A kind of carbon sulfur wollastonite type sulfate corrosion inhibitor and preparation method thereof

A technology of tobermorite and sulfate corrosion, which is applied in the field of building materials, can solve the problems of inability to fundamentally solve the problem of TSA durability, affect the workability of cement-based materials, long TSA incubation period, etc., so as to improve the anti-TSA damage performance. , Improve the ionic strength and concrete pore structure, the preparation process and the operation steps are simple and convenient

Active Publication Date: 2019-10-25
中建西部建设西南有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, although there have been reports on products that can resist various types of sulfate erosion damage (wollowstone type, gypsum type, calcium carbon sulfosilicate type), but usually involve a large number of raw materials, the preparation process is complicated, and the transportation cost is relatively high. high
And some research data show that after adding barium salt directly into concrete, although it can improve the TSA resistance performance of cement-based materials to a certain extent, it will affect the workability of cement-based materials, and the improvement effect of such products is only short-term effective, while TSA has a long incubation period, which cannot fundamentally solve the durability problem caused by TSA

Method used

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  • A kind of carbon sulfur wollastonite type sulfate corrosion inhibitor and preparation method thereof
  • A kind of carbon sulfur wollastonite type sulfate corrosion inhibitor and preparation method thereof

Examples

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Effect test

Embodiment 1~5

[0038] The preparation method of the tobermorite-type sulfate corrosion (TSA) inhibitor described in Examples 1-5 includes the following steps:

[0039] 1) Weigh the raw materials, and take each raw material according to the proportioning conditions described in Table 1;

[0040]2) Dissolve the weighed ion curing agent in deionized water to prepare an ion curing agent solution with a solubility of 1.5mol / L, then mix and stir with dry sepiolite powder for 1.5h, make it fully contact and place it on medium vacuum (10 2 ~10 -1 Pa) under the condition of drying to constant weight, the drying temperature is 50-60 ° C, to obtain the solid product I;

[0041] 3) Mixing: inject the obtained solid product I, mineral admixture, water glass, polyacrylamide, iron salt, and glyceryl monostearate into the mixer and mix at a high speed of 800 r / min for 10 min;

[0042] 4) Grinding: Dry the mixture obtained in step 3) in an oven at 105°C to remove its crystal water or adsorbed water, and t...

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Abstract

The invention discloses a thaumasite form of sulfate attack (TSA) inhibitor and a preparation method. Mainly constituent components of the TSA inhibitor comprise sepiolite powder, an ionic curing agent, a mineral admixture, sodium silicate, polyacrylamide, an iron salt, glycerol monostearate and the like. The TSA inhibitor can be used for effectively inhibiting the formation of thaumasite, can be used for effectively curing a SO4<2-> ion and retarding the migration rate of the SO4<2-> ion for a long time, is used for improving the pore structure and the penetration resistance of concrete, and on the basis of having no adverse influences on the workability and the mechanical performance of the concrete, can be used for effectively improving and solving the influence, which is brought to the safety of a structure, of the concrete due to the TSA; further, the sources of raw materials to which the TSA inhibitor relates are wide; the preparation process is simple; the popularization and the application are suitable.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to a tobermorite-type sulfate corrosion inhibitor and a preparation method. Background technique [0002] In modern engineering construction, cement-based materials are the most widely used man-made building materials, which constitute the main body and frame of civil engineering structures, and mainly bear the load of the main structure of the building and the erosion of climate environment; therefore, the durability of cement-based material structures Sex becomes an important feature of its performance. At present, limestone has become an important raw material in my country's cement concrete industry. However, when cement-based materials mixed with limestone powder or using limestone aggregates have sufficient sulfate, humidity and suitable temperature (generally considered to be lower than 15°C), they are very likely to suffer from tolerite-type sulfates. Erosion ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/26C04B103/60C04B103/65
CPCC04B40/0039C04B2103/60C04B2103/65C04B14/042C04B22/085C04B18/141C04B18/146C04B12/04C04B24/2652C04B24/085C04B14/106C04B22/124C04B22/12
Inventor 兰聪陈景甘戈金刘东卢佳林王晶晶
Owner 中建西部建设西南有限公司
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