The invention relates to a process for producing protecting pipes of thermocouples, which is composed of three parts of a process for producing cores, a process for dip-coating and a process for combining boxes to cast. The invention comprises firstly, producing sand cores in a wood-made box which is composed of an upper half and a lower half, arranging sand cores which are produced into an iron slot which contains coating materials and dip-coating, reserving after drying, lastly, arranging the sand cores which are dip-coated with the coating materials on an upper sand box and a lower sand box, molding closely, and casting, finishing steps of cutting, hole-filling and wire-coning on a turning machine after polishing, and obtaining qualified protecting pipes of the thermocouples. The invention has the advantages that firstly, a plurality of common casting defects can be avoided and eliminated, finished product rate is increased from 70% to 95%, secondly, the preciseness of casts can be increased greatly, un-straightness is 0.5%, and the tolerance of wall thickness is +-1.5, thirdly, mechanical processing has good performance with non hard points which are easy to appear on thin-wall casts and hard phases of carbides, the conditions of surface electric plating and enamels are good with no tiny defects such as needle holes which affect electric plating, enamels and sand holes, and fourthly, the finished product rate of casting processes can reach 85%.