The invention relates to a method of recycling
anhydrous sulfate sodium from de-sulfurized lead paste
filtration, belonging to a
resource recovery and utilization process, which avoids the disadvantages that waste
sulfate is used and low concentration
sulfate sodium is emitted into the environment. The method of the invention comprises: desulfurized lead paste
filtration collection,
sodium carbonate neutralization, first time heavy
metal removal,
filtration PH value adjustment, second-time heavy
metal removal, decolorizing step, and
vaporization and
crystallization step; the device comprises a transfer tank, a
neutralization tank, a first-stage purifying tank, a PH adjusting tank, a second-stage purifying tank, a decolorization tank, a filtration collection tank and a
vaporization crystallization system; the waste sulfate collection tank is connected with a waste sulfate pre-
processing tank, the waste sulfate pre-
processing tank is respectively connected with the
neutralization tank and the PH adjusting tank. The invention can directly recycle
anhydrous sulfate sodium, the waste sulfate is used to neutralize the
carbonate sodium remained in the filtration; the heavy
metal ions and other ions in the filtration are removed according to two steps, so that the grade of obtained
anhydrous sulfate sodium is equal to or larger than industrial grade.