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A kind of environment-friendly brass alloy for casting and its manufacturing method

A brass alloy, environmentally friendly technology, applied in the field of alloys, can solve the problems of high casting defect rate, poor stress corrosion resistance of silicon brass, difficulty in recycling waste materials, etc., and achieve good mechanical properties and casting performance, and stress corrosion resistance Good, polished and weldable results

Active Publication Date: 2019-03-01
XIAMEN LOTA INT CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Bismuth brass is prone to hot cracks during the molding process due to its Bi content, and its welding performance is poor, and because bismuth will be associated with lead during the mining process, polluting the environment, so bismuth brass has not been accepted by the European market; Its stress corrosion resistance is poor, and the product is prone to stress corrosion failure during use; while the arsenic brass developed to meet the Australian anti-dezincification requirements AS 2345-2006 (the average dezincification layer depth is not greater than 100μm) has poor alloy fluidity , large shrinkage tendency and high casting defect rate
[0005] Phosphorus, magnesium, and manganese are added to some brass to improve the properties of brass, but the introduction of these elements has brought difficulties in the recycling of waste materials

Method used

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  • A kind of environment-friendly brass alloy for casting and its manufacturing method
  • A kind of environment-friendly brass alloy for casting and its manufacturing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Preparation and component analysis of embodiment 1 alloy of the present invention and contrast alloy

[0042] a. Preparation and component analysis of alloy 1-6 of the present invention

[0043]Alloy 1-6 of the present invention is prepared according to the following method: take brass waste and old material, electrolytic copper, Zn, Al, Sn, Ni, Pb and copper-iron master alloy according to the mass percentage of alloy composition of the present invention, wherein in the copper-iron master alloy The content of Cu is 90-95wt.%. Before each furnace is smelted, an appropriate amount of non-borax slag cleaning agent is added to the furnace bottom, and then nickel, copper-iron intermediate alloy, and brass scrap are added until 1 / 4 of the brass scrap has been melted. When adding electrolytic copper on the surface, after all the materials are completely melted, add Zn, Al, Sn, Pb in turn, and stir well, after the metal is completely melted, heat up to remove the slag, and ...

Embodiment 2

[0050] The performance detection of embodiment 2 alloy of the present invention and contrast alloy

[0051] The properties of the alloys of the present invention and comparative alloys obtained from the above preparation examples will be tested below. The specific performance testing items and methods are as follows. Please refer to Table 2 for the testing results.

[0052] 1. Casting performance

[0053] Bar sample: used to determine the linear shrinkage of the alloy, the lower the linear shrinkage, the stronger the alloy's resistance to thermal cracking. The alloy melt is cast on a bar-shaped sample mold with a length of 200 mm at a temperature of 1050 ° C. After cooling, the linear shrinkage rate is calculated by measuring the gap distance between the mold and the alloy sample.

[0054] Spiral sample: The alloy melt is cast on the spiral sample mold at a temperature of 1050°C, and the flow length of the alloy melt is measured to measure the fluidity of the alloy. The lo...

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Abstract

Disclosed are an environmentally friendly brass alloy for casting and a manufacturing method therefor. The brass alloy is free of the elements selenium, tellurium, antimony, phosphorus, magnesium and manganese, and the components thereof are: 58-61.5 wt.% of Cu, ≤ 0.25 wt.% of Pb, 0.5-0.8 wt.% of Al, < 0.1 wt.% of Sn, < 0.1 wt.% of Ni, 0.02-0.15 wt.% of Fe, and 5-12 ppm of B, with the balance being Zn and inevitable impurities. In addition to excellent polishing performance and hot tearing resistance performance, the brass alloy has good comprehensive performance, and is suitable for casting formed bathroom plumbing parts.

Description

technical field [0001] The invention belongs to the field of alloy technology, and specifically relates to a lead-free environment-friendly brass alloy for casting which is different from bismuth brass, silicon brass and arsenic brass and does not contain selenium, tellurium, antimony, phosphorus, magnesium and manganese elements and its method of manufacture. Background technique [0002] Lead brass contains 1wt.%-4wt.% lead. Because of its excellent cutting and forming properties and low cost, it is widely used in various fields such as electrical, mechanical, and plumbing. However, because lead brass will pollute the environment and endanger human health in the process of production and use, the United States, the European Union, Japan and other developed countries and regions have successively formulated lead-free standards and laws, such as NSF-ANSI61, NSF-ANSI372, AB-1953, RoHS, etc. Among them, the U.S. AB-1953 defines "lead-free" as the Pb content not exceeding 0.2...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C9/04C22C1/03C22C1/06
CPCC22C1/03C22C1/06C22C9/04C22C1/02C22F1/08
Inventor 龙佳张华威毕秋林明源吕青张卫星胡振青
Owner XIAMEN LOTA INT CO LTD
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