Polarizing plate with anti-reflection layer and method for producing the same
An anti-reflection layer and manufacturing method technology, applied in the direction of polarizing elements, chemical instruments and methods, layered products, etc., can solve the problems of poor appearance, poor appearance, and uneven hue difference of polarizers, and achieve optical reliability and suppression bad appearance effect
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[0093] Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited to these Examples. In addition, the measuring method of each characteristic is as follows.
[0094] (1) Moisture permeability of polarizer
[0095] The polarizing plate (polarizer laminated body) used in the Example and the comparative example was cut out in the circular shape of 10 cmΦ, and it was set as a measurement sample. The measurement sample was left to stand for 24 hours under the conditions of a temperature of 40°C and a humidity of 92%RH, and then the moisture permeability was measured under the test conditions of a temperature of 40°C and a humidity of 90%RH using "MOCON" manufactured by Hitachi, Ltd. .
[0096] (2) The moisture permeability of the substrate
[0097] For the films used as the substrates in the examples and comparative examples, in accordance with the moisture permeability test (cup method) of JIS Z0208, the passing area of 1 m within 2...
manufacture example 1
[0108] Production of acrylic resin film 1
[0109] Methyl methacrylate (MMA), 2-(hydroxymethyl) methyl acrylate (MHMA), and toluene were added to a reactor equipped with a stirring device, a temperature sensor, a condenser tube, and a nitrogen gas introduction tube, and extrusion at 250°C was carried out. Cyclization condensation reaction and devolatilization are carried out in the machine to obtain transparent lactone ring-containing acrylic resin particles. The obtained pellets were mixed with acrylonitrile-styrene resin, melt-kneaded using a twin-screw extruder at a cylinder temperature of 240°C, and re-pelletized.
[0110]The obtained pellets were put into a single-screw extruder, melt-mixed, and formed into a film through a T-die.
[0111] The obtained extruded film was simultaneously biaxially stretched to 2 times in the longitudinal direction and the width direction, respectively, at a stretching temperature of 160°C. The thickness of the obtained film was 40 μm. Th...
manufacture example 2
[0112] Production of acrylic resin film 2
[0113] Methyl methacrylate (MMA), 2-(hydroxymethyl) methyl acrylate (MHMA), toluene, and polystyrene were added to the reactor equipped with a stirring device, a temperature sensor, a condenser tube, and a nitrogen introduction tube, and the mixture was heated at 250 °C. The cyclization condensation reaction and devolatilization are carried out in an extruder at ℃ to obtain transparent lactone ring-containing acrylic resin particles. The obtained pellets were put into a single-screw extruder, melt-mixed, and formed into a film through a T-die. The obtained extruded film was simultaneously biaxially stretched to 2 times in the longitudinal direction and the width direction, respectively, at a stretching temperature of 160°C. The thickness of the obtained film was 40 μm. The resin composition ratio of the obtained film was confirmed by NMR and found to be 76% of MMA, 19% of lactone rings, and 5% of styrene.
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