Asphalt composition containing hydrogenated conjugated diene copolymer

Abstract

An asphalt composition comprising from 0.5 to 50 parts by weight of a hydrogenated conjugated diene copolymer (a) and 100 parts by weight of asphalt (b), wherein the hydrogenated conjugated diene copolymer (a) comprises a polymer block (A) comprising vinyl aromatic monomer units and at least one hydrogenated copolymer block (B) obtained by hydrogenation of a non-hydrogenated random copolymer block comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated conjugated diene copolymer (a) having the following characteristics (1) to (5): (1) the content of the vinyl aromatic monomer units is more than 30% and not more than 60% by weight per weight of the hydrogenated conjugated diene copolymer; (2) the content of the polymer block (A) is from 5% to 50% by weight per weight of the hydrogenated copolymer; (3) the weight average molecular weight is from 30,000 to 500,000; (4) the percentage of hydrogenation of the double bonds in the conjugated diene monomer units is from 60% to 100%; and (5) at least one peak of the loss tangent (tan δ) is present in the range of from −40° C. to less than −10° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer.

Description

BACKGROUND OF THE INVENTION [0001] (1) Field of the Invention [0002] The present invention relates to an asphalt composition containing a hydrogenated conjugated diene copolymer with a specific structure. More particularly, the present invention relates to an asphalt composition comprising 0.5 to 50 parts by weight of a hydrogenated conjugated diene copolymer (a) and 100 parts by weight of asphalt (b), wherein the above described hydrogenated conjugated diene copolymer (a) comprises a polymer block (A) comprising vinyl aromatic monomer units and at least one hydrogenated copolymer block (B) obtained by hydrogenation of a non-hydrogenated random copolymer block comprising conjugated diene monomer units and vinyl aromatic monomer units, the above described hydrogenated conjugated diene copolymer (a) having the following characteristics (1) to (5): [0003] (1) the content of the above described vinyl aromatic monomer units is more than 30% and not more than 60% by weight per weight of t...

AI Technical Summary

Benefits of technology

[0015] Under these circumstances, the present inventors have conducted intensive investigations on the improvement in characteristics of a composition comprising a hydrogenated conjugated diene copolymer and asphalt in order to solve the above problems in the prior art. As a result, the present inventors have found that an asphalt composition containing a hydrogenated conjugated diene copolymer has high softening point, modulus and elongation and is excellent in high-temperature storage stability, wherein the hydrogenated conjugated diene copolymer comprises a polymer block (A) comprising vinyl aromatic monomer units and at least one hydrogenated copolymer block (B) obtained by hydrogenation of a non-hydrogenated random copolymer block comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated ...

Problems solved by technology

However, the asphalt composition obtained according to such a method does not provide sufficient storage stability during high-temperature storage, resulting in separation of polymers from the asphalt composition, increase in melt viscosity and reduction of workability for road pavement.

However, such improvement methods have not yet provided adequate results and a further improvement has been desired.

However, the above described composition is inadequ...