Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Method for degrading bisphenol A by activating sodium percarbonate with nanometer zero valent iron

A nano-zero-valent iron and sodium percarbonate technology, applied in the field of analytical chemistry, can solve the problems of biological organism growth and reproduction and adverse effects of endocrine, difficulty in separation and recycling, high cost of iron sludge treatment, etc., to achieve stable activity, high activity, easy-to-handle effects

Inactive Publication Date: 2021-05-14
CHINA UNIV OF GEOSCIENCES (WUHAN)
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Even when its concentration is very low, it can still cause adverse effects on the normal growth, reproduction and endocrine of biological organisms
In the related art, the traditional Fenton reagent is used to process bisphenol A, and there is a large amount of Fe 2+ It is difficult to separate, recycle and reuse, a large amount of iron sludge is produced after the reaction, the treatment cost is high, and liquid H 2 o 2 Inconvenient storage and transportation, easy to decompose and unstable

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for degrading bisphenol A by activating sodium percarbonate with nanometer zero valent iron
  • Method for degrading bisphenol A by activating sodium percarbonate with nanometer zero valent iron
  • Method for degrading bisphenol A by activating sodium percarbonate with nanometer zero valent iron

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 2

[0033] The method according to Embodiment 1 of the present invention uses nanometer zero-valent iron to degrade bisphenol A, comprising the following steps:

[0034] (1) Preparation of nanometer zero-valent iron (nFe 0 ); The preparation process of the nanometer zero-valent iron is:

[0035] (1-1) First boil the ultrapure water for 20 minutes, then pass high-purity nitrogen into the ultrapure water for 30 minutes to remove the oxygen and cool it to obtain anaerobic water, and weigh 0.01mol of FeSO 4 ·7H 2 O and 0.02 mol of NaBH 4 respectively dissolved in 50ml of anaerobic water to obtain FeSO 4 solution and NaBH 4 solution;

[0036] (1-2) The configured FeSO 4 ·7H 2 The O solution was placed in a three-necked flask equipped with mechanical stirring, and NaBH was slowly and evenly added dropwise to it with a rubber dropper. 4 solution, mechanical stirring during the dropping process, Fe 2+ with BH 4 - The ions react as follows:

[0037] Fe 2+ +2BH 4 - +6H 2 O→n...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
specific surface areaaaaaaaaaaa
diameteraaaaaaaaaa
Login to View More

Abstract

The invention discloses a method for degrading bisphenol A by activating sodium percarbonate with nanometer zero-valent iron, and catalytically activating sodium percarbonate to degrade bisphenol A after preparing nanometer zero-valent iron. The reaction conditions are mild and easy to operate; nanometer zero-valent iron is used as the reaction system The catalyst activates the oxidant sodium percarbonate to generate OH and O 2 ·‑ Free radicals degrade bisphenol A, the degradation process is simple, and the degradation efficiency is high; the catalyst can be recycled and reused, and the oxidant is convenient for storage and transportation, with high activity and stability.

Description

technical field [0001] The invention belongs to the technical field of analytical chemistry, and in particular relates to a method for degrading bisphenol A by activating sodium percarbonate with nanometer zero-valent iron. Background technique [0002] With the rapid development of my country's industry, a large amount of industrial production wastewater containing various pollutants has been discharged, which has caused increasingly serious impacts on the environment. Bisphenol A (BPA), as one of the most produced chemical raw materials in the world, is also a representative environmental endocrine disruptor. Even when its concentration is very low, it can still cause adverse effects on the normal growth, reproduction and endocrine of biological organisms. In the related art, the traditional Fenton reagent is used to process bisphenol A, and there is a large amount of Fe 2+ It is difficult to separate, recycle and reuse, a large amount of iron sludge is produced after th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/72B01J23/745B01J35/02C02F101/34
CPCB01J23/745B01J35/023C02F1/72C02F1/725C02F2101/345
Inventor 鲍建国柳翔郑汉
Owner CHINA UNIV OF GEOSCIENCES (WUHAN)
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com