Halogenated pheromone analogue for controlling spotted cutworm
A horoscope cutworm and pheromone technology, applied in the fields of chemicals for biological control, pest control, application, etc., to achieve the effects of less consumption, lower reproduction rate, and lower encounter probability
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Embodiment 1
[0024] The preparation of embodiment 1 trans-5-tetradecenyl-2-monofluoroacetate
[0025] Compounds in the present invention can be synthesized by the same route, Figure 9 Shown is the synthesis method using trans-5-tetradecenyl-2-fluoroacetate as an example.
[0026] Dissolve 2.00g (9.42mmol) trans-5-tetradecenol in 27mL of anhydrous dichloromethane, add 8.70×10-2g of 4-dimethylaminopyridine, ice-bath, and keep the temperature at 0°C From left to right, gradually add the dichloromethane solution of fluoroacetic anhydride dropwise, after the dropwise addition, ice bath for 30min, react overnight at room temperature, remove the solvent by rotary evaporation under reduced pressure, and separate by chromatography column to obtain 2.30g (8.45mmol) of yellow oil, producing The rate is 89.5%.
Embodiment 2
[0027] Embodiment 2 field biological activity determination test
[0028] Lure preparation:
[0029] (1) The lure carrier adopts a cylindrical green concave rubber plug with a height of 1 cm and a bottom diameter of 1 cm.
[0030] (2) Mix cis-7-tetradecene acetate and cis-5-tetradecene acetate in a mass ratio of 90:8 and dilute with n-hexane to a concentration of 1 μg / μL of solution.
[0031] (3) Pipette 98 μL (1 μg / μL) of the cutworm pheromone solution above and add it to the bottom of the rubber head. The cutworm pheromone solution will penetrate into the rubber with the solvent (n-hexane). After the solvent (n-hexane) evaporated, 98 μg of cutworm pheromone was obtained.
[0032] (4) Trans-5-tetradecenyl-2-monofluoroacetate, trans-5-tetradecenyl-2-monochloroacetate, trans-5-tetradecenyl- 2,2-Difluoropropionate, trans-5-tetradecenyl-2,2-dichloropropionate, trans-5-tetradecenyl-2,2,2-trifluoroacetic acid Ester, trans-5-tetradecenyl-2,2,2-trichloroacetate, trans-5-tetrade...
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