Cosmetic preparation, method for producing same, composition for cosmetic preparations, cosmetic preparation containing the composition for cosmetic preparations and method for producing same, and cleanser for industrial use
A technology for cosmetics and compositions, applied in cosmetic preparations, cosmetics, detergent compositions, etc., can solve the problems of poor cleaning, skin pain, sebum removal, etc., and achieve excellent cleaning properties, reduced environmental load, and excellent cleaning properties. and low aggressiveness
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[0218] The present invention will be described in more detail by showing examples below, but the present invention is not limited to the following examples.
[0219] The viscosity of isostearic acid was measured at 10° C. in a strain-controlled rheometer (manufactured by Haake Co., Ltd., Leostress RS1 type) using a spinner C60 / 2Ti.
Synthetic example 1
[0220] [Synthesis Example 1: Synthesis of PDO Diisostearate]
[0221] Into a 1 L four-necked flask equipped with a stirrer, a thermometer, a nitrogen blowing tube, and a dehydrator, 79 g (1.04 mol) of 1,3-propanediol {Zemea propanediol (manufactured by DuPont Tate & Lyle BioProducts)} from microbial fermentation and 621 g of (2.13mol) isostearic acid [trade name: EMERSOL 875 (manufactured by Cognis Co., Ltd., viscosity: 103mPa·s (10°C, 10Pa))] derived from plants such as rapeseed, under a stream of nitrogen, the generated water was removed, and at the same time React at a temperature of 220° C. for 9 hours, remove excess fatty acid under reduced pressure, carry out decolorization and deodorization, and obtain 490 g of PDO diisostearate (yield 70%).
[0222] The purity of the obtained PDO diisostearate can be confirmed by gas chromatography (GC-2010 column; DB-5HT detector; manufactured by FID Corporation, Shimadzu Corporation).
[0223] The obtained PDO diisostearate is used ...
Synthetic example 2
[0224] [Synthesis example 2: Synthesis of PDO-C8 / C10 diester]
[0225] Into a 1 L four-necked flask equipped with a stirrer, a thermometer, a nitrogen blowing tube, and a dehydrator, 130 g (1.71 mol) of 1,3-propanediol {Zemea propanediol (manufactured by DuPont Tate & Lyle BioProducts)} from microbial fermentation and 407 g (2.83 mol) n-caprylic acid (caprylic acid) derived from palm kernel (manufactured by Wako Pure Chemical Industries, Ltd.) and 163 g (0.92 mol) of n-capric acid (capric acid) derived from palm kernel (manufactured by Wako Pure Chemical Industries, Ltd.), under nitrogen flow , The water generated was removed, while reacting at a temperature of 220° C. for 7 hours, the excess fatty acid was removed under reduced pressure, and decolorization and deodorization were carried out to obtain 420 g of PDO-C8 / C10 diester (yield 60%).
[0226] The purity of the obtained PDO-C8 / C10 diester can be confirmed by gas chromatography (GC-2010 column; DB-5HT detector; manufactu...
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