A kind of durable reflective self-layering road marking paint and preparation method thereof
A road marking and self-layering technology, applied in reflective/signal coatings, rosin coatings, coatings, etc., can solve problems such as increasing construction difficulty, reducing the reflective effect and service life of marking lines, and falling off of microcrystalline ceramic beads. Achieve the effect of ensuring reflective brightness and lasting brightness, improving lasting reflective performance, and improving low temperature crack resistance
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Embodiment 1
[0045] In order to realize the "suspension" of irregular ceramic particles in the matrix of road marking paint and provide mosaic sites for reflective materials, the present invention screens the fillers. Different types of fillers and particle sizes were used to form road marking paints with irregular ceramic particles (particle size 1.0-1.5mm), and the settlement effect of irregular ceramic particles in road marking paints composed of different fillers was investigated (drying rear micrometer measurement), the method is as follows:
[0046] 1) First add 16 parts by weight of C5 petroleum resin, 3 parts by weight of rosin maleic anhydride polyol ester, 20 parts by weight of internally mixed glass microspheres and 20 parts by weight of filler in the stirring tank and stir evenly; then add 35 parts by weight of irregular ceramic particles (particle size is 1.0-1.5 mm), 5 parts by weight of calcium halophosphate fluorescent powder, and finally add 10 parts by weight of pigment t...
Embodiment 2
[0055] With sequence 14 in embodiment 1 as filler, reflective material glass beads and / or 3M are sprinkled on the surface of road markings TM All-weather microcrystalline ceramic beads (90S, white), test 1) the wear resistance of road markings, and evaluate the bonding force between reflective materials and road markings; 2) test the change value of the retroreflective brightness coefficient with the service cycle to measure the actual reflection Performance, which can evaluate the actual service life of the reflective material; the specific method is as follows:
[0056] 1) First add 16 parts by weight of C5 petroleum resin, 3 parts by weight of rosin maleic anhydride polyol ester, 20 parts by weight of internally mixed glass beads and 20 parts by weight of filler (quartz sand 400-500 mesh, barium sulfate and dolomite) in the stirred tank Mother powder is 200-300 mesh, the three are equal in weight) and stirred evenly; then add 35 parts by weight of irregular ceramic particle...
Embodiment 3
[0066] Compared with Example 2, Example 3 does not add internally mixed glass beads when preparing the road marking paint, so as to remove the influence of internally mixed glass beads on the coefficient of retroreflection brightness, and detect the change of the coefficient of retroreflective brightness with the service cycle The value is used to measure the actual reflective performance, so as to measure the degree of shedding of the reflective material sprinkled on the road markings. The results are shown in Table 3:
[0067] Table 3 Variation of retroreflective luminance coefficient of different road markings with service cycle
[0068]
[0069]
[0070] Note: 3M microcrystalline ceramic beads-D1 refers to the use of 3M microcrystalline ceramic beads as the reflective material, but the particle size of irregular ceramic particles is reduced from 1.0-1.5mm to 0.1-0.3mm.
[0071] The retroreflection brightness coefficient in the above Table 3 is the dry state retroref...
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