Method for processing and recycling wastewater containing fluorine, chromium ion

A recovery method and wastewater treatment technology, which is applied in water/sewage treatment, adsorption water/sewage treatment, neutralization water/sewage treatment, etc., can solve the problem of chromium and chemical oxygen demand (COD) content indicators, and waste water that has not been scaled Problems such as advanced application and unseen application, to meet the requirements of environmental protection production, realize the effect of emission reduction and waste water recycling and reuse

Inactive Publication Date: 2008-10-29
佛山市三水凤铝铝业有限公司 +1
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Problems solved by technology

It should be pointed out that the content of various pollutants in the treated wastewater was not found in this report, and the full text did not involve the content indicators of chromium and chemical oxygen demand (COD). In addition, this article was published in 2001, so far no relevant applications have been seen.
[0009] To sum up, at present, my country, especially Guangdong Pro

Method used

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Embodiment Construction

[0018] The implementation of the present invention divides the waste water of aluminum profile production enterprises (using fluorine-containing technology for surface treatment) into three categories according to the difference of pollutants, including that the main pollutants are hexavalent chromium-containing waste water, the main pollutants are fluorine and chemical The waste water with high oxygen demand COD and fluorine content and the main pollutant is waste water with low fluorine content of aluminum, which are treated by classification and diversion.

[0019] (1) Chromium-containing wastewater treatment

[0020] The first is to collect wastewater, adjust the pH value, and perform a chemical reaction of reducing hexavalent chromium to trivalent on the collected wastewater, so that trivalent chromium can form chromium hydroxide precipitation, and then add PAM to flocculate the chromium hydroxide precipitation to obtain fluoride Calcium precipitation, followed by mud con...

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Abstract

The invention discloses a wastewater treatment and recycling technology for aluminum profile production enterprises. According to different pollutants, the wastewater produced by the aluminum profile production enterprises can be divided into three types to be treated: chromium-containing wastewater, high fluorine-containing wastewater and low fluorine-containing wastewater. The three types of wastewater carry out classification treatment and splitting treatment: (1) the chromium-containing wastewater is secondarily processed to remove hexavalent chromium and other harmful impurities; the processed water can be 100 percent recycled; (2) most of the fluorine and aluminum in the high fluorine-containing wastewater can be removed by coagulation precipitation method; part of the first treated wastewater can be recycled and used in the related process which has low requirement to the quality of water; other wastewater is secondarily processed by adopting composite of modified activated carbon and modified zeolite to further remove the fluorine and chemical oxygen demand COD; then part of the wastewater is recycled and the other part achieved standard is discharged; (3) most of the aluminum in the low fluorine-containing wastewater is removed by neutralization precipitation method; then the wastewater is secondarily processed by adopting the composite of the modified activated carbon and the modified zeolite to further remove the pollutants in the wastewater; the wastewater can be all recycled.

Description

Technical field: [0001] The invention relates to the technical field of waste water treatment of aluminum profile production enterprises, in particular to 100% treatment and reuse of chromium ion-containing waste water, using modified activated carbon and modified zeolite to compound secondary treatment of aluminum profile production waste water, and removing waste water A treatment and recovery method for waste water containing fluorine and chromium ions, in which fluorine and chemical oxygen demand (COD) are reused. Background technique: [0002] my country's per capita water resources are far below the world average, so saving and protecting water resources is particularly important. The "National Environmental Protection Eleventh Five-Year Plan" issued on November 22, 2007 clearly requires that by 2010, the total national chemical oxygen demand (COD) emissions will be reduced by 10% compared with 2005, from 14.14 million tons in 2005 to 12.7 million tons in 2010, the to...

Claims

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Application Information

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IPC IPC(8): C02F9/04C02F1/70C02F1/62C02F1/52C02F1/66C02F1/28C02F101/14C02F101/22
Inventor 吴小源黄志其陈慧刘志铭
Owner 佛山市三水凤铝铝业有限公司
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