodiment 2, formula (1) dyestuff preparation:

[0086] After beating 40.4 parts of bromonic acid (compound of formula (4)) in an appropriate amount of water for 1 hour, add 23 parts of 3.5-diamino2.4.6-trimethylbenzenesulfonic acid (formula (A-1)) compound, add 2.9 cuprous chloride and 4.6 parts of sodium sulfite, heat up to 60°C, adjust pH=8 with soda ash, condense for 4 hours, refine 2-3 times, acidify, salt out (add 15% sodium chloride by volume percentage for salting out Add hydrochloric acid to adjust pH = 1 for acid analysis), filter after 2 hours, add an appropriate amount of water to dissolve the filter cake to obtain a blue dye matrix, add the blue dye matrix solution to 18.45 parts of fully ice-ground cyanurea for 30 minutes Condensation reaction occurs in the acid chloride (compound of formula (6)), control T=10°C, pH=3.5, maintain the reaction for 4 hours, and finally add 2.5 parts of ethylenediamine (compound of formula (7)) to the system to maintain T=45...

Embodiment 3

[0088] Embodiment 3, formula (1) dyestuff preparation:

[0089] After beating 40.41 parts of bromine (compound of formula (4)) in an appropriate amount of water for 1 hour, add 23 parts of 3.5-diamino2.4.6-trimethylbenzenesulfonic acid (compound of formula (A-1)), Then add 2.9 parts of cuprous chloride and 4.6 parts of sodium sulfite, raise the temperature to 60°C, adjust the pH to 8 with soda ash, condense for 4 hours, refine with diatomaceous earth for 2-3 times, then acidify and salt out (add 15 parts by volume percentage) % sodium chloride for salting out; add hydrochloric acid to adjust pH=1 (acid out), filter after 2 hours, add appropriate amount of water to dissolve the filter cake, obtain a blue dye mother solution, and mix 13.5 parts of cyanuric fluoride ( The compound of formula (6)) is added dropwise into the blue dye matrix solution to undergo condensation reaction, the process control is T=10℃, pH=3.5-8.0, and the reaction is maintained for 1 hour after adding, an...

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Abstract

The invention discloses a blue active dye mixture, which is characterized by comprising a mixture of dyes shown as general formulas (1), (2) and (3), wherein the weight part ratio of the dyes shown as the general formulas (1), (2) and (3) in the mixture is 80:(12-10):(10-8). The dye mixture can be applied to dyeing and printing hydroxyl-containing or nitrogen-containing fiber or a hydroxyl-containing or nitrogen-containing fiber material for ink jet printing, has high dye uptake, high leveling property, high lifting power, high water washing resistance, high light resistance and high comprehensive firm properties such as light ray resistance and dampness resistance.

Description

technical field [0001] The invention relates to a blue reactive dye mixture and its preparation and application, belonging to the field of dyes. Background technique [0002] Recently, the practice of using reactive dyes has put forward higher requirements for dyeing quality and economic efficiency of dyeing methods and environmental protection, so there is still a need for new types of dyes with good properties, high dye uptake, and especially good properties in their application. The resulting dye composition. Current dyeing requirements for reactive dyes, for example, should have sufficient substantivity, ease of washing, in addition to good color yield and high reactivity. In many cases, especially when dyeing in very dark shades, the combination properties of reactive dyes are often not satisfactory. [0003] Therefore, there is an urgent need to develop a group of dyes in the market, especially for dyes that need to be printed and dyed in very deep colors. For exampl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09B67/22D06P1/38D06P3/66
Inventor 罗润富
Owner HUBEI COLOR ROOT TECH CO LTD
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