932 results about "Carbonate sodium" patented technology

The invention belongs to the technical field of sandy soil reinforcement, and relates to a sandy soil reinforcement method combining modified chitosan film coating and cementation with biomimetic mineralization and application, the sandy soil reinforcement method comprises the following steps: S1, chitosan is subjected to swelling, alkalization, carboxymethylation and refining treatment to obtain modified chitosan; s2, respectively preparing a calcium chloride solution and a sodium carbonate solution with the same concentration; a calcium chloride solution is a cementing solution A; adding modified chitosan into a sodium carbonate solution, and uniformly stirring to form a cementing solution B; s3, the cementing liquid A is sprayed to the sandy soil, then the cementing liquid B is sprayed, and primary cementing is completed; carrying out circulating cementing for 5-20 times according to the spraying mode; and then air drying is conducted to complete sandy soil reinforcement. According to the invention, the agglomeration among calcium carbonate particles is enhanced by utilizing the cementing, film covering, mineralized crystal form adjusting and filling coupling effects of the modified chitosan, so that the calcium carbonate particles form effective cementing connection among sand particles, thereby improving the mechanical properties of the sand.

The invention relates to the technical field of fluorite ore beneficiation, discloses a fluorite ore flotation composite collecting agent and a preparation method and application thereof, and aims to solve the problems that an existing collecting agent is limited in applicability, insufficient in selectivity, poor in environmental stability and the like and is difficult to deal with separation of fluorite ore containing various impurities or under complex working conditions. The composite collecting agent is composed of dehydroabietylamine, sodium oleoyl sarcosinate, sodium silicate-citric acid composite salt, ethylene glycol butyl ether and a sodium carbonate-sodium bicarbonate buffer pair, all the components have a synergistic effect, dehydroabietylamine provides selective collecting and fine particle agglomeration functions, sodium oleoyl sarcosinate enhances adsorption stability, the composite salt inhibits gangue in a targeted mode, and therefore the adsorption efficiency is improved. Buffer pairs and ethylene glycol butyl ether guarantee the environmental adaptability of a system. The collecting agent can adapt to various fluorite ores with high sulfur, high silicon, low temperature and the like, can stably play a role under different water quality and working conditions, realizes efficient separation of fluorite and impurities, improves the separation efficiency and the concentrate quality, and is flexible in preparation process and convenient for industrial application.

The invention relates to the technical field of environmental protection, and discloses a method for degrading formamide organic wastewater and recycling key metals of a retired lithium ion battery. The method comprises the following steps: S1, obtaining the positive electrode material of the retired lithium ion battery, mixing the positive electrode material with formamide organic wastewater, and carrying out hydrothermal reaction to obtain a leachate; s2, adjusting the pH value of the leachate to 6-14, and carrying out a transition metal precipitation reaction to obtain a transition metal hydroxide precursor and a lithium-rich filtrate; and S3, adding a sodium carbonate solution into the lithium-rich filtrate, carrying out a precipitation reaction, and collecting lithium carbonate. The formamide organic wastewater serves as an endogenous reducing agent, deep degradation of the formamide organic wastewater is achieved under the hydrothermal condition, efficient leaching of key metal in the retired lithium ion battery is achieved, and waste is treated with waste; the formamide degradation efficiency can reach 90% or above, and the defects that an existing formamide wastewater treatment method is high in energy consumption, large in reagent consumption, high in cost, low in degradation efficiency and large in environmental treatment pressure are overcome.

The invention relates to the technical field of resource recycling of manganese-containing wastewater, in particular to a process for preparing industrial-grade manganese carbonate by using a recycled manganese chloride solution, which adopts a two-stage purification and impurity removal strategy, performs primary purification and impurity removal by using sodium sulfide and sodium fluoride, and performs secondary impurity removal by using iminodiacetic acid grafted chelating resin. According to the invention, the problems of poor adaptability and incomplete impurity removal of the manganese chloride solution in the prior art are solved, the purity of the product is obviously improved so as to meet the requirements of the industrial grade manganese carbonate, and the process flow is simple.

The invention provides a preparation method and application of low-bath-ratio and high-viscosity hydroxypropyl carboxymethyl composite starch ether, and relates to the technical field of starch deep processing. The method comprises the following steps: S1, premixing corn starch with a compound base catalyst and magnesium stearate, and spraying an ethanol water solution for alkalization; s2, adding epoxypropane to carry out first-stage etherification, and then adding sodium chloroacetate to carry out second-stage etherification; and S3, after the reaction is finished, performing vacuum drying, crushing and sieving to obtain the high-viscosity hydroxypropyl carboxymethyl composite starch ether. Wherein the composite alkali catalyst comprises sodium hydroxide, sodium carbonate and calcium oxide. The starch ether obtained by the method has the advantages of high substitution degree, high viscosity, low solvent consumption and low energy consumption, and overcomes the defects of the traditional semi-dry method.

The invention relates to a method for selectively leaching and regenerating a positive electrode material from a waste lithium ion battery, and belongs to the technical field of lithium ion batteries. The method comprises the following steps: discharging, disassembling, crushing, calcining and screening the waste lithium ion battery, adding an obtained positive active material into an oxalic acid solution, and stirring and reacting at 60-80 DEG C under the irradiation of an ultraviolet lamp to obtain a leaching solution rich in metal elements and leaching residue iron phosphate; adding sodium carbonate into the leachate for reaction to obtain lithium carbonate; and ball-milling and mixing iron phosphate, lithium carbonate and a carbon source, drying and calcining to obtain the regenerated lithium iron phosphate positive electrode material. The oxalic acid system is catalyzed by ultraviolet light to generate hydroxyl free radicals with strong oxidizing property, so that the leaching efficiency of lithium is remarkably improved, and the dissolution of iron is inhibited, thereby realizing the efficient separation of lithium and iron. The leaching residue is high-purity iron phosphate, lithium in the leaching solution is recycled in the form of lithium carbonate, and the leaching residue and the lithium carbonate can be directly used for regenerating the lithium iron phosphate positive electrode material as precursors, so that the technological process is greatly simplified, and the production cost is reduced.

The invention discloses micron-sized pearl glaze ceramic and a preparation method thereof, and relates to the technical field of ceramic, and the micron-sized pearl glaze ceramic is characterized by comprising a ceramic body, a toning ground coat layer and a dry particle layer, the toning ground coat layer is prepared from the following raw materials in parts by weight: 15 to 25 parts of quartz, 20 to 30 parts of feldspar, 5 to 10 parts of kaolin, 3 to 8 parts of calcined zinc oxide, 5 to 10 parts of calcium carbonate, 8 to 15 parts of barium carbonate, 8 to 15 parts of zirconium silicate, 0.05 to 0.5 part of toning metal oxide and 1 to 3 parts of functional additive; the dry particle layer is prepared from the following raw materials in parts by weight: 30 to 40 parts of quartz sand, 10 to 15 parts of borax, 5 to 8 parts of sodium carbonate, 3 to 6 parts of lithium carbonate, 10 to 18 parts of Bi2O3, 10 to 18 parts of TiO2, 0.5 to 2 parts of rare earth oxide and 0.5 to 2 parts of nucleating agent. The prepared ceramic shows soft and layered pearl luster under light rays of different angles, and the physical performance is greatly improved.

The invention belongs to the technical field of lithium battery material recovery, and particularly relates to a method for recovering a waste lithium iron phosphate positive electrode material. The method comprises the following steps: (1) grinding and sieving the positive electrode material of the waste lithium iron phosphate battery, mixing with an alkaline solution, stirring and leaching, and carrying out solid-liquid separation to obtain a lithium-rich solution and leaching residues; (2) introducing a saturated sodium carbonate solution into the obtained lithium-rich solution, carrying out heating reaction, filtering, taking a solid phase, and drying to obtain lithium carbonate; and the obtained leaching residues are dried, and ferroferric oxide is obtained. According to the method, the waste lithium iron phosphate battery positive electrode material is leached through the alkaline liquid phase, it can be guaranteed that lithium and iron in waste lithium iron phosphate are separated through a one-step leaching method, and therefore selective lithium extraction is achieved. The whole technological process is convenient to operate, mild in reaction condition and low in energy consumption, does not need to use any acid or oxidant, avoids generation of a large amount of waste liquid and harmful gas, and is high in selective lithium extraction efficiency.

The invention discloses a method for intensively leaching chromium from vanadium extraction waste slag, and belongs to the field of metallurgical chemical industry. According to the method, diboron trioxide serves as a catalyst, vanadium extraction waste slag, sodium carbonate and sodium hydroxide serve as raw materials, the raw materials and the catalyst are mixed according to a set proportion, and leaching is conducted after roasting is conducted in a microwave muffle furnace. According to the method provided by the invention, the reaction can be promoted to be efficiently carried out at medium and low temperatures, the extraction rate of chromium can reach 95% or above, and the synergistic effect of'low addition amount-high catalytic efficiency 'can be realized under the condition that a small amount of catalyst is added.

The invention provides a zinc-copper-nickel-copper smelting deslagging agent and a preparation method and a use method thereof. The zinc-copper-nickel-copper smelting deslagging agent comprises the following raw materials in percentage by mass: 5-15% of calcium fluoride, 20-30% of sodium carbonate, 5-15% of sodium fluoride, 10-20% of sodium hexafluoroaluminate and the balance of borax. Compared with the prior art, the zinc-copper-nickel-copper slag remover prepared by mixing the raw materials can effectively reduce impurities to be less than 0.14% of Fe, less than 0.005% of Pb and less than 0.003% of Si in the smelting process, the impurity components are obviously reduced, the number of times of component adjustment and unqualified sampling is reduced, impurities mixed in a casting blank are reduced, and finally the metal purity and the casting quality are improved. Meanwhile, loss of zinc and nickel is reduced to the maximum extent; and adverse effects on the zinc-copper-nickel alloy are avoided.

The invention provides a preparation method of a lyocell and polyester interwoven fabric, which is characterized in that the preparation method comprises preparation and dyeing and finishing processes of a lyocell polyester fabric, and the dyeing and finishing processes comprise a lyocell anti-fibrillation treatment process, a polyester dyeing process and a lyocell dyeing treatment process; wherein the lyocell anti-fibrillation treatment process comprises the following steps: adding an anti-fibrillation aid KR-6347 according to 1%-4%, then adding anhydrous sodium sulphate, treating for 8-15 minutes, heating to 60-70 DEG C, adding 10-25 g / L sodium carbonate, continuing for 30-50 minutes, then cooling, draining water and cleaning. The lyocell terylene fabric is woven into knitted single jersey through knitting equipment in a yarn matching mode of separating lyocell terylene, separating lyocell and spandex. The fabric structure and the dyeing and finishing process are reasonable, the fibrillation degree of the fabric is greatly reduced through the dyeing and finishing process, the fastness to washing is high, and the breathable effect of the fabric is better under the wet condition after dyeing and finishing.

According to the method, sodium carbonate, limestone and coke are used as sintering aids and are uniformly mixed with the high-iron Bayer process red mud, the mixed material is sintered by adopting a one-step low-calcium reduction sintering process, and the sintered clinker is subjected to water leaching and dissolution to obtain a sodium aluminate crude solution and filter residues. And returning the sodium aluminate crude liquid to an aluminum oxide industrial production line to prepare aluminum oxide, and carrying out a hydrolysis alkali recovery process on filter residues to obtain industrial sodium carbonate. The hydrolysis residues are subjected to magnetic separation and recovery to obtain fine iron powder, and the remaining tailings are completely harmless and can be used as raw materials of building materials or used for soil backfilling. The process is characterized in that the one-step low-calcium reduction sintering temperature is 200-300 DEG C lower than the sintering temperature of a sintering method, and the energy consumption is low; na2CaSiO4 is a sintering target product, Ca2SiO4 generally generated by a traditional sintering method is not generated, the situation that Ca2SiO4 is hydrolyzed in the water leaching process to inhibit dissolution of aluminum oxide is avoided, and the recycling rate of aluminum oxide is increased while the using amount of limestone is greatly reduced. The technological process is simple, efficient, energy-saving and free of three-waste emission, and the method is a novel method capable of treating the high-iron red mud in a large-scale and reduction mode.

The invention provides a method for short-process all-component echelon recovery of a waste hydrogenation catalyst, and relates to the field of solid waste treatment. The recovery method of the waste hydrogenation catalyst comprises the following steps: roasting the waste hydrogenation catalyst and sodium carbonate to obtain a roasted product; the roasted product is leached with water, and leaching liquid and leaching residues are obtained; extracting the leaching solution by using an extracting agent to obtain a vanadium-molybdenum-containing organic phase, sequentially carrying out reverse extraction treatment on the vanadium-molybdenum-containing organic phase by using a strong alkaline reverse extraction agent and a weak alkaline reverse extraction agent to obtain a vanadium reverse extraction solution and a molybdenum reverse extraction solution, and carrying out vanadium precipitation treatment on the vanadium reverse extraction solution to obtain ammonium metavanadate; acidizing the molybdenum strip liquor to precipitate molybdenum to obtain ammonium molybdate; carrying out sintering treatment on the leaching residues and alkaline substances, leaching obtained calcine with water to obtain water leaching residues and filtrate, and carrying out aluminum precipitation treatment on the filtrate to obtain aluminum hydroxide, aluminum oxide or pseudo-boehmite; and reducing and smelting the water leaching residues to obtain the ferro-nickel alloy. According to the invention, multi-element comprehensive recovery of all components of vanadium, molybdenum, nickel, aluminum and sulfur can be realized, and high-value utilization of all components of the waste hydrogenation catalyst is realized.

The invention discloses a nitrogen-doped carbon nanotube modified magnetic pyrite composite catalyst as well as a preparation method and application thereof, and belongs to the technical field of water treatment. The nitrogen-doped carbon nanotube modified magnetic pyrite composite catalyst is prepared from the following raw materials: multi-walled carbon nanotubes, a concentrated nitric acid solution, melamine, magnetic pyrite powder and sodium percarbonate. According to the preparation method, magnetic pyrite and nitrogen-doped carbon nanotubes are mixed according to the ratio of 15: 1, nitrogen heat treatment is performed for 3 h at the temperature of 600 DEG C to form a composite carrier, and then activation treatment is performed through sodium percarbonate to obtain the catalyst. According to the catalyst, the electron transfer capacity and adsorption performance are enhanced through the nitrogen-doped carbon nanotubes, Fe < 2 + > / Fe < 3 + > circulation of the magnetic pyrite is cooperated, and the dual effects that sodium percarbonate is efficiently activated to generate free radicals to degrade pollutants and rapid recovery is achieved through magnetism can be achieved. The catalyst prepared by the invention is suitable for deep treatment of organic matters and heavy metals in industrial wastewater, and has the advantages of wide pH adaptation range, no secondary pollution and recyclability.

The invention belongs to the technical field of functional nano materials, and particularly relates to a preparation method of a detachable engine type braking nano motor, a nano drug carrier is jointly composed of HMSN and CAT modified PNA, tetraethyl orthosilicate serves as a silicon source, and solid silicon dioxide balls are synthesized; on the basis, tetraethyl orthosilicate is used as a silicon source, CTAB is used as a pore-forming agent to synthesize mesoporous silica coated solid silica spheres; etching the core silicon dioxide ball through sodium carbonate to obtain a hollow mesoporous silicon dioxide ball; then, amino modification is carried out on the CAT modified PNA2 through 3-aminopropyltrimethoxysilane, PNA1 is connected with HMSN through an amido bond, and a double-chain structure is formed by the CAT modified PNA2 and PNA1 through complementary base pairing. According to the nano motor provided by the invention, the engine CAT of the nano motor can be detached by adding the unwinding chain PNA3, so that in-vivo deceleration and braking are realized.

The invention discloses high-performance compound bentonite for drilling mud and a preparation method of the high-performance compound bentonite, and relates to the technical field of bentonite, and the high-performance compound bentonite comprises the following raw materials in parts by weight: 80-100 parts of mixed bentonite, 4-6 parts of sodium carbonate, 0.3-0.5 part of sodium humate, 0.2-0.4 part of triethanolamine and 0.2-0.4 part of a surfactant. Through the synergistic effect of the bentonite A with the high montmorillonite content, the bentonite B with the high expansion multiple and the bentonite C with the medium water absorption rate, in cooperation with sodium modification and assistant regulation and control, the product viscosity is stable, the requirement for the sand-carrying capacity of the drilling fluid is met, the filter loss is far lower than that of a traditional product, the filter cake thickness is smaller than or equal to 1.2 mm, the structure is compact, water permeation can be effectively controlled, the well wall can be stabilized, and the drilling fluid can be used for well drilling. The problem that single raw ore is insufficient in viscosity or too high in filter loss is solved.

The invention provides a method for determining boron element in iron ore, which comprises the following steps: weighing 0.2 g of sample, uniformly mixing with a flux, heating to red at 700-800 DEG C, cooling, adding sodium peroxide for secondary melting, dissolving in water, and transferring to a beaker; adding ethanol to boil, fixing the volume to 500mL, filtering and taking 100mL, adjusting the pH value, adding hydrogen peroxide to slightly boil, cooling, adding barium carbonate to boil, diluting and filtering, and taking 25mL for color development determination. According to the method, sodium carbonate and / or potassium carbonate and sodium peroxide are adopted to form a composite flux, an iron ore sample is completely decomposed through secondary melting and step-by-step dissolution, and the sample decomposition efficiency is improved; the method is stable in recovery rate, is superior to a conventional method in precision, can accurately measure the boron content in the iron ore, meets the technical requirements on boron element detection in the fields of ferrous metallurgy, geological exploration and the like, provides an efficient and reliable detection means for boron content analysis, and ensures the accuracy and reproducibility of a detection result.

The invention relates to the technical field of sodium silicate production, and particularly discloses a method for preparing sodium silicate by dissolving fluorine-containing silicon dioxide with alkali lye, which comprises the following steps: step 1, adding fluorine-containing silicon dioxide, sodium carbonate and water into a reaction kettle with a stirrer and a heating device to obtain a mixed material; 2, fully and uniformly stirring the mixed material obtained in the step 1, heating the mixed material by using a reaction kettle, and controlling the reaction temperature and the reaction time for reaction; and 3, filtering and separating the reaction product obtained in the step 2 to obtain a sodium fluoride filter cake and a sodium silicate solution. Sodium carbonate and sodium bicarbonate are used for dissolving silicon dioxide in a liquid phase reaction to prepare sodium silicate, the process is green and environment-friendly, sodium carbonate in chemical production can be effectively utilized, energy is saved, consumption is reduced, and the environment is protected. The technical problems that in the prior art, the temperature is high in the reaction process, a large amount of heat needs to be consumed, and energy consumption is high are solved.

The invention relates to a method for preparing thick mud from shield siltstone slag to prevent slurry loss, and belongs to the technical field of urban underground engineering construction. The method for preparing thick mud from shield siltstone slag to prevent slurry loss comprises the following steps: preparation of slurry: taking bentonite slurry as base slurry, and then adding waste weathered rock powder, calcium carbonate, sodium carbonate, xanthan gum or electropositive gel to prepare plastic flowing slurry, so that the slurry reaches certain density and viscosity; in the tunneling process of the shield tunneling machine, prepared slurry is injected out of a shield shell through a plurality of grouting holes in the radius direction and formed in the circumferential direction of the shield shell of the shield tunneling machine, and the slurry is diffused along the surface of the shield shell and fills gaps of a shield body within a certain range; according to the method, the waste soil generated by the shield tunnel can be effectively utilized, the moisture content and fluidity of the cabin soil are controlled, meanwhile, shield tail cement grout is prevented from entering the cutterhead and the soil cabin to threaten construction safety, operation is easy and economical, and the construction efficiency is improved.

The invention belongs to the technical field of wastewater treatment, and particularly relates to an intelligent dosing system and method for hardness and alkali removal wastewater. The monitoring unit is used for monitoring calcium hardness, magnesium hardness and alkalinity of inlet water and outlet water and monitoring the pH value in a reaction tank 1; the control system is in communication connection with the monitoring unit, receives the monitoring data, and is used for selecting a dosing mode according to the calcium hardness, magnesium hardness and alkalinity data of the inlet water, calculating the dosing amount and feeding back and adjusting the dosing and pH value according to the monitoring data of the outlet water; the chemical adding unit comprises a lime chemical adding device, a sodium hydroxide chemical adding device and a sodium carbonate chemical adding device which are respectively connected with the control system, and corresponding chemicals are added according to instructions of the control system; the treatment unit sequentially comprises a coagulation tank, a reaction tank 1, a reaction tank 2, a flocculation tank and a sedimentation tank. According to the invention, through automatic intelligent dosing, the purpose of removing alkalinity and hardness in water at the lowest cost is achieved.

The application provides a clean recycling method of waste lithium iron phosphate positive electrode material, which comprises the following steps: (1) the waste lithium iron phosphate positive electrode material is pretreated to separate aluminum foil, a binder and carbon, and a mixture containing phosphorus, iron and lithium is obtained; (2) the mixture is subjected to oxidative leaching in a sodium hydroxide solution, and the obtained mixed slurry is subjected to solid-liquid separation to obtain iron hydroxide precipitation and a leaching solution; (3) sodium carbonate and the leaching solution are mixed, lithium is precipitated, and solid-liquid separation is performed to obtain lithium carbonate and a separation solution; the separation solution is subjected to crystallization and solid-liquid separation to obtain sodium phosphate crystals; (4) the lithium carbonate in step (2), the iron hydroxide precipitation in step (3), phosphoric acid and carbon powder are mixed, and calcination is performed to obtain lithium iron phosphate. The clean recycling method can realize high-purity and high-efficiency recycling of the waste lithium iron phosphate positive electrode material, and the process flow is clean and environmentally friendly.

The present application aims at the problems of excessive consumption of traditional cement limestone resources, excessive energy consumption and high carbon emission, and provides a carbonated hardened low-calcium cement and a preparation and hardening method thereof, which is a hardening method for curing low-calcium cement by CO2 carbonation. The mass percentage composition of cement raw material components is: limestone: 60-70%, sandstone or clay or silica ash: 15-25%, phosphogypsum, fluorogypsum or desulfurization gypsum: 5-25%, component A: 0.5-2%. Component A is composed of the following raw material components in mass percentage: fluorite 0-50%, barium slag: 0-50%, lithium slag 0-50%, wood ash 0-50%, industrial sodium carbonate 0-30%. The composition design of carbonated hardened cement clinker minerals is C2S: 10-90%, C5S2$: 10-90%, C$: 0-5%, C4A3$: 0-10%, etc. In the present application, the limestone required for the cement clinker is lower than that of ordinary Portland cement clinker, the calcination temperature is reduced by 200-350 DEG C than that of ordinary Portland cement clinker, and the energy consumption and carbon emission are significantly lower than those of Portland cement; the low-calcium cement is hardened by CO2 carbonation curing, which can make the cement obtain excellent mechanical properties within 2 hours.

The invention discloses a preparation process of polyether-ether-ketone, and relates to the technical field of preparation of inorganic compounds. The preparation process comprises the following steps: reacting 4, 4 '-difluorobenzophenone, sodium carbonate and hydroquinone to generate polyether-ether-ketone, taking a polyaryletherketone block oligomer as an end-capping reagent, reacting 4, 4'-difluorobenzophenone with 4, 4 '-dimercaptodiphenyl sulfone, and then reacting with pentaerythritol phosphate to obtain the polyaryletherketone block oligomer. The thioester bond reversibly breaks at the polymerization temperature, exposed active sulfenyl reacts with hydroxyl at the tail end of the polyether-ether-ketone to form a more stable covalent bond, volatilization of the end-capping reagent is avoided, meanwhile, the initial decomposition temperature of the end-capped polyether-ether-ketone is increased, and the stability of the end-capping reagent is improved. The polyether-ether-ketone generated in the polyether-ether-ketone resin product is subjected to treatment procedures of crushing, organic solvent extraction, water washing, filtering, drying and the like, so that the product polyether-ether-ketone is obtained, less three wastes are generated, the solvent can be recycled, the atom economy is relatively high, and the preparation process of comprehensive utilization of resources is realized.

The application provides a kind of shaped phase change material and its preparation method.The phase change material includes the following component materials according to mass percentage: 45.8-56.7% of dodecahydrate disodium hydrogen phosphate, 7.9-22.9% of sodium carbonate decahydrate, 7.6-15.9% of sodium sulfate decahydrate, 2.46-4.05% of reinforcing material, and 15-20% of adsorption material.The preparation of the phase change material includes the following steps: 1, preparing materials;2, preparing inorganic salt mixture;3, preparing molten inorganic salt mixture;4, preparing mixture and sealing;5, preparing shaped phase change material.The shaped phase change material prepared by the application has suitable phase change temperature, higher latent heat of phase change, no liquid leakage, no toxicity and non-combustibility, small supercooling degree, and no phase separation;at the same time, for the application occasions requiring transportation and storage between 20-30℃, the shaped phase change material can be used as an effective normal temperature cold storage agent to resist low temperature environment and protect specific chemicals and medicines from temperature fluctuation.

The invention relates to the technical field of sewage treatment, in particular to an urban sewage treatment plant sludge deep dehydration conditioner and an application method thereof, and the urban sewage treatment plant sludge deep dehydration conditioner comprises the following raw materials: functional layered composite powder, cationic polyacrylamide, diatomite and sodium carbonate. After the functionalized layered composite powder and the bentonite are organically modified by the lauryl trimethyl ammonium bromide, the interlayer spacing is obviously increased, the hydrophobic property and the cation exchange capacity are excellent, negative charges on the surface of sludge colloid can be efficiently neutralized, a double-electrode-layer structure can be destroyed, and part of bound water can be released; ferric hydroxide deposited on the surface serves as amphoteric metal hydroxide, further compresses double electric layers through electric neutralization, forms an amorphous net structure and serves as a high-efficiency adsorption flocculation net to capture fine sludge particles; under the synergistic effect of the powder and cationic polyacrylamide, efficient removal of water combined with sludge and water in cells is achieved, and the dual purposes of deep dehydration and mud cake volume reduction are achieved.

The invention provides equipment and a process for recycling battery-grade lithium carbonate by roasting waste residues of an aluminum electrolysis cell with assistance of aluminum salt, and relates to the technical field of lithium carbonate preparation, the equipment comprises a reaction kettle body, a stirring mechanism, a driving mechanism and a medicament adding mechanism; the stirring mechanism comprises a stirring shaft which is vertically and rotatably connected to the interior of the reaction kettle body, and the stirring mechanism is used for mixing the sodium carbonate precipitant and the filtrate. According to the scheme, a stirring shaft finally drives a driving disc and a shifting plate to rotate anticlockwise, a rotating disc and a convex disc are driven to intermittently rotate clockwise under the cooperation of a driving block and a driven block, and the convex disc intermittently rotates to press a piston rod and a piston downwards through a contact piece, so that a sodium carbonate solution is conveyed to a water dropper through a liquid outlet hose; through intermittent rotation of the convex disc, the sodium carbonate solution is intermittently and slowly dropwise added into the filtrate, the lithium precipitation reaction concentration is accurately controlled, and the phenomenon that the added sodium carbonate solution has instantaneous extremely-high local supersaturation degree in the reaction kettle is avoided.

A method for recovering platinum group precious metal in a silicon carbide DPF catalyst comprises the steps that S1, smelting treatment is conducted, specifically, the silicon carbide DPF catalyst is crushed and then mixed with a smelting agent in a layered mode, a smelting reaction is conducted at the high temperature, and the smelting agent is composed of sodium carbonate and sodium peroxide; s2, leaching and separation are conducted, specifically, after the smelting product obtained in the step S1 is cooled, acid leaching treatment is conducted through hydrochloric acid, leaching liquid containing platinum group precious metal and residues are obtained through filtering separation, the residues are washed, and washing liquid is added into main leaching liquid; and S3, precious metal enrichment is conducted, specifically, the leachate obtained in the step S2 is enriched through a chemical precipitation method, the obtained precipitate is dissolved with aqua regia, and a platinum-palladium chloride mixed solution is obtained. The method is high in recovery rate, and under the optimal condition, the recovery rate of platinum can reach 91% or above, and the recovery rate of palladium can reach 96% or above; the process is simple, the cost is controllable, the used smelting agent is a common chemical raw material, and the cost is low.

The invention provides a lithium slag flotation desulfurization method, a ceramic tile doped with lithium slag and a preparation method of the ceramic tile, and the method comprises the following steps: controlling the particle size of the lithium slag to be treated within a preset particle size range, adding water into the lithium slag, and blending into ore pulp with preset solid content; sodium dodecyl sulfate and xanthate serve as collecting agents to be added into the ore pulp, sodium silicate serves as an inhibitor to be added into the ore pulp, and sodium carbonate is adopted to adjust the pH of the ore pulp to be within the preset pH range; and stirring the ore pulp of which the pH is adjusted to obtain desulfurized lithium slag concentrate, and dehydrating and drying the desulfurized lithium slag concentrate to obtain flotation lithium slag. Through complementation of chemical adsorption and physical adsorption, charge regulation and control and reinforcement of the hydrophobic layer, efficient selective separation of sulfide is realized, the addition proportion of a dispergator when the lithium slag is applied to wet ball milling of the ceramic billet is greatly reduced, the slurry performance of the lithium slag billet is remarkably improved, the cost is low, and the desulfurization effect is good.

The invention discloses an oxygen evolution-free sodium carbonate composite material as well as a preparation method and application thereof. The preparation method of the composite material comprises the following steps: carrying out powder refinement treatment on a sodium carbonate precursor to obtain particles with the average particle size from micron to nanoscale; s2, uniformly mixing the sodium carbonate precursor treated in S1 with a conductive carbon material to form a composite precursor; placing the composite precursor in an inert atmosphere or a reducing atmosphere, calcining the composite precursor at 400-900 DEG C, and then cooling the composite precursor to room temperature to obtain the oxygen evolution-free sodium carbonate composite material, wherein the conductive carbon material is a high-specific-surface-area carbon material of which the surface is rich in at least one of carbonyl, carboxyl and hydroxyl. The composite material obtained by the method disclosed by the invention is applied as a pre-sodium-modified additive, so that the decomposition voltage of the pre-sodium-modified additive can be greatly reduced, and oxygen evolution is effectively inhibited, thereby improving the first-week coulombic efficiency, cycling stability and overall safety performance of the sodium-ion battery.

The application discloses a chlorine-free compound electrolyte for improving magnesium battery performance and a preparation method thereof, and belongs to the technical field of magnesium air battery electrolytes.The chlorine-free compound electrolyte for improving magnesium battery performance is a mixed solution of sodium sulfate, sodium carbonate, 2-methyl imidazole and deionized water.The application first uses sodium sulfate to replace sodium chloride to avoid chlorine ions from accelerating magnesium corrosion;sodium carbonate reacts with a magnesium matrix to form a uniform thin magnesium carbonate layer;and 2-methyl imidazole uses a large Pi bond structure and nitrogen atoms to adsorb positive charge magnesium surfaces to form a dense film layer.The synergistic effect of the three materials can inhibit loose and porous discharge products from being deposited on the anode surface, greatly improve anode utilization efficiency to 87%, and improve the discharge voltage to -1.9 V.The application adjusts the ratio of a solvent to a solute to maximize the improvement of the discharge performance of the air battery;the prepared battery has the advantages of green environmental protection, convenient operation, simple preparation process and the like, and can realize the potential of remote electronic equipment application.