The invention relates to a refrigerating
machine oil composition, a preparation method and an application of the refrigerating
machine oil composition in cryosleep
refrigeration equipment. The refrigerating
machine oil composition comprises
base oil, an anti-wear agent, an
antioxidant, a
metal deactivator and an acid capturing agent. The
fluorine-containing cyclobutyl synthetic ester disclosed by the invention is generated by esterification of n-
caprylic acid (long-chain
carboxylic acid) and (3, 3-difluorocyclobutyl)
methanol (
fluorine-containing cyclobutyl
alcohol), so that a four-membered ring rigid framework of (3, 3-difluorocyclobutyl) in a molecular structure of the
fluorine-containing cyclobutyl synthetic ester can destroy regular stacking of molecular chains; moreover, due to the strong
electron withdrawing effect of two fluorine atoms connected with cyclobutyl, the intermolecular Van der Waals' force is weakened, and due to the flexible adjustment of n-
caprylic acid linear
alkyl, the
pour point of the refrigerating machine oil composition is as low as-50 DEG C or below, so that the refrigerating machine oil composition still has excellent flowability at an ultralow temperature, and the refrigerating machine oil composition can be widely applied to refrigerating machines. Therefore, the lubricating oil has the advantages of excellent
viscosity-temperature performance, excellent lubricating performance and low
pour point.