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Foaming composite material with high thermal conductivity

A composite material and foaming material technology, which is applied in the directions of non-polymer adhesive additives, adhesive types, adhesive additives, etc. Excellent waterproof and shock absorption function, improved thermal conductivity and shock resistance, improved processing performance

Active Publication Date: 2014-05-28
ZHEJIANG RUNYANG NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the prior art, epe, eva, ixpe, xpe, rubber foaming materials, etc. are often used as foaming materials. These products have the function of heat preservation and heat insulation, but their thermal conductivity is poor, which is limited in many application fields and consumes a lot of energy.
[0003] CN101974208A (2011-2-16) discloses a high thermal conductivity resin composition and a high thermal conductivity metal clad board made of it, but the application of this material is not wide enough, and the thermal conductivity needs to be improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Primary mixing: Add 8 parts of alumina powder to 40 parts by weight in a 1:1 weight ratio to form low-density polyethylene with a density of 0.900-0.915 g / cm3 and low-density polyethylene with a density of 0.940-0.978 g / cm3 After the high-density polyethylene is mixed evenly, 3 parts of silicone oil are added to obtain the initial mixture;

[0048] Plasticizing and granulating: Add 2 parts of flame retardant, 6 parts of dioctyl phthalate, 3 parts of EPDM toughening agent for EPDM, 1 part of silane coupling agent and 0.6 parts by weight to the primary mixture The antioxidant blending modification plasticizing that the mixture of the phenolic main antioxidant 1010 that forms by weight ratio 3:7 and the mixture of auxiliary antioxidant 168 is formed, extrudes granulation to obtain the first particle;

[0049] The flame retardant consists of the following components in parts by weight: 20 parts of ammonium oligophosphate, 10 parts of ammonium phosphate, 6 parts of ammonium ...

Embodiment 2

[0054] Primary mixing: Add 12 parts of graphite to 100 parts by weight and mix at a weight ratio of 1:1 to form high-density polyethylene with a density of 0.940-0.978 g / cubic centimeter and linear low-density polyethylene with a density of 0.918-0.935 g / cubic cm After the density polyethylene is mixed evenly, 6 parts of silicone oil are added to obtain the initial mixture;

[0055] Plasticizing and granulating: Add 8 parts of flame retardant, 10 parts of chlorinated paraffin, 7 parts of EPDM toughening agent for EPDM, 4 parts of aluminate coupling agent and 1.2 parts by weight to the initial mixture. Antioxidant blending modified plasticization composed of phenolic primary antioxidant 1010 and auxiliary antioxidant 168 mixed at a weight ratio of 4:6, extruded and granulated to obtain the first particle;

[0056] The flame retardant consists of the following components in parts by weight: 50 parts of ammonium oligophosphate, 25 parts of ammonium phosphate, 12 parts of ammonium...

Embodiment 3

[0066] Initial mixing: Add 10 parts of copper powder to 80 parts by weight and mix high-density polyethylene with a density of 0.940-0.978 g / cubic centimeter and ethylene-vinyl acetate copolymer at a weight ratio of 1:1. Mix evenly and then add 5 parts of silicone oils obtain initial mixture;

[0067] Plasticizing and granulating: Add 6 parts of flame retardant, 8 parts of dioctyl phthalate, chlorinated paraffin or one or more softening plasticizers in naphthenic oil to the initial mixture by weight , 5 parts of EPDM toughening agent for EPDM rubber, 3 parts of aluminum-titanium composite coupling agent and 1 part of phenolic primary antioxidant 1010 and auxiliary antioxidant 168 mixed at a weight ratio of 1:1. Antioxidant blending modification plasticization, extrusion granulation to obtain the first particle;

[0068] The flame retardant consists of the following components in parts by weight: 30 parts of ammonium oligophosphate, 15 parts of ammonium phosphate, 10 parts of ...

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Abstract

The invention relates to a resin foaming composite material, especially to a foaming composite material with high thermal conductivity. The foaming composite material is prepared by the following steps: primary mixing: 8-12 parts by weight of a heat conduction material is added into 40-100 parts by weight of matrix resin to obtain a primary mixed object; plasticization and granulation: 2-8 parts by weight of a fire retardant, 6-10 parts by weight of a softening plasticizer, 3-7 parts by weight of a flexibilizer, 1-4 parts by weight of a coupling agent and 0.6-1.2 parts by weight of an antioxidant are added into the primary mixed object for blending modification and plasticization, and extrusion and granulation are carried out to obtain a first granule; remixing and foaming: 15-25 parts by weight of one or more selected from fatty alcohol polyoxyethylene lauryl ether sulfate sodium or an azo-compound are mixed with one or more selected from the first granule and 30-70 parts by weight of the matrix resin, extrusion and foaming are conducted to prepare a foaming material, and a full-open foaming material layer is compounded on the foaming material through glue to form the foaming composite material with high thermal conductivity. The material provided by the invention has high thermal conductivity and is waterproof and shock-absorbing.

Description

technical field [0001] The invention relates to a resin foam composite material, in particular to a high thermal conductivity foam composite material. Background technique [0002] In the prior art, epe, eva, ixpe, xpe, rubber foaming materials, etc. are commonly used as foaming materials. These products have the function of heat preservation and heat insulation, but their thermal conductivity is poor, which limits their application in many fields and consumes a lot of energy. [0003] CN101974208A (2011-2-16) discloses a high thermal conductivity resin composition and a high thermal conductivity metal-clad board manufactured using it. However, the application of this material is not wide enough, and the thermal conductivity needs to be improved. Contents of the invention [0004] The object of the present invention is to provide a high thermal conductivity foaming composite material with high thermal conductivity and waterproof and shock absorption. [0005] Above-mentio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/06B32B27/18B32B27/32B32B7/12C08L23/06C08L83/04C08L23/08C08K13/02C08K3/22C08K3/04C08K3/08C08K3/34C08K3/28C08K5/01C08J9/10C08J9/04C08J3/28C08J3/24C08K13/04C08K7/14C09J201/00C09J111/00C09J11/04C09J11/06
Inventor 杨庆锋
Owner ZHEJIANG RUNYANG NEW MATERIAL TECH
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