1325 results about "Carbonate sodium" patented technology

According to the invention, biomass rice hull ash and a sodium hydroxide solution are reacted to obtain water glass and carbon mud. And reacting the water glass with CO2 generated by calcining the limestone to produce a white carbon black product and a mixed waste liquid of sodium carbonate and sodium bicarbonate. Meanwhile, quick lime obtained by calcining limestone is digested and then reacts with sodium carbonate and sodium bicarbonate mixed waste liquid to generate a light calcium carbonate product and dilute sodium hydroxide waste liquid. And finally, the dilute sodium hydroxide waste liquid is concentrated and reused for water glass production, so that the waste liquid is recycled, and a complete process closed loop is formed. According to the process method disclosed by the invention, two leading-edge innovative processes, namely production of white carbon black by renewable resource biomass rice hull ash and production of white carbon black by a carbonization method, are organically combined and are coupled with production of light calcium carbonate by a limestone calcination process, so that the problem that a large amount of sodium sulfate-containing wastewater is discharged in a traditional process is solved; meanwhile, the carbon footprint of white carbon black and calcium carbonate products is greatly reduced.

The invention provides a lithium precipitation mother liquor lithium recovery method based on countercurrent centrifugal extraction. The method comprises the following steps: S1, pretreating a lithium precipitation mother liquor to obtain a lithium-containing pre-extraction solution; s2, conveying the lithium-containing pre-extraction liquid to a centrifugal extraction system, fully mixing the lithium-containing pre-extraction liquid with an organic phase, and sequentially carrying out multi-stage countercurrent centrifugal extraction; performing phase splitting to obtain raffinate and a lithium-loaded organic phase; s3, the lithium-loaded organic phase enters a washing section to be subjected to multi-stage countercurrent centrifugal washing; s4, performing multi-stage countercurrent centrifugal reverse extraction on the washed lithium-loaded organic phase to obtain a lithium-rich solution; and S5, synthesizing the lithium-rich solution and a sodium carbonate solution to obtain the battery-grade lithium carbonate. The lithium recovery method has the characteristics of rapidness, high efficiency, low equipment investment, small occupied area, less extraction agent consumption and short process flow.

The invention discloses polyether-ether-ketone resin with adjustable molecular weight distribution as well as a synthesis method and application of the polyether-ether-ketone resin. The synthesis method comprises the following steps: preparing polyether-ether-ketone resin in the presence of carbonate and / or bicarbonate of alkali metal; wherein the carbonate and / or bicarbonate of the alkali metal comprises sodium carbonate and potassium carbonate, and the sodium carbonate has gradient particle size distribution. According to the invention, sodium carbonate with specific particle size distribution is used to regulate and control the reaction rate to be stable and continuous, so that the molecular weight distribution of the polymer presents a narrower distribution form. Therefore, the molecular structure is uniform, the molecular form is uniform, the physical and chemical properties, including mechanical strength, thermal stability and chemical stability, of the material can be improved, and particularly, the thermal stability of the material is improved most remarkably.

The invention relates to the technical field of purification of organic chemicals, in particular to an aroma purification method of leaf alcohol. Comprising the following steps: preparing a methanesulfonic acid magnetic catalyst; esterification of leaf alcohol; and alcoholysis and fractionation of the esterification solution. According to the method, acetic acid is used for esterification of leaf alcohol, then clear water and a sodium carbonate solution are used for washing, the clear water can effectively remove some water-soluble impurities and acidic byproducts, and the sodium carbonate solution not only can neutralize residual acidic substances, but also can promote siloxane impurities in initial leaf alcohol to be hydrolyzed and then taken away by a water phase, so that the content of the siloxane impurities in the leaf alcohol is reduced; in the subsequent process of producing leaf alcohol through alcoholysis of the organic phase I, pure water and ethanol, silyl ether impurities are hydrolyzed in a high-temperature and strong-alkali environment, products are dissolved in waste liquid to be removed, olefine aldehyde impurities with the boiling point lower than that of leaf alcohol are removed through azeotropic fractionation with ethanol, in conclusion, the impurities in the finished product leaf alcohol can be effectively reduced, and the yield of the finished product leaf alcohol is increased. And the prepared finished product leaf alcohol is high in purity and pure in fragrance.

The invention provides a method for recycling a waste lithium iron phosphate battery positive electrode material based on organic solvent soaking. The method comprises the following steps: mixing waste lithium iron phosphate positive electrode material powder and a crown ether chelating type co-dissolving agent to obtain a leaching solution; hydrogen peroxide is added into the leachate, the pH is adjusted, a diammonium hydrogen phosphate solution is added, and iron phosphate and filtrate containing lithium ions are obtained; adding sodium carbonate into the filtrate containing lithium ions, and adjusting the pH value to obtain lithium carbonate; mixing the iron phosphate with a phosphoric acid solution to obtain purified iron phosphate; and mixing the purified iron phosphate, lithium carbonate and acetylene black to obtain the regenerated lithium iron phosphate positive electrode material. According to the method for recycling the positive electrode material of the waste lithium iron phosphate battery based on soaking of the organic solvent, the leaching rate of the lithium element is effectively increased, the selectivity to other metal ions is low, and the regenerated positive electrode material of the lithium iron phosphate battery has relatively high discharge capacity and good cycling stability.

The invention relates to the technical field, in particular to an ultralight foamed ceramic hollow sphere prepared from iron lepidolite tailings and a preparation method and application of the ultralight foamed ceramic hollow sphere. The foamed ceramic hollow sphere is prepared from the following raw materials: iron lepidolite tailings, silicon carbide, bentonite, sodium carbonate and potassium carbonate; in percentage by mass, the content of the iron lepidolite tailings is 90 to 96.4 percent; the content of the silicon carbide is 0.1-1%; the iron lepidolite tailings are prepared from the following components in percentage by mass: 77 to 80 percent of SiO2, 10 to 13 percent of Al2O3, 1.3 to 1.6 percent of Fe2O3 and 0.1 to 0.17 percent of Li2O. The ultralight foamed ceramic hollow sphere is prepared by using the iron lepidolite tailings, the silicon carbide, the bentonite, the sodium carbonate and the potassium carbonate as raw materials, can meet various market requirements of heat preservation, heat insulation, sound insulation, noise reduction and the like, and brings remarkable economic benefits and social benefits.

The invention relates to the technical field of composite catalyst materials, in particular to a ferrocobalt bimetal hydroxide / BCN composite material and a preparation method and application thereof.The preparation method comprises the steps that cobalt nitrate and ferric nitrate are used for preparing a metal salt solution, sodium carbonate and sodium hydroxide are used for preparing a precipitant solution, a B-doped carbon nitride BCN material is added into the metal salt solution to form a uniform suspension, and the suspension is dried to obtain the ferrocobalt bimetal hydroxide / BCN composite material; dropwise adding the precipitant solution into the suspension to obtain a precursor solution, performing hydrothermal reaction on the precursor solution, and performing centrifugal impurity removal and drying to construct a heterostructure between layered double hydroxide and BCN in situ to obtain the Co-Fe LDH-coated BCN composite material. Through boron doping and heterostructure construction, the charge separation capacity of graphite carbon nitride is enhanced, the electron migration efficiency is improved through a heterointerface structure, the metal ion release amount and the cycle stability are controlled, and the catalytic performance is remarkably improved.

The invention relates to the technical field of piezoelectric light-transmitting functional ceramics, and discloses a high-light-transmitting ceramic material and a preparation method thereof.The preparation method comprises the following preparation steps that sodium carbonate, potassium carbonate, niobium pentoxide, antimony trioxide, samarium oxide and zirconium dioxide powder raw materials are taken, and after primary ball milling and drying are conducted on the powder raw materials, mixed powder is obtained; carrying out pre-sintering and secondary ball milling on the mixed powder, carrying out compression molding to form a tablet, and sintering and polishing the tablet to obtain a ceramic matrix; and spraying the composite slurry to the surface of a ceramic matrix, carrying out heat treatment, and cooling to room temperature to obtain the high-transmittance ceramic material. The antimony trioxide, the samarium oxide and the zirconium dioxide are co-doped, an antimony-samarium-zirconium liquid phase is generated in the ceramic material, pores of the ceramic material are filled and eliminated, and the prepared ceramic material has excellent optical transmittance, piezoelectric property and mechanical strength.

The present invention provides a system and method for extracting lithium from salt lake brine and preparing battery-grade lithium carbonate. The system includes a coagulation and precipitation system, a filtration system, an adsorption and desorption system, a calcium and magnesium removal system, a boron removal system, a concentration system, an evaporation system, and a lithium precipitation system connected in sequence. The calcium and magnesium removal system includes a first-stage reverse osmosis concentration unit, a first-stage nanofiltration calcium and magnesium removal unit, a second-stage reverse osmosis concentration unit, a multi-stage nanofiltration calcium and magnesium removal unit, and a calcium and magnesium ion exchange unit connected in sequence. The boron removal system includes a first-stage nanofiltration boron removal unit, a multi-stage nanofiltration boron removal unit, and a boron ion exchange unit connected in sequence. After the lithium precipitation system, there are also a precision filtration system and a water washing and drying system connected in sequence. By adopting the process of the present invention, the lithium recovery rate is improved, and the product is battery-grade lithium carbonate, greatly improving the resource utilization and recovery rate of the lithium extraction system, reducing the amount of externally added water and the consumption of sodium carbonate in the process of the lithium precipitation system.

The invention belongs to the technical field of sandy soil reinforcement, and relates to a sandy soil reinforcement method combining modified chitosan film coating and cementation with biomimetic mineralization and application, the sandy soil reinforcement method comprises the following steps: S1, chitosan is subjected to swelling, alkalization, carboxymethylation and refining treatment to obtain modified chitosan; s2, respectively preparing a calcium chloride solution and a sodium carbonate solution with the same concentration; a calcium chloride solution is a cementing solution A; adding modified chitosan into a sodium carbonate solution, and uniformly stirring to form a cementing solution B; s3, the cementing liquid A is sprayed to the sandy soil, then the cementing liquid B is sprayed, and primary cementing is completed; carrying out circulating cementing for 5-20 times according to the spraying mode; and then air drying is conducted to complete sandy soil reinforcement. According to the invention, the agglomeration among calcium carbonate particles is enhanced by utilizing the cementing, film covering, mineralized crystal form adjusting and filling coupling effects of the modified chitosan, so that the calcium carbonate particles form effective cementing connection among sand particles, thereby improving the mechanical properties of the sand.

The invention relates to the technical field of fluorite ore beneficiation, discloses a fluorite ore flotation composite collecting agent and a preparation method and application thereof, and aims to solve the problems that an existing collecting agent is limited in applicability, insufficient in selectivity, poor in environmental stability and the like and is difficult to deal with separation of fluorite ore containing various impurities or under complex working conditions. The composite collecting agent is composed of dehydroabietylamine, sodium oleoyl sarcosinate, sodium silicate-citric acid composite salt, ethylene glycol butyl ether and a sodium carbonate-sodium bicarbonate buffer pair, all the components have a synergistic effect, dehydroabietylamine provides selective collecting and fine particle agglomeration functions, sodium oleoyl sarcosinate enhances adsorption stability, the composite salt inhibits gangue in a targeted mode, and therefore the adsorption efficiency is improved. Buffer pairs and ethylene glycol butyl ether guarantee the environmental adaptability of a system. The collecting agent can adapt to various fluorite ores with high sulfur, high silicon, low temperature and the like, can stably play a role under different water quality and working conditions, realizes efficient separation of fluorite and impurities, improves the separation efficiency and the concentrate quality, and is flexible in preparation process and convenient for industrial application.

The invention relates to the technical field of water treatment, and discloses a method for circularly inducing crystallization, hardness removal and desalination of calcium carbonate. Adding the seed crystal into high salt water; adding sodium hydroxide into the heavy salt water; adding sodium carbonate to generate a supersaturated solution; introducing the solution containing the calcium carbonate crystal nucleus into crystallization equipment; treating the reacted solution through solid-liquid separation equipment; further desalting the water body subjected to hardness removal by adopting a membrane separation mode; collecting and treating the formed calcium carbonate precipitate, and recovering the precipitate by adopting a separation technology; by adopting the synthesized vaterite type seed crystal, the hardness removal and desalination efficiency is remarkably improved in the cyclic induced crystallization process of calcium carbonate. Compared with the traditional non-synthetic seed crystal, the synthetic seed crystal has higher surface area and uniformity, so that the combination of calcium ions and carbonate ions can be more quickly induced to form a stable crystal nucleus, and the overall effect of the reaction is finally improved.

The utility model relates to the technical field of carbon dioxide capture, in particular to a device for capturing carbon dioxide by using sodium hydroxide and sodium carbonate, which comprises a spray tower, a power box, a gas outlet pipe, a gas inlet mechanism and a spray mechanism, the gas inlet mechanism is arranged on the inner bottom wall of the spray tower and used for blowing flue gas into the spray tower, and the spray mechanism is arranged in the spray tower and used for spraying a sodium hydroxide solution to the flue gas entering the spray tower. And meanwhile, the spraying effect of the sodium hydroxide solution is improved through the spraying mechanism, so that the problem of relatively low spraying efficiency in the sodium hydroxide spraying process in the related technology is solved.

The embodiment of the invention discloses a fluorine removal agent and a fluorine removal process for rare earth feed liquid. The fluorine removal agent comprises a first fluorine removal agent and a second fluorine removal agent, the first fluorine removal agent is polycrystal system composite calcium, the polycrystal system composite calcium is composed of calcium oxide / calcium hydroxide and calcium carbonate according to the mass ratio of (0.1-1): (0.1-1), and the second fluorine removal agent is composed of polycrystal system composite calcium and an inorganic flocculant according to the mass ratio of (0.01-1): (0.01-1). According to the method, fluorine is removed under the condition that the pH value is 4.6-5.8, fluoride composite salt precipitation is formed, fluorine in the rare earth solution can be efficiently removed, rare earth carbonate precipitated from subsequent oxalic acid or carbonate (sodium carbonate, sodium bicarbonate, ammonium bicarbonate and the like) or high-concentration rare earth feed liquid can be recycled, and the quality of the rare earth is improved. The requirements (the F content in the mixed rare earth oxide is less than 0.3%, and the F content in the high-concentration rare earth feed liquid (the concentration is greater than 100g / L) is less than 100mg / L) are met. The method is simple in process and high in operability, and has a relatively good application prospect.

The invention relates to the technical field of antistatic agents, and particularly discloses an oil product antistatic agent and a preparation method thereof. The modified polysulfone is obtained by mixing and treating the following raw materials in parts by mass: 35-40 parts of xylene, 20-25 parts of composite polyamine, 15-20 parts of polysulfone, 5-8 parts of oligomeric dopamine and 1-2 parts of an activating agent, the preparation method comprises the following steps: taking composite polyamine, mixing with oligomeric dopamine, dispersing with xylene, then adding an activator, stirring, then adding polysulfone, and continuously treating, thereby obtaining the product. The preparation method of the composite polyamine comprises the following steps: taking epichlorohydrin, dispersing, adding a mixed amine source, heating, adding sodium carbonate, continuously stirring, cooling, adding a deprotection agent, filtering after treatment, taking a liquid part, drying by distillation, washing, drying again, and grinding to obtain the composite polyamine. The oil product antistatic agent prepared by the invention has relatively strong antistatic capability and relatively long duration time, and can form a firmer double-electric-layer structure.

The invention relates to the technical field of environmental protection, and discloses a method for degrading formamide organic wastewater and recycling key metals of a retired lithium ion battery. The method comprises the following steps: S1, obtaining the positive electrode material of the retired lithium ion battery, mixing the positive electrode material with formamide organic wastewater, and carrying out hydrothermal reaction to obtain a leachate; s2, adjusting the pH value of the leachate to 6-14, and carrying out a transition metal precipitation reaction to obtain a transition metal hydroxide precursor and a lithium-rich filtrate; and S3, adding a sodium carbonate solution into the lithium-rich filtrate, carrying out a precipitation reaction, and collecting lithium carbonate. The formamide organic wastewater serves as an endogenous reducing agent, deep degradation of the formamide organic wastewater is achieved under the hydrothermal condition, efficient leaching of key metal in the retired lithium ion battery is achieved, and waste is treated with waste; the formamide degradation efficiency can reach 90% or above, and the defects that an existing formamide wastewater treatment method is high in energy consumption, large in reagent consumption, high in cost, low in degradation efficiency and large in environmental treatment pressure are overcome.

The invention relates to the technical field of resource recycling of manganese-containing wastewater, in particular to a process for preparing industrial-grade manganese carbonate by using a recycled manganese chloride solution, which adopts a two-stage purification and impurity removal strategy, performs primary purification and impurity removal by using sodium sulfide and sodium fluoride, and performs secondary impurity removal by using iminodiacetic acid grafted chelating resin. According to the invention, the problems of poor adaptability and incomplete impurity removal of the manganese chloride solution in the prior art are solved, the purity of the product is obviously improved so as to meet the requirements of the industrial grade manganese carbonate, and the process flow is simple.

The invention relates to the technical field of recovery and regeneration of waste lithium ion battery materials, in particular to a method for synchronously realizing selective extraction of lithium and direct regeneration of iron phosphate. The method comprises the following steps: providing positive electrode powder of the waste lithium iron phosphate battery; a hydrogen bond donor and a hydrogen bond acceptor are mixed, heated and stirred to obtain the eutectic solvent, the hydrogen bond donor is one or more of formic acid, acetic acid, propionic acid, pyruvic acid, phytic acid and citric acid, and the hydrogen bond acceptor is ethylene glycol; adding water into the deep-eutectic solvent for dilution, then adding the positive electrode powder and an oxidizing agent, heating and stirring, and filtering to obtain a lithium-containing leaching solution and leaching residues; carrying out concentration treatment and impurity removal treatment on the lithium-containing leachate, and then adding a saturated sodium carbonate solution to carry out lithium precipitation reaction to obtain lithium carbonate; and calcining the leaching residues to obtain iron phosphate. According to the method, the specific eutectic solvent is adopted to treat the positive electrode powder of the waste lithium iron phosphate battery, and selective extraction of lithium and direct regeneration of iron phosphate can be synchronously realized under mild conditions.

The invention provides a preparation method and application of low-bath-ratio and high-viscosity hydroxypropyl carboxymethyl composite starch ether, and relates to the technical field of starch deep processing. The method comprises the following steps: S1, premixing corn starch with a compound base catalyst and magnesium stearate, and spraying an ethanol water solution for alkalization; s2, adding epoxypropane to carry out first-stage etherification, and then adding sodium chloroacetate to carry out second-stage etherification; and S3, after the reaction is finished, performing vacuum drying, crushing and sieving to obtain the high-viscosity hydroxypropyl carboxymethyl composite starch ether. Wherein the composite alkali catalyst comprises sodium hydroxide, sodium carbonate and calcium oxide. The starch ether obtained by the method has the advantages of high substitution degree, high viscosity, low solvent consumption and low energy consumption, and overcomes the defects of the traditional semi-dry method.

The invention relates to a method for selectively leaching and regenerating a positive electrode material from a waste lithium ion battery, and belongs to the technical field of lithium ion batteries. The method comprises the following steps: discharging, disassembling, crushing, calcining and screening the waste lithium ion battery, adding an obtained positive active material into an oxalic acid solution, and stirring and reacting at 60-80 DEG C under the irradiation of an ultraviolet lamp to obtain a leaching solution rich in metal elements and leaching residue iron phosphate; adding sodium carbonate into the leachate for reaction to obtain lithium carbonate; and ball-milling and mixing iron phosphate, lithium carbonate and a carbon source, drying and calcining to obtain the regenerated lithium iron phosphate positive electrode material. The oxalic acid system is catalyzed by ultraviolet light to generate hydroxyl free radicals with strong oxidizing property, so that the leaching efficiency of lithium is remarkably improved, and the dissolution of iron is inhibited, thereby realizing the efficient separation of lithium and iron. The leaching residue is high-purity iron phosphate, lithium in the leaching solution is recycled in the form of lithium carbonate, and the leaching residue and the lithium carbonate can be directly used for regenerating the lithium iron phosphate positive electrode material as precursors, so that the technological process is greatly simplified, and the production cost is reduced.

The invention discloses micron-sized pearl glaze ceramic and a preparation method thereof, and relates to the technical field of ceramic, and the micron-sized pearl glaze ceramic is characterized by comprising a ceramic body, a toning ground coat layer and a dry particle layer, the toning ground coat layer is prepared from the following raw materials in parts by weight: 15 to 25 parts of quartz, 20 to 30 parts of feldspar, 5 to 10 parts of kaolin, 3 to 8 parts of calcined zinc oxide, 5 to 10 parts of calcium carbonate, 8 to 15 parts of barium carbonate, 8 to 15 parts of zirconium silicate, 0.05 to 0.5 part of toning metal oxide and 1 to 3 parts of functional additive; the dry particle layer is prepared from the following raw materials in parts by weight: 30 to 40 parts of quartz sand, 10 to 15 parts of borax, 5 to 8 parts of sodium carbonate, 3 to 6 parts of lithium carbonate, 10 to 18 parts of Bi2O3, 10 to 18 parts of TiO2, 0.5 to 2 parts of rare earth oxide and 0.5 to 2 parts of nucleating agent. The prepared ceramic shows soft and layered pearl luster under light rays of different angles, and the physical performance is greatly improved.

The invention belongs to the technical field of lithium battery material recovery, and particularly relates to a method for recovering a waste lithium iron phosphate positive electrode material. The method comprises the following steps: (1) grinding and sieving the positive electrode material of the waste lithium iron phosphate battery, mixing with an alkaline solution, stirring and leaching, and carrying out solid-liquid separation to obtain a lithium-rich solution and leaching residues; (2) introducing a saturated sodium carbonate solution into the obtained lithium-rich solution, carrying out heating reaction, filtering, taking a solid phase, and drying to obtain lithium carbonate; and the obtained leaching residues are dried, and ferroferric oxide is obtained. According to the method, the waste lithium iron phosphate battery positive electrode material is leached through the alkaline liquid phase, it can be guaranteed that lithium and iron in waste lithium iron phosphate are separated through a one-step leaching method, and therefore selective lithium extraction is achieved. The whole technological process is convenient to operate, mild in reaction condition and low in energy consumption, does not need to use any acid or oxidant, avoids generation of a large amount of waste liquid and harmful gas, and is high in selective lithium extraction efficiency.

The invention discloses a method for intensively leaching chromium from vanadium extraction waste slag, and belongs to the field of metallurgical chemical industry. According to the method, diboron trioxide serves as a catalyst, vanadium extraction waste slag, sodium carbonate and sodium hydroxide serve as raw materials, the raw materials and the catalyst are mixed according to a set proportion, and leaching is conducted after roasting is conducted in a microwave muffle furnace. According to the method provided by the invention, the reaction can be promoted to be efficiently carried out at medium and low temperatures, the extraction rate of chromium can reach 95% or above, and the synergistic effect of'low addition amount-high catalytic efficiency 'can be realized under the condition that a small amount of catalyst is added.

The invention provides a zinc-copper-nickel-copper smelting deslagging agent and a preparation method and a use method thereof. The zinc-copper-nickel-copper smelting deslagging agent comprises the following raw materials in percentage by mass: 5-15% of calcium fluoride, 20-30% of sodium carbonate, 5-15% of sodium fluoride, 10-20% of sodium hexafluoroaluminate and the balance of borax. Compared with the prior art, the zinc-copper-nickel-copper slag remover prepared by mixing the raw materials can effectively reduce impurities to be less than 0.14% of Fe, less than 0.005% of Pb and less than 0.003% of Si in the smelting process, the impurity components are obviously reduced, the number of times of component adjustment and unqualified sampling is reduced, impurities mixed in a casting blank are reduced, and finally the metal purity and the casting quality are improved. Meanwhile, loss of zinc and nickel is reduced to the maximum extent; and adverse effects on the zinc-copper-nickel alloy are avoided.

The embodiment of the utility model discloses a disposal system for incineration fly ash washing liquid, which comprises a pretreatment unit, a first-stage decalcification reaction tank, a second-stage decalcification reaction tank, a third-stage decalcification reaction tank, a third-stage decalcification reaction tank and a fourth-stage decalcification reaction tank, the post-treatment unit comprises a secondary decalcification reaction tank connected with a liquid phase outlet of the vertical scraper centrifuge, and the secondary decalcification reaction tank is connected with a plate-and-frame filter press; the primary decalcification reaction tank and the secondary decalcification reaction tank are respectively connected with the sodium sulfate dissolving tank and the sodium carbonate dissolving tank, and a liquid phase outlet of the plate-and-frame filter press is connected with the sodium sulfate dissolving tank and the sodium carbonate dissolving tank. By combining sodium sulfate and sodium carbonate decalcification technologies, the operation cost can be reduced, the product quality can be improved, and production equipment can be effectively protected. The method is helpful for promoting environmental protection and sustainable development, and contributes to long-term prosperity of the chemical industry.

The invention discloses a flame-retardant coating and a preparation method thereof, and relates to the technical field of coatings, the flame-retardant coating comprises the following raw materials: 100 parts of epoxy resin, 25-50 parts of hexagonal boron nitride functional modified ammonium polyphosphate, 20-30 parts of cerium-cobalt-iron layered double hydroxide, 10-15 parts of hafnium diboride, 8-16 parts of a fireproof filler, 18-30 parts of a fluxing agent, and 20-25 parts of a curing agent; the hexagonal boron nitride functionalized modified ammonium polyphosphate is prepared from the following raw materials in parts by weight: 1-3 parts of functionalized boron nitride nanosheets, 5-10 parts of ammonium polyphosphate, 70-90 parts of ethanol and 7-9 parts of water. The cerium-cobalt-iron layered double hydroxide comprises the following raw materials: 3-4 parts of cerium nitrate hexahydrate, 2-4 parts of cobalt nitrate hexahydrate, 16-20 parts of iron nitrate nonahydrate, 80-100 parts of deionized water, 20-30 parts of a sodium hydroxide solution and 60-80 parts of a sodium carbonate solution. The flame retardant provided by the invention has excellent flame retardant property.

The invention discloses high-proportion nutritional tartarian buckwheat noodles and a processing technology thereof, and relates to the technical field of tartarian buckwheat noodles. The high-proportion nutritional tartarian buckwheat noodles are composed of basic components and other components; the basic component consists of the following raw materials in parts by weight: 22-26 parts of microwave tartary buckwheat whole flour, 33-39 parts of extruded tartary buckwheat whole flour, 31-37 parts of flour and 5-7 parts of artemisia desertorum powder; the other components are added according to the following proportions by taking the amount of the basic components as the basic amount: 0.8-1.2% of table salt, 38-42% of water, 6-8% of vital gluten, 0.2-0.3% of konjac glucomannan and 0.18-0.26% of sodium carbonate. According to the tartary buckwheat noodles prepared by the formula disclosed by the invention, the proportion of tartary buckwheat is high and reaches about 60%, and the tartary buckwheat is subjected to pre-gelatinization treatment, so that the bitter taste is reduced; the noodles are good in taste, color, luster and appearance and not prone to breakage and muddy soup, the cooked breakage rate is 0%, and the cooking loss rate is only 12.4%.

The invention provides a preparation method of a lyocell and polyester interwoven fabric, which is characterized in that the preparation method comprises preparation and dyeing and finishing processes of a lyocell polyester fabric, and the dyeing and finishing processes comprise a lyocell anti-fibrillation treatment process, a polyester dyeing process and a lyocell dyeing treatment process; wherein the lyocell anti-fibrillation treatment process comprises the following steps: adding an anti-fibrillation aid KR-6347 according to 1%-4%, then adding anhydrous sodium sulphate, treating for 8-15 minutes, heating to 60-70 DEG C, adding 10-25 g / L sodium carbonate, continuing for 30-50 minutes, then cooling, draining water and cleaning. The lyocell terylene fabric is woven into knitted single jersey through knitting equipment in a yarn matching mode of separating lyocell terylene, separating lyocell and spandex. The fabric structure and the dyeing and finishing process are reasonable, the fibrillation degree of the fabric is greatly reduced through the dyeing and finishing process, the fastness to washing is high, and the breathable effect of the fabric is better under the wet condition after dyeing and finishing.

The utility model provides a sodium percarbonate oxidation reinforced low-pressure membrane method shale gas wastewater treatment system, and relates to the technical field of wastewater treatment. The sodium percarbonate oxidation reinforced low-pressure membrane method shale gas wastewater treatment system comprises a contact oxidation reaction tank, a low-pressure membrane unit and a water production unit, wherein the contact oxidation reaction tank is provided with a sodium percarbonate oxidizing agent adding pipeline and supply equipment for providing an activating agent for activating a sodium percarbonate oxidizing agent; the low-pressure membrane unit comprises a low-pressure membrane reaction tank and a membrane assembly arranged in the low-pressure membrane reaction tank, a water outlet of the contact oxidation reaction tank is communicated with a water inlet of the low-pressure membrane reaction tank, and the low-pressure membrane reaction tank is connected with a water outlet pipeline; the produced water unit comprises a produced water overflow pool and a produced water collecting pool, a water inlet of the produced water overflow pool is communicated with the water outlet pipeline, and a water outlet of the produced water overflow pool is communicated with the produced water collecting pool. The system can reduce membrane pollution in the process of purifying the shale gas wastewater by the low-pressure membrane and improve the wastewater treatment effect.

The invention belongs to the technical field of drilling fluid additives for petroleum drilling, and discloses a heat-resistant water-based drilling fluid additive as well as a preparation method and application thereof. The water-resistant water-based drilling fluid additive is a high-molecular compound which is formed by taking water as a solvent, dissolving animal bone glue to form a glue solution, and performing etherification reaction on the glue solution and bromoethane under the action of a chain transfer agent and a base catalyst. The preparation method comprises the following steps: adding animal bone glue into water, dissolving to obtain a glue solution, sequentially adding sodium hydroxide, sodium carbonate and bromoethane to form a reaction system solution, then adding a chain transfer agent, and heating and refluxing to react to obtain the water-resistant water-based drilling fluid additive. According to the prepared bromoethane modified bone glue, the chain transfer agent is added in the modification process, the technical defect that the molecular weight of the bone glue cannot be manually controlled is overcome, the inhibition effect is obvious, meanwhile, the rheological property of drilling fluid is not affected, and the problems of borehole wall instability and the like caused by shale hydration expansion in the drilling process can be effectively solved.