The present invention provides an ACQ fluorescent probe composition, which is characterized in that the ACQ fluorescent probe composition is a probe solution for directly determining the cmc concentration of a surfactant, the ACQ fluorescent probe composition comprises a probe molecule and an auxiliary agent, the probe molecule is a fluorescent molecule having the property of aggregation-caused
luminescence quenching (ACQ), the auxiliary agent comprises more than one non-volatile
organic solvent, and the auxiliary agent is a non-volatile
organic solvent. The
boiling point of the
organic solvent is 100 DEG C or more, and the HSP distance Ra, which is the distance between the Hansen
solubility parameters of the probe molecule and the organic
solvent, is 17 (MPa) 1 / 2 or less. Also provided are a cmc measurement method, a
stain cleaning concentration determination method, a detergent delivery control method, and a detergent delivery
control system using the ACQ fluorescent probe composition.