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Processing method for increasing aromatic hydrocarbon content in petroleum fraction

A technology for the content of petroleum fractions and aromatics, which is applied in the petroleum industry, hydrotreating process, and hydrocarbon oil treatment to achieve the effect of broadening the source of petroleum fractions

Active Publication Date: 2014-11-26
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The above-mentioned production of high aromatic rubber oil is mainly prepared by solvent extraction and refining, and does not involve other processes to increase the aromatic content of petroleum fractions and its processing technology

Method used

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  • Processing method for increasing aromatic hydrocarbon content in petroleum fraction
  • Processing method for increasing aromatic hydrocarbon content in petroleum fraction
  • Processing method for increasing aromatic hydrocarbon content in petroleum fraction

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Using crude oil A as raw material, whose properties are shown in Table 1, a thermal cracking process was carried out, and the operating conditions of the thermal cracking process are shown in Table 3. The 360-520°C fraction is obtained by cutting the fraction, and the 360-520°C fraction is obtained through hydrogenation and furfural production process. The operating parameters of each production process are shown in Table 4 and Table 5. The properties of the hydrogenation catalyst are shown in Table 6. The aromatic content of each fraction is shown in Table 7.

Embodiment 2

[0016] Using crude oil B as the raw material, whose properties are shown in Table 1, a thermal cracking process was carried out, and the operating conditions of the thermal cracking process are shown in Table 3. The 360-520°C fraction is obtained by cutting the fraction, and the 360-520°C fraction is obtained through hydrogenation and furfural production process. The operating parameters of each production process are shown in Table 4 and Table 5. The properties of the hydrogenation catalyst are shown in Table 6. The aromatic content of each fraction is shown in Table 7.

Embodiment 3

[0018] Using crude oil C as raw material, whose properties are shown in Table 1, a thermal cracking process was carried out, and the operating conditions of the thermal cracking process are shown in Table 3. Cut the fraction to obtain a 360-520°C fraction, and the fraction is subjected to hydrogenation and furfural production processes to obtain a 360-20°C fraction. The operating parameters of each production process are shown in Table 4 and Table 5. The properties of the hydrogenation catalyst are shown in Table 6. The aromatic content of each fraction is shown in Table 7.

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Abstract

The invention relates to a processing method for increasing aromatic hydrocarbon content in a petroleum fraction. According to the invention, crude oil, atmospheric pressure residual oil, residual oil and a reduced pressure distillate are used as raw materials and are subjected to thermal cracking and fractionation so as to obtain a fraction prepared at a temperature of 360 to 520 DEG C; the fraction undergoes hydrorefining and solvent refining so as to obtain a petroleum fraction with a CA value of 30 to 80%; inlet temperature and pressure of thermal cracking are 360 to 480 DEG C and 0.1 to 2.0 MPa, respectively; in hydrorefining, temperature is 250 to 400 DEG C, hydrogen partial pressure is 2.0 to 20 MPa, a volume hourly space velocity is 0.2 to 2.0 / h, and a volume ratio of hydrogen to oil is 300: 1 to 1500: 1; a mass ratio of a furfural solvent to a refining solvent is 1: 1.3-3.5; the fraction is subjected to hydrorefining, olefin saturation and aromatic hydrogenation; hydrofined oil undergoes solvent refining for enrichment of aromatic hydrocarbons and polar materials in the oil so as to obtain extract oil; and aromatic hydrocarbon content in the extract oil reaches 30 to 80%.

Description

technical field [0001] The invention relates to a method for increasing the content of aromatic hydrocarbons in petroleum fractions by utilizing thermal cracking technology. Background technique [0002] Petroleum is mainly composed of three hydrocarbons: alkanes, cycloalkanes, and aromatics. The proportions of the three hydrocarbons in crude oil produced in different regions and different formations are not the same. According to the different proportions of the three hydrocarbons, they are divided into paraffins. Base, cycloalkyl, aromatic base and other crude oils. In the process of petroleum processing, the most suitable processing route and scheme are usually determined according to the type of crude oil. With the expansion of the application range of petroleum products, the demand for oil products with high aromatic content is also increasing. There are two main sources of oil products with high aromatic content, one is petroleum distillate produced from aromatic base...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G69/06
Inventor 汪军平熊春珠甄新平王华田凌燕教震朱路新
Owner PETROCHINA CO LTD