A kind of flame-retardant two-component adhesive and preparation method thereof

A two-component, adhesive technology, applied in the direction of adhesives, adhesive additives, non-polymer adhesive additives, etc., can solve the problem that two-component adhesives do not have flame retardancy, etc., and achieve high adhesion intensity effect

Active Publication Date: 2021-09-03
信泰永合(烟台)新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Aiming at the problem that the existing two-component adhesives for batteries do not have flame retardancy, the present invention provides a flame-retardant two-component adhesive and a preparation method thereof

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A flame retardant double-component adhesive, including the A component and the B component, the A component and the B component are composed of the following weight percent material, respectively.

[0019] A Component: Modified isocyanate prepolymer 85%, toluene phosphate diphenyl phosphate phosphate diphenyl phosphate, 8% alumina and 1% of phenol, B component: propylene glycol 75%, 4,4'-double bismino group 3%, γ-aminopropyltriethoxysilane 2%, γ-aminopropyltriethoxysilane, 10% phosphate diphenyl phosphate, 10% aluminum hydroxide; the weight ratio of the component A component and B component is 1: 1.

[0020] The modified isocyanate prepolymer consists of 120 parts of the following weight: 120 parts of IPDI dimers, 60 parts of PPG 20070 parts, three (2-carbonylthyl) phosphorus hydrochloride, 1 part of Dibutinikinikin, and 0.05 benzene phenols.

[0021] The preparation method of the flame retardant double-component adhesive adhesive is:

[0022] 1) Preparation modified isocy...

Embodiment 2

[0025] A flame retardant double-component adhesive, including the A component and the B component, the A component and the B component are composed of the following weight percent material, respectively.

[0026] A component: 70% of modified isocyanate prepolymer, 3 (xylene) of three (xylene) esters, 15% aluminum hydroxide, 2% of naphthoquinone; B component: propanol 50%, MoCA 6%, γ- (2,3-cyclopropoxy) propyltrimethoxysilane 4%, isopropylphocyanlate triphenyl ester, 20% graphene; the amount of component A component and B component is 1: 1 .

[0027] The modified isocyanate prepolymer consists of 150 parts by weight of the following weight: MDI trimer, PEG40050 parts, N, N-bis (2-hydroxyethyl) amamomethylphosphonic acid diethyl ester, two 0.5 parts of Dibutylmateikhalate and 2.5 parts of tert-butylphenol.

[0028] The preparation method of the flame retardant double-component adhesive adhesive is:

[0029] 1) Preparation modified isocyanate prepolymer: MDI trimer, PEG400, N, N-bis ...

Embodiment 3

[0032] A flame retardant double-component adhesive, including the A component and the B component, the A component and the B component are composed of the following weight percent material, respectively.

[0033] A component: 50% of modified isocyanate prepolymer, trioliphenyl phosphate 20%, graphene 22% and a naphthoquinone; B component: propylene glycol 30%, D2000%, vinyl triethoxysilane 5% , Phosphate phosphate 30%, 25% alumina; the weight ratio of the amount of component A and B component is 1: 1.

[0034] The modified isocyanate prepolymer consists of 180 parts by weight of the following: TDI dimer, 100 parts of PCDL, three (2-chloropropyl) esters, 0.05 parts of Dibuttin dibutyltin in February, 5 parts of phosphoric acid .

[0035] The preparation method of the flame retardant double-component adhesive adhesive is:

[0036] 1) Preparation of modified isocyanate prepolymer: TDI dimer, PCDL500, phosphoric acid three (2-chloropropyl) ester, dibutyltin and phosphoric acid, mixing...

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PUM

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Abstract

The invention discloses a flame-retardant two-component adhesive, which comprises A component and B component. The A component and the B component are respectively composed of the following substances by weight percentage. A component: modified isocyanate prepolymerized Body 55‑85%, flame retardant a 6‑20%, filler a 8‑22% and stabilizer 1‑3%; B component: polyol 30‑75%, amine 3‑10%, coupling agent 2 ‑5%, flame retardant b 10‑30%, filler b 10‑25%; the weight ratio of component A to component B is 1:1. The invention adopts the hydroxyl-terminated phosphorus copolymer to modify the polyurethane prepolymer, and prepares the polyurethane prepolymer with flame retardant performance, which has flame retardancy when used as an adhesive, while maintaining the traditional two-component polyurethane adhesive strength and thermal conductivity. The flame-retardant two-component adhesive of the present invention has good application in the bonding of new energy battery structures and the like, and has high bonding strength to plastics and metals.

Description

Technical field [0001] The present invention relates to the field of adhesives, and more particularly to a flame retardant double-component adhesive and a preparation method thereof. Background technique [0002] Flame retardant double-component polyurethane adhesive for new energy cells, require high strength, excellent thermal conductivity, and can be suitable for bonding, solvent corrosion resistance and high temperature resistance. Compared to traditional adhesives, the two-component adhesive has high temperature and good thermal conductivity, and the application on new energy batteries can solve some of the limitations facing traditional curing adhesives. However, in some special scenes, there is a need to have flame retardancy, and the flame retardant adhesive can improve the safety and reliability of the battery in addition to high-strength and thermally conductive performance. Inventive content [0003] The present invention provides a flame retardant double-component ad...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J175/04C09J175/08C09J11/04C08G18/32
CPCC08G18/3882C08G18/3885C08G18/3889C08K2003/2227C08K2201/014C09J11/04C09J175/04C09J175/08C08K3/22C08K3/042
Inventor 李贯中林志秀林绍盛
Owner 信泰永合(烟台)新材料有限公司
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