The present application belongs to the field of gel
electrolyte, and discloses a
hydrolysis-resistant
Schiff base hydrogel
electrolyte for supercapacitors, and a preparation method and application thereof. The present application utilizes the natural dissociation of
polyallylamine hydrochloride in
aqueous solution, and does not need to adjust the pH value, so that
free amino groups can be released under acidic conditions to occur
condensation reaction with
glutaraldehyde, and a three-dimensional network crosslinked by
Schiff base structure is obtained. The preparation method is simple, does not need
organic solvent, and the reaction is controllable, and the gelation can be completed at
room temperature in a short time. The obtained hydrogel
electrolyte overcomes the defect that the traditional
Schiff base structure is easy to hydrolyze under acidic conditions, and has excellent
chemical stability. The
solid-state
supercapacitor assembled by using the in-situ forming capacity effectively solves the problem of poor contact between the
electrode and the electrolyte, improves the
conductivity, specific
capacitance and
energy density of the device, and has wide application prospect in the field of flexible
energy storage devices.